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41.
Ae Ran Lim 《Applied magnetic resonance》2014,45(1):9-17
To clarify the nature of microscopic structural changes of N(CH3)4CdCl3 at high temperatures, the nuclear magnetic resonance (NMR) spectra of the protons and carbons in N(CH3)4CdCl3 were measured. NMR studies of the 1H and 13C spin–lattice relaxation time, T 1ρ, in the rotating frame were also performed. No changes in the T 1ρ of 1H and 13C associated with the N(CH3)4 groups were observed at the high-temperature transition from phase I to phase I′. However, the 14N NMR spectra reflected changes in the structural geometry during the transition to phase I′, indicating that this transition is driven by N(CH3)4. 相似文献
42.
Yongdo Lim 《Mathematische Annalen》2001,319(3):457-468
Let V be a Euclidean Jordan algebra, and let be the corresponding symmetric cone. The geometric mean of two elements a and b in is defined as a unique solution, which belongs to of the quadratic equation where P is the quadratic representation of V. In this paper, we show that for any a in the sequence of iterate of the function defined by converges to a. As applications, we obtain that the geometric mean of can be represented as a limit of successive iteration of arithmetic means and harmonic means, and we derive the L?wner-Heinz
inequality on the symmetric cone Furthermore, we obtain a formula which leads a Golden-Thompson type inequality for the spectral norm on V.
Received October 5, 1999 / Revised March 6, 2000 / Published online October 30, 2000 相似文献
43.
We consider an integrated problem of plant location and capacity planning for components procurement in knockdown production systems. The problem is that of determining the schedule of opening components manufacturing plants, plans for acquisition of capacities in opened components manufacturing plants, and plans for components procurement in final assembly plants with the objective of minimizing the sum of fixed costs for opening plants, acquisition and operation costs of facilities, and delivery and subcontracting costs of components. The problem is formulated as a mixed integer linear program and solved by a two-stage solution procedure. In the solution procedure, the problem is decomposed into two tractable subproblems and these subproblems are solved sequentially. In the first stage, a dynamic plant location problem is solved using a cut and branch algorithm based on Gomory cuts, while a multiperiod capacity planning problem is solved in the second stage by a heuristic algorithm that uses a cut and branch algorithm and a variable reduction scheme. The solution procedure is tested on problems of a practical size and results show that the procedure gives reasonably good solutions. 相似文献
44.
Chang Sung Lim 《Journal of luminescence》2012,132(7):1774-1780
MMoO4 (M=Ca, Ba) particles were synthesized by a metathetic reaction in ethylene glycol assisted by cyclic microwave irradiation followed by further heat-treatment. The MMoO4 (M=Ca, Ba) particles were well crystallized after heat-treatment at 400–600 °C for 3 h. The microstructures exhibited fine morphologies with sizes of 0.5–1 μm and 1.5–2 μm for the CaMoO4 and BaMoO4 particles, respectively. The synthesized MMoO4 (M=Ca, Ba) particles were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy and transmission electron microscopy. The optical properties were examined by photoluminescence emission and Raman spectroscopy. 相似文献
45.
Ariel Carreño-Montero Luis A. Maldonado María Isabel Chávez Simón Hernández-Ortega Guillermo Delgado 《Tetrahedron letters》2019,60(48):151282
The synthesis of ethyl (2′-hydroxy-4′,5′-methylendioxophenyl)acetate, a fragment of the antihyperglycemic natural coumarin subcoriacin, is reported. We found an expeditious route to the title compound in five steps. Final metal catalyzed acid ethanolysis of the vinylic 1,1-methylthio methylsulfoxide derivative afforded the required aryl acetic ester, but in the absence of metal catalyst, an unexpected Pummerer rearrangement produced the 2,3-dimethylthiofuran derivative as the major product. This last result provides an alternative entry to 2,3-dimethlythiobenzofurans. 相似文献
46.
Chromatographia - Optimal derivatization conditions were established for the simultaneous determination of 12 aliphatic saturated aldehydes, 8 aliphatic saturated ketones, 4 cyclic ketones, 3... 相似文献
47.
K. C. Nicolaou Phil S. Baran Rolf Jautelat Yun He Kin Chiu Fong Ha‐Soon Choi Won Hyung Yoon Yong‐Li Zhong 《Angewandte Chemie (International ed. in English)》1999,38(4):549-552
A seven‐step cascade reaction —in which selective mesylation, epoxide formation, epoxide lysis, cyclization, reiterative oxidation, and nitrogen–oxygen exchange occur sequentially—facilitates the construction of the maleic anhydride moiety of CP molecules 1 and 2 (>93% yield per step). Unstable intermediates of this reaction sequence were detected, providing evidence for the proposed mechanism and resulting in the discovery of a new chemical entity. 相似文献
48.
Sala X Poater A von Zelewsky A Parella T Fontrodona X Romero I Solà M Rodríguez M Llobet A 《Inorganic chemistry》2008,47(18):8016-8024
A new set of Ru-Cl complexes containing either the pinene[5,6]bpea ligand (L1) or the C3 symmetric pinene[4,5]tpmOMe (L2) tridentate ligand in combination with the bidentate (B) 2,2'-bipyridine (bpy) or 1,2-diphenylphosphinoethane (dppe) with general formula [RuCl(L1 or L2)(B)](+) have been prepared and thoroughly characterized. In the solid state, X-ray diffraction analysis techniques have been used. In solution, cyclic voltammetry (CV) and 1D and 2D NMR spectroscopy have been employed. DFT calculations have been also performed on these complexes and their achiral analogues previously reported in our group, to interpret and complement experimental results. Whereas isomerically pure complexes ([Ru(II)Cl(L2)(bpy)](BF4), 5 and [Ru(II)Cl(L2)(dppe)](BF4), 6) are obtained when starting from the highly symmetric [Ru(III)Cl3(L2)], 2, isomeric mixtures of cis, fac-[Ru(II)Cl(L1)(bpy)](BF4) (3b/3b'), trans,fac- (3a) and up/down,mer- (3c, 3d) isomers are formed when bpy is added to the less symmetric [Ru(III)Cl3(L1)], 1, in contrast to the case of the bulky dppe ligand that, upon coordination to 1, leads to the trans,fac-[Ru(II)Cl(L1)(dppe)](BF4) (4a) complex as a sole isomer due to steric factors. 相似文献
49.
Yong‐beom Lim Dr. Myongsoo Lee Prof. 《Angewandte Chemie (International ed. in English)》2009,48(19):3394-3396
Available in small print : Block copolymer lithography has great potential for reducing the size and fabrication time of integrated circuits. Hydrogen‐bonding‐mediated molecular recognition in self‐assembly processes can be used to produce highly ordered square arrays of block copolymers on the surface of a silicon substrate (see picture).
50.
A. V. M. Chandramalar Y. Y. Lim Y. K. Leong 《Colloids and surfaces. A, Physicochemical and engineering aspects》1999,160(3):49-205
The effects of cis- and trans-1,2-, trans-1,4-cyclohexanedicarboxylic acid, 95% cis-1,3,5-cyclohexane tricarboxylic acid and cis-1,2,3,4,5,6-cyclohexanehexacarboxylic acid on the yield stress–pH behaviour of concentrated ZrO2 dispersions are reported. Adsorbed cis-1,2,3,4,5,6-cyclohexanehexacarboxylic acid imparts predominantly steric interactions. It forms a steric barrier keeping the interacting particles apart. Adsorbed cis- and trans-1,2 increase the maximum yield stress and this was attributed to a hydrophobic force resulting from the part of the cyclohexane ring sticking out into the solution which is devoid of charged or hydrophilic group. Adsorbed trans-1,4 increases the maximum yield stress by at least threefold and its configuration favours strong bridging interaction with an adjacent particle. Predominantly, cis-1,3,5 also increases the maximum yield stress but only by 60% at the same additive concentration. This was attributed to a smaller degree of bridging. 相似文献