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排序方式: 共有144条查询结果,搜索用时 46 毫秒
31.
This paper employed the principle of undetermined coefficients and Bernoulli sub-ODE methods to acquire the topological, non-topological, periodic wave and algebraic solutions of the coupled generalized Schrödinger–Boussinesq system (CGSBs). The concept of Lie point symmetry is applied to derive the point symmetries of the CSGE. The problem on nonlinear self-adjointness of the CSGE has not been solved in previous time. In the present paper, we solve this problem and find an explicit form of the differential substitution providing the nonlinear self-adjointness. Then we use this fact to construct a set of conserved vectors using the classical symmetries admitted by the equation and the general conservation laws (Cls) theorem presented by Ibragimov. Numerical simulation of the obtained results are analyzed with interesting figures showing the physical meaning of the solutions. 相似文献
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The conducting polymer electrolyte films consisting of polyacrylonitrile (PAN) as the host polymer, lithium triflate (LiCF3SO3) and sodium triflate (NaCF3SO3) as inorganic salts were prepared by the solution-cast technique. The pure PAN film was prepared as a reference. The ionic
conductivity for the films is characterized using impedance spectroscopy. The room temperature conductivity for the PAN + 26 wt.%
LiCF3SO3 film and the PAN + 24 wt.% NaCF3SO3 film is 3.04 × 10−4 S cm−1 and 7.13 × 10−4 S cm−1, respectively. XRD studies show that the complexation that has occurred in the PAN containing salt films and complexes formed
are amorphous. The FTIR spectra results confirmed the complexation has taken place between the salt and the polymer. These
results correspond with surface morphology images obtained from SEM analysis. The conductivity–temperature dependence of the
highest conducting film from PAN + LiCF3SO3 and PAN + NaCF3SO3 systems follows Arrhenius equation in the temperature range of 303 to 353 K. The PAN containing 24 wt.% LiCF3SO3 film has a higher ionic conductivity and lower activation energy compared to the PAN containing 26 wt.%LiCF3SO3 film. These results can be explained based on the Lewis acidity of the alkali ions, i.e., the interaction between Li+ ion and the nitrogen atom of PAN is stronger than that of Na+ ion. 相似文献
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This paper describes the preparation of and experimentation undertaken by heterogeneous chitosan membrane as ion selective electrode for glutamate ion. The linearity response was obtained in the range of 1.0 × 10−5 to 1.0 × 10−1 M with a detection limit of 1.0 × 10−6 M. The performance of the electrode was found in the pH range of 4.0-8.0 at temperature 25 ± 3 °C. The response time was at 5-35 s and was useful for a period of more than 4 months. The selectivity values towards some anions indicates good selectivity over a number of interfering anions. No significant improvement of membrane performance over additional of plasticizers such as 2-NPOE, BEHA and DOPP. The electrodes gave sufficient Nernstian responses with the exception of membrane with 2-NPOE. 相似文献
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Jaskaran S. Kang David A. Dunmur Christopher J. Booth John W. Goodby Kenneth J. Toyne Isa Nishiyama 《Liquid crystals》1995,19(3):379-386
Optical rotation and circular dichroism measurements performed in the pretransitional isotropic region above the chiral smectic phases TGBA*, TGBC*, S*C, and S*A exhibited by 1-alkylalkyl 4'-(4'-n-alkoxyphenylpropioloyloxy)biphenyl-4-carboxylates are reported. These results revealed a high degree of increasing chiral ordering on cooling in the isotropic phase, particularly in the temperature region where a broad DSC peak appears. However, the behaviour of the pretransitional optical activity was unlike that commonly observed for chiral nematic or blue phase compounds and did not follow a simple Landau-de Gennes temperature dependence. Characteristic features of the pretransitional optical activity may aid in understanding the local structure of chiral smectic phases. Electric fields did not seem to influence the results significantly, but strong electric field-induced optical rotation behaviour was demonstrated for a mixture constituted of the laterally fluorinated propiolate ester component and a nematic with a large positive dielectric anisotropy. These field-induced results could be fitted to expressions from the existing theory of pretransitional optical activity. Circular dichroism studies at low temperatures were performed for two compounds in dilute solution and were found to exhibit very large changes in their extinction coefficient at wavelengths in the ultraviolet region, which may indicate strong chiral interactions even in dilute isotropic solutions of these materials. 相似文献