Femtosecond study of surface structure and composition and time-resolved spectroscopy in metals

Surface structuring and compositioning in aluminum alloy 2024-T3 were demonstrated using a femtosecond pulse laser. Surface nanostructuring was developed as a function of laser parameters and the surface micrographs of the scanning electron microscopy were characterized as a function of incident laser fluence. Surface compositioning was performed by selectively removing the elements on the surface of the sample. Femtosecond studies of highly excited electrons were performed by a pump–probe technique, and the thermalization time was found to be in a range of 1.5–3 ps, increasing with incident fluence. The time-resolved measurement is well matched to the numerical calculation. Received: 6 September 2001 / Accepted: 18 July 2002 / Published online: 25 October 2002 RID="*" ID="*"Corresponding author. Fax: +1-405/744-6811, E-mail: dou@okstate.edu     

Unprecedented syndioselectivity and syndiotactic polyolefin melting temperature: polypropylene and poly(4-methyl-1-pentene) from a highly active, sterically expanded eta1-fluorenyl-eta1-amido zirconium complex

The structurally unique, sterically expanded eta1-fluorenyl-eta1-amido single-site precatalyst, Me2Si(eta1-N-tBu)(eta1-C29H36)ZrCl2.OEt2 (3), upon activation with methylaluminoxane (MAO), is remarkably active and constitutes the most syndioselective alpha-olefin polymerization catalyst system yet reported. 3/MAO affords as-prepared syndiotactic polypropylene with [rrrr] > 99% and unprecedented melting temperatures for the unannealed (165 degrees C) and annealed (174 degrees C) polymers. The activity of this system is 4 times that of the prototypical syndioselective catalyst Me2C(eta5-C5H4)(eta5-C13H8)ZrCl2/MAO. The high activity and syndioselectivity of 3/MAO can be extended to the production of syndiotactic poly(4-methyl-1-pentene) with a record melting temperature of 215 degrees C and [rrrr] = 97%.     

Demonstration of a portable device for predicting vehicle tractive performance in snow

This workshop study program which was sponsored by the ISTVS Snow Mechanics Committee examined the problems of snow traction and methods of predicting vehicle mobility on snow. This study presents one aspect of the field prediction problem where a portable, hand-held instruments is used and prescribed by requirements for simplicity, portability and facility.     

Mode coupling theory of hydrodynamics and steady state systems

We construct a formal mode coupling theory for hydrodynamic systems which includes contributions from all powers of the hydrodynamic variables. This theory is applied to nonequilibrium steady state systems. A generalization of the local equilibrium distribution is used to describe the nonequilibrium state. This distribution independently constrains all moments of the hydrodynamic variables. The infinite hierarchy of equations for the moments of the hydrodynamic variables is truncated using an inverse system size expansion. Explicit results are obtained for the time correlation functions of fluids with a linear temperature gradient or a linear shear. These results agree with previous studies of these steady states.     

Transport in two dimensions. II the thermal conductivity coefficient

The study of generalized transport coefficients in two dimensions is continued. In this article, the thermal conductivity coefficient is examined. The Mori formalism is used and the set of variables consists of all finite multilinear products of two collective conserved variables, the energy density and the momentum density. The tensorial symmetry of Euler and dissipative matrix elements is taken into account explicitly. Two simultaneous non-linear integral equations are obtained, the asymptotic solution for which behave in the same manner as the self-diffusion coefficient studied in an earlier paper. However, the coefficient is dependent upon the intermolecular potential. The heat current auto-correlation function decays asymptotically as $\text{[t}\text{In}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{t]}{}^{\mathrm{?1}}$. The asymptotic form for the shear viscosity coefficient is examined briefly and found to be independent of the intermolecular potential. A better approximation for the coefficient of the asymptotic form of the self-diffusion coefficient is presented.     

Transport in two dimensions. III self-diffusion coefficient at low densities

The low density form of the generalized frequency (s) and wavevector (k) dependent self-diffusion coefficient D(k, s) is calculated, from which the low density forms of related quantities, e.g. the velocity autocorrelation function, are derived. Agreement is obtained with the low density kinetic theory results. A closed form expression for D(k, s) valid over a wide range of densities and times is also given, showing consistency between the asymptotic long time results, obtained previously, and the low density kinetic theory results.