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91.
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Doubly charged lead clusters Pb72+, Pb92+, Pb112+ and Pb132+, far below the critical size for Coulomb explosion of par ticles with sphere like configurations (Pb30) have been detected in time of flight mass spectra. Their existence can be explained by chain-like clusters. 相似文献
94.
95.
Simons C Hanefeld U Arends IW Minnaard AJ Maschmeyer T Sheldon RA 《Chemical communications (Cambridge, England)》2004,(24):2830-2831
Rhodium-MonoPhos was successfully immobilised by ionic interactions on aluminosilicate AlTUD-1. The resulting new heterogeneous catalyst can be used in water and showed excellent enantioselectivity and activity in the asymmetric hydrogenation of methyl-2-acetamidoacrylate. 相似文献
96.
Gago S Pillinger M Valente AA Santos TM Rocha J Gonçalves IS 《Inorganic chemistry》2004,43(17):5422-5431
A Zn,Al layered double hydroxide (LDH) with Zn/Al = 1.45 and containing nitrate anions was prepared by coprecipitation and characterized by powder X-ray diffraction, Zn K-edge extended X-ray absorption fine structure spectroscopy (EXAFS), thermogravimetric analysis, FTIR and FT Raman spectroscopy, and (27)Al MAS NMR spectroscopy. Three Zn...O and four Zn...M (M = Zn, Al) shells could be fitted to the low-temperature (40 K) EXAFS spectrum, in accordance with a model for an ordered cationic sheet. The nitrate anions were easily exchanged by 2,2'-bipyridine-5,5'-dicarboxylate anions, resulting in an increase in the basal spacing from 9 to 18 A. The basal spacing of the pillared derivative indicates that the anions are arranged with their longest dimension nearly perpendicular to the host layers. This material exhibits a high encapsulating ability, as evidenced by its interaction with a dichloromethane solution of the dioxomolybdenum(VI) complex MoO(2)Cl(2)(THF)(2). A material with a metal loading of 11.2 wt % was obtained. Molybdenum K-edge EXAFS analysis could not substantiate the formation of a supported complex of the type MoO(2)Cl(2)(N-N) but instead indicated the formation of unidentate-bridged entities of the type [O(2)Mo-O-MoO(2)] with a metal-metal separation of 3.29 A. The molybdenum-containing LDH was active as a catalyst for the liquid-phase epoxidation of cis-cyclooctene, 1-octene, and trans-2-octene using tert-butyl hydroperoxide as the oxygen source, yielding the corresponding epoxides as the only products. For reactions carried out with no additional solvent (other than n-decane) or in the presence of 1,2-dichloroethane, the solid catalyst could be recycled with no major loss of activity. Other tests confirmed that the systems functioned as true heterogeneous catalysts. 相似文献
97.
98.
Angurell I Martínez-Ruiz I Rossell O Seco M Gómez-Sal P Martin A 《Chemical communications (Cambridge, England)》2004,(15):1712-1713
Tri(N-pyrrolyl)phosphine reacted with the sigma/pi complex [Pd(mu-Cl)(COD-MeO)]2 to give the octa-cycle [Pd(mu-Cl)[P(pyrl)3]]8 containing four Pd(I)-Pd(I) unbridged bonds. 相似文献
99.
100.
Silva MM Vale MG Damin IC Welz B Mandaji M Fett JP 《Analytical and bioanalytical chemistry》2003,377(1):165-172
The amount of sample that is available for analysis in laboratory plant cultivation experiments is usually very limited. Highly sensitive analytical techniques are therefore required, even for elements that are present in the plants at mg g–1 concentrations, and graphite furnace atomic absorption spectrometry (GFAAS) was chosen in this work because of its micro-sampling capability, and its relatively simple operation. Four micro-methods were investigated for the determination of iron in roots and leaves of rice plants: i) a micro-digestion with nitric and hydrochloric acids, ii) a slurry procedure using tetramethylammonium hydroxide (TMAH) tissue solubilizer, iii) a slurry prepared in 1.4 mol L–1 nitric acid, and treated in an ultrasonic bath, and iv) the direct analysis of solid samples. The micro-digestion was suffering from high blank values and contamination problems, so that it could not be recommended for routine purposes. The TMAH method exhibited poor precision and occasional low recoveries, particularly for real samples. Direct solid sampling analysis gave results similar to those obtained with the slurry technique with ultrasonic agitation for the determination of iron in certified reference materials with iron content up to about 100 g g–1, but was too sensitive for the investigated rice plants, which had an iron content up to several mg g–1. The slurry technique with ultrasonic treatment of the samples, suspended in dilute nitric acid, was finally adopted as the method of choice.The method was then applied for the determination of iron in the leaves and in different compartments of the roots of two rice cultivars, one sensitive to iron toxicity, an important nutritional disorder, and the other one resistant to iron toxicity. The results suggest that the higher resistance to iron toxicity of the second cultivar is due to a smaller uptake of iron from the soil, resulting in lower iron levels in all compartments of the plant. 相似文献