Can the trilinear Higgs self-coupling be measured at future linear colliders?

We assess the possibility of measuring the trilinear self-coupling of the Standard Model Higgs boson at future electron-positron linear colliders with centre-of-mass energies between 500 and 1500 GeV. We consider rather light Higgs scalars, with mass below the threshold, produced in the double Higgs-strahlung channel and decaying via the dominant mode . Assuming ideal vertex tagging of the heavy-quark jets and mass reconstruction of the Z boson produced in association with the Higgs pair, we compare the yield of the above process to those of all irreducible electroweak and strong backgrounds proceeding through a intermediate state. Total cross sections and differential spectra of phenomenological relevance to the selection and analysis of the signal are given and discussed. Received: 20 September 1999 / Published online: 6 March 2000     

Comparison of Electrolytic Conductivity Theories: Performance of Classical and New Theories

Conductivity equations, based on the mean spherical approximation (MSA), haverecently been derived. We compare their performance with that of classicalequations at the level of experimental uncertainty using conductivity data forsome typical electrolyte solutions. For symmetrical electrolytes, the pictureisconsistent showing a better performance for the classical equations. The Leeand Wheaton equation also shows advantages at moderate concentrations. Forunsymmetrical electrolytes, the differences between MSA and classical equationsis larger. There is, however, an inherent inconsistency with the equilibriuminformation, which cannot be resolved at present.     

Anisotropic branching random walks on homogeneous trees

Symmetric branching random walk on a homogeneous tree exhibits a weak survival phase: For parameter values in a certain interval, the population survives forever with positive probability, but, with probability one, eventually vacates every finite subset of the tree. In this phase, particle trails must converge to the geometric boundaryΩ of the tree. The random subset Λ of the boundary consisting of all ends of the tree in which the population survives, called the limit set of the process, is shown to have Hausdorff dimension no larger than one half the Hausdorff dimension of the entire geometric boundary. Moreover, there is strict inequality at the phase separation point between weak and strong survival except when the branching random walk is isotropic. It is further shown that in all cases there is a distinguished probability measure μ supported by Ω such that the Hausdorff dimension of Λ∩Ω_μ, where Ω_μ is the set of μ-generic points of Ω, converges to one half the Hausdorff dimension of Ω_μ at the phase separation point. Exact formulas are obtained for the Hausdorff dimensions of Λ and Λ∩Ω_μ, and it is shown that the log Hausdorff dimension of Λ has critical exponent 1/2 at the phase separation point. Received: 30 June 1998 / Revised version: 10 March 1999     

Vertically aligned Ni/NiO nanocomposites with abundant oxygen deficient hetero-interfaces for enhanced overall water splitting

The design of heterostructured transition metal-based electrocatalysts with controlled composition and interfaces is key to increasing the efficiency of the water electrolysis and the elucidation of reaction mechanisms.In this work,we report the synthesis of well-controlled vertically aligned Ni/NiO nanocomposites consisting of Ni nanoclusters embedded in NiO,which result in highly efficient electrocatalysts for overall water splitting.We show that such a high catalytic efficiency toward both th...     

Organische Nitroverbindungen

Ohne Zusammenfassung     

Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand

The spectroscopic and chemical characterization of a new synthetic non-heme iron(IV)-oxo species [Fe(IV)(O)((Me,H) Pytacn)(S)](2+) (2, (Me,H)Pytacn=1-(2'-pyridylmethyl)-4,7-dimethyl-1,4,7-triazacyclononane, S=CH(3)CN or H(2)O) is described. Complex 2 was prepared by reaction of [Fe(II)(CF(3)SO(3))(2)((Me,H) Pytacn)] (1) with peracetic acid. Complex 2 bears a tetradentate N(4) ligand that leaves two cis sites available for binding an oxo group and a second external ligand but, unlike the related iron(IV)-oxo species with tetradentate ligands, it is remarkably stable at room temperature (t(1/2)>2 h at 288 K). Its ability to exchange the oxygen atom of the oxo ligand with water has been analyzed in detail by means of kinetic studies, and a mechanism is proposed on the basis of DFT calculations. Hydrogen-atom abstraction from C-H bonds and oxygen-atom transfer to sulfides by 2 have also been studied. Despite its thermal stability, 2 proves to be a very powerful oxidant that is capable of breaking the strong C-H bond of cyclohexane (bond dissociation energy=99.3 kcal mol(-1)).     

Step-by-step calculation of all maximum common substructures through a constraint satisfaction based algorithm

In this paper we propose a new algorithm for subgraph isomorphism based on the representation of molecular structures as colored graphs and the representation of these graphs as vectors in n-dimensional spaces. The presented process that obtains all maximum common substructures is based on the solution of a constraint satisfaction problem defined as the common m-dimensional space (m< or =n) in which the vectors representing the matched graphs can be defined.     

Different binding thermodynamics of Ni2+, Cu2+, and Zn2+ to bacitracin A1 determined by capillary electrophoresis

Thermodynamics of the binding of Ni(2+), Cu(2+) and Zn(2+) to bacitracin A(1) was studied by capillary electrophoresis measuring the peptide effective mobility at different pH in the presence of increasing concentration of the three ligands. The affinity follows the order Ni(2+) > Cu(2+) > Zn(2+), with association constant values of (2.3 +/- 0.1)x10(4), (4.9 +/- 0.2)x10(3), and (1.5 +/- 0.1)x10(3) M(-1), respectively. The only model able to rationalize mobility data implies that metal ion binds to the P(0) peptide form. Moreover, mobility values indicated a change of bacitracin A(1) acidic properties on Ni(2+) and Cu(2+) binding, with a shift of the pK(a) of N-terminal Ile-1 from 7.6 to about 5 and of the pK(a) of the delta-amino group of D-Orn-7 from 9.7 to about 7. Even though on Zn(2+) binding a shift of the N-terminal Ile-1 pK(a) was observed, restrictions in the pH range suitable for investigation, due to precipitation phenomena, did not allow establish if the shift of D-Orn-7 lateral chain pK(a) also occurred. Nonetheless, if present, the shift should be limited to the 7.8-9.7 range. Mobility data indicated that the Stokes radius of the complexes is ca. 3 A lower than that of the free peptide. The present results indicate that metal-ion binding to bacitracin A(1) is more complex than previously assumed.