A reinvestigation of the “determination” of uranium(VI) and thorium(IV) with dithizone

It has not been possible to repeat any of the observations in a paper describing the determination of traces of uranium(VI) and thorium(IV) via coloured 1:2 complexes with dithizone.     

Transitions of Collective Motions Driven by Phase Resetting

The front cover artwork is provided by Prof. Gao's group. The image shows the motion patterns transition of the active gel group under the step light intensity, which describes the mechanism of a new collective emergence structure. Read the full text of the Research Article at 10.1002/cphc.202300054 .     

Core carbo-mer of an Extended Tetrathiafulvalene: Redox-Controlled Reversible Conversion to a carbo-Benzenic Dication

carbo-Benzene is an aromatic molecule devised by inserting C₂ units within each C−C bond of the benzene molecule. By integrating the corresponding carbo-quinoid core as bridging unit in a π-extended tetrathiafulvalene (exTTF), it is shown that a carbo-benzene ring can be reversibly formed by electrochemical reduction or oxidation. The so-called carbo-exTTF molecule was thus experimentally prepared and studied by UV–visible absorption spectroscopy and cyclic voltammetry, as well as by X-ray crystallography and by scanning tunneling microscopy (STM) on a surface of highly oriented pyrolytic graphite (HOPG). The molecule and its oxidized and reduced forms were subjected to a computational study at the density functional theory (DFT) level, supporting carbo-aromaticity as a driving force for the formation of the dication, radical cation, and radical anion. By allowing co-planarity of the dithiolylidene rings and carbo-quinoidal core, carbo-exTTFs present a promising new class of redox-active systems.