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171.
Georgi E. Chernev Borislava V. Borisova Lyudmila V. Kabaivanova Isabel M. Salvado 《Central European Journal of Chemistry》2010,8(4):870-876
This work reports the sol-gel synthesis of silica hybrids. We determined the effect of the type and quantity of silica precursors
and organic compounds on the resulting structure, surface area, nanostructure design and size, and potential applications.
The structure of the synthesized hybrids was analyzed using FT-IR, XRD, BET-Analysis, SEM, and AFM. We demonstrate the immovilization
of whole living thermophilic bacterial cells with cyanocompound degradation activity in the synthesized silica hybrid biomaterials
by entrapment, chemical binding, and adsorption. 相似文献
172.
Violeta Yeguas Gloria Inés Cárdenas-Jirón María Isabel Menéndez Ramón López 《Journal of mathematical chemistry》2010,48(1):137-144
The B3LYP density functional theory methodology in conjunction with the 6-31G(d,p) basis set has been used to characterize
triply N-confused meso-tetraphenylporphyrins. According to our computations, there is no a direct correlation between stability and aromaticity
as already found for non-substituted confused porphyrins. The inclusion of these substituents in the calculations provokes
a decrease of the planarity and aromaticity of these macrocycles along with a notable rise of their relative stability with
respect to the non-substituted case. Steric repulsions, both among phenyl rings and β atoms in the pyrrolic rings, and among H atoms in the core of the macrocycles, dominate over aromaticity in the establishment
of the most stable conformation of each isomer. 相似文献
173.
174.
J. S. Garitaonandia K. Suzuki J. D. Cashion E. Goikolea M. Insausti F. Plazaola R. Pizarro P. Gorria P. Minguez 《Hyperfine Interactions》2005,165(1-4):161-165
The crystallization of the Fe75Zr25 as-milled amorphous alloy has been studied by Mössbauer spectroscopy. The process begins at around 880 K with the complete and fast crystallization of the amorphous phase into the crystalline α-Fe and Fe2Zr ones but, from around 915 K, there is a sudden phase transformation into the Fe23Zr6 phase, which remains stable after cooling. A fitting for the Mössbauer contribution of the Fe23Zr6 phase, consistent with its crystalline structural features, has been obtained. 相似文献
175.
Joaquim J. Júdice Hanif D. Sherali Isabel M. Ribeiro 《Computational Optimization and Applications》2007,37(2):139-156
In this paper an eigenvalue complementarity problem (EiCP) is studied, which finds its origins in the solution of a contact
problem in mechanics. The EiCP is shown to be equivalent to a Nonlinear Complementarity Problem, a Mathematical Programming
Problem with Complementarity Constraints and a Global Optimization Problem. A finite Reformulation–Linearization Technique
(Rlt)-based tree search algorithm is introduced for processing the EiCP via the lattermost of these formulations. Computational
experience is included to highlight the efficacy of the above formulations and corresponding techniques for the solution of
the EiCP. 相似文献
176.
177.
Reverdito Ana María García Mariano Hernán Salerno Alejandra Locani Oscar Alberto Perillo Isabel Amalia 《平面色谱法杂志一现代薄层色谱法》2007,20(3):227-230
JPC – Journal of Planar Chromatography – Modern TLC - When the components of a reaction mixture cannot be quantified by UV-visible spectrophotometry, because the λmax values of... 相似文献
178.
Isabel Hubard 《Journal of Combinatorial Theory, Series A》2005,111(1):128-136
We prove that self-dual chiral polytopes of odd rank possess a polarity, that is, an involutory duality, and give an example showing this is not true in even ranks. Properties of the extended groups, that is of the groups of automorphisms and dualities, of self-dual chiral polytopes are discussed in detail. 相似文献
179.
Carboxylic‐Acid‐Passivated Metal Oxide Nanocrystals: Ligand Exchange Characteristics of a New Binding Motif
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Jonathan De Roo Dr. Yolanda Justo Katrien De Keukeleere Freya Van den Broeck Prof. Dr. José C. Martins Prof. Dr. Isabel Van Driessche Prof. Dr. Zeger Hens 《Angewandte Chemie (International ed. in English)》2015,54(22):6488-6491
Ligand exchange is central in the processing of inorganic nanocrystals (NCs) and requires understanding of surface chemistry. Studying sterically stabilized HfO2 and ZrO2 NCs using 1H solution NMR and IR spectroscopy as well as elemental analysis, this paper demonstrates the reversible exchange of initial oleic acid ligands for octylamine and self‐adsorption of oleic acid at NC surfaces. Both processes are incompatible with an X‐type binding motif of carboxylic acids as reported for sulfide and selenide NCs. We argue that this behavior stems from the dissociative adsorption of carboxylic acids at the oxide surface. Both proton and carboxylate moieties must be regarded as X‐type ligands yielding a combined X2 binding motif that allows for self‐adsorption and exchange for L‐type ligands. 相似文献
180.
High Sensitive Microsensor Based on Organic‐Inorganic Composite for Two‐Dimensional Mapping of H2O2 by SECM
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Danielle Diniz Justino Isabel Lourenço Torres Rita de Cássia Silva Luz Flavio Santos Damos 《Electroanalysis》2015,27(5):1202-1209
The present work describes the development of a selective, sensitive and stable sensing microsensor for scanning electrochemical microscopy (SECM) to measure H2O2 during electrochemical reduction of oxygen. The microsensor is based on graphene and Poly(3,4‐ethylenedioxythiophene) composite as support to iron (III) hexacyanoferrate (II) (PEDOT/graphene/FeIII4[FeII(CN)6]3 microsensor). The electrochemical properties of the PEDOT/graphene/FeIII4[FeII(CN)6]3 microsensor were investigated by cyclic voltammetry (CV) and scanning electrochemical microscopy (SECM). The PEDOT/graphene/FeIII4[FeII(CN)6]3 microsensor showed an excellent electrocatalytic activity toward hydrogen peroxide (H2O2) reduction with a diminution of the overpotential of about 500 mV in comparison to the process at a bare gold microelectrode. The microsensor presented excellent performance for two dimensional mapping of H2O2 by SECM in 0.1 mol L?1 phosphate buffer solution (pH 7.0). Under optimized conditions, a linear response range from 1 up to 1000 µmol L?1 was obtained with a sensitivity of 0.08 nA L µmol?1 and limit of detection of 0.5 µmol L?1. 相似文献