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101.
Arad Lang Sylwia Mijowska Iryna Polishchuk Simona Fermani Giuseppe Falini Alexander Katsman Frédéric Marin Boaz Pokroy 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(70):16860-16868
Carbohydrates, along with proteins and peptides, are known to represent a major class of biomacromolecules involved in calcium carbonate biomineralization. However, in spite of multiple physical and biochemical characterizations, the explicit role of saccharide macromolecules (long chains of carbohydrate molecules) in mineral deposition is not yet understood. In this study, we investigated the influence of two common acidic monosaccharides (MSs), the two simplest forms of acidic carbohydrates, namely glucuronic and galacturonic acids, on the formation of calcite crystals in vitro. We show here that the size, morphology, and microstructure of calcite crystals are altered when they are grown in the presence of these MSs. More importantly, these MSs were found to become incorporated into the calcite crystalline lattice and induce anisotropic lattice distortions, a phenomenon widely studied for other biomolecules related to CaCO3 biomineralization, but never before reported in the case of single MSs. Changes in the calcite lattice induced by MSs incorporation were precisely determined by high-resolution synchrotron powder X-ray diffraction. We believe that the results of this research may deepen our understanding of the interaction of saccharide polymers with an inorganic host and shed light on the implications of carbohydrates for biomineralization processes. 相似文献
102.
Shum Andrew D. Liu Christopher P. Lim Wei Han Parkinson Dilworth Y. Zenyuk Iryna V. 《Transport in Porous Media》2022,144(3):715-737
Transport in Porous Media - X-ray computed tomography (CT) is increasingly used to characterize the morphology of water distribution in gas diffusion layers (GDLs) for polymer electrolyte fuel cell... 相似文献
103.
We explore differences between canonical and grand canonical ensembles of 500–2000 free electrons confined in a spherical well with a radius from 1.2 to 2 nm. The averaged occupation numbers of the electronic energy levels and their variances are calculated. For isolated Ag and Au particles, the sum of the variances of all occupation numbers differs from the corresponding bulk-metal value by a factor of 0.005 to 2. 相似文献
104.
Eugen P. Koval’chuk Oleksandr V. Reshetnyak Orest B. Pereviznyk Iryna E. Marchuk Vasyl Ya. Smetanets’kyj Jerzy B?a?ejowski 《Central European Journal of Chemistry》2010,8(3):652-661
The reaction of metals and glassy carbon with benzenediazonium tetrafluoroborate (BDFB) in aprotic solvents has been studied.
During contact of Pt, Au, Ag, Pd, or V with glassy carbon in concentrated diazonium salt solution no change of color was observed.
For Al, Ca, Cr, Cu, Fe, Ga, In, Mg, Li, Na, or Zn the process was accompanied by a rapid solution color change, rapid N2 release and the loss of metal sample mass. The copper metal ionization-dissolution was studied by ultraviolet and visible
absorption spectroscopy, along with gravimetric and volumetric measurements. A dissolution mechanism was proposed based on
kinetic, infrared, and X-ray diffraction data. The 432 nm absorption band appearing after Cu-BDFB reaction indicates formation
of the mixed complex [Cu(N2C6H5·(N≡C-CH3)3]+ where the copper atom is covalently bonded to the azophenyl radical and coordinated to acetonitrile (ACN). This complex is
thermodynamically unstable and decomposes slowly to a colorless crystalline and a black amorphous phase. The crystalline phase
was identified as [Cu(NC-CH3)4]BF4. The amorphous phase is a mixture of products formed by azophenyl and phenyl radical condensation.
相似文献
105.
Domasevitch KV Solntsev PV Krautscheid H Zhylenko IS Rusanov EB Chernega AN 《Chemical communications (Cambridge, England)》2012,48(47):5847-5849
Domino cyclization of ketoenols and hydrazine leads to a series of polycondensed pyridazines, which reveal potential as rigid N-donor multidentate ligands for supramolecular synthesis of open coordination polymers. 相似文献
106.
107.
Philip C. Andrews Iryna Nuzhnaya Nafty Vanderhoek 《Journal of organometallic chemistry》2006,691(16):3426-3433
The important role of supporting solvent in transmetallation reactions involving Grignard reagents is highlighted in the formation and crystallisation of the Group 13 ‘ate’ species, [Mg3Br3Cl2(Et2O)6][GaPh2Br2] (1), [Mg3Br5(Et2O)6][InPh2Br2] (2), [MgBr(THF)5][GaPh3Br] (3), [MgBr(THF)5][InPh3Br] (4), [Mg(THF)6][GaPh2Br2]2 (5) obtained by reaction of PhMgBr with gallium and indium halides. The compounds have been characterised by 1H NMR, elemental analyses, and single-crystal X-ray diffraction. 相似文献
108.
Journal of Thermal Analysis and Calorimetry - Citrate precursors of copper, nickel and cobalt oxides, namely Cu(C6H7O7)2·5H2O, Ni(C6H7O7)2·2.5H2O and CoC6H6O7·6H2O, have been... 相似文献
109.
We solve the Cauchy problem for the Korteweg-de Vries equation with steplike quasi-periodic, finite-gap initial conditions
under the assumption that the perturbations have a given number of finite derivatives with finite moments. 相似文献
110.
Let 𝒩(∞,R) be the Lie algebra of infinite strictly upper triangular matrices over a commutative ring R. We show that every derivation of 𝒩(∞,R) is a sum of diagonal and inner derivations. 相似文献