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131.
Peter M. Ireland 《Journal of Electrostatics》2012,70(6):524-531
Triboelectric particle charging features in many industrial processes. Dynamic particle-surface contact is the key charging mechanism in many types of particle tribocharger. Models of dynamic charging have tended to assume that the particle is spherical, but experiments have shown that particle shape can strongly influence the charging behaviour. We review some experimental work, then present a simple two-dimensional model of the dynamic contact charging of an elliptical particle, of varying roundness ratio, with a flat surface. A rich variety of contact modes (sliding, rolling, tumbling) are captured, each producing distinctive charging behaviour. 相似文献
132.
133.
Structural colour is observed in a number of naturally occurring minerals such as labradorite, bornite, hematite and ammolite, in addition to the well-known example of opal, the semi-precious gemstone. The origin of the structural colour is examined for these inorganic systems using electron microscopy to obtain structural information on the nanoscale. The structural colour that is observed in natural inorganic systems can be mimicked in synthetic inorganic systems, as exemplified by the synthetic opals reported herein. These systems exhibit stop bands, i.e. wavelength regions in which visible light cannot propagate, which show a shift in their wavelength location when the angle of the incident light is varied. When light-emitting phosphors and dyes are incorporated into the opal structures, their emission spectra are modified when the stop bands of the opals overlap the emission bands of the light-emitting materials. 相似文献
134.
The novel monomer, π-(2, 4-hexadiene- l-yl acrylate) tricarbonyliron (HATI), has been prepared by two routes. It was homopolymerized and copolymerized with acrylonitrile, vinyl acetate, styrene, and methyl acrylate in benzene solutions. In all cases azobisisobutyronitrile was the initiator. The relative reactivity ratios, where HATI is defined as M1, were determined: r1 = 0.34, r2 = 0.74, M2 = acrylonitrile; r1 = 2.0, r2 = 0.05, M2 = 0.74, M2 = acrylonitrile; r1 = 2.0, r2 = 0.05, M2 = vinyl acetate; r1 = 0.26, r2 = 1.81, M2 = styrene; and r1 = 0.30, r2 = 0.74, M2 = methyl acrylate. The homo-and copolymers had high values of Tg. When polymerizations are carried out at high concentrations, a very high molecular weight tail is observed in HATI hompolymerizations and in HATI-methyl acrylate copolymerizations. The polymers were characterized by IR, gel permeation chromatography, viscosity, and differential scanning calorimetry studies. Finally, thermal decompositions carried out in air resulted in decomposition of the Fe(CO)3 group, producing Fe2O3 as a fine powder. Thermal decomposition under nitrogen (in solution and on solids ground into KBr pellets) resulted in slow destruction of the Fe(CO)3 groups but the resulting polymer mass was insoluble, and the question of what form the iron exists in (Fe metal, oxides, carbides, etc.) has not been answered. 相似文献
135.
Mixtures of methane and olefins (ethylene, propylene, butenes, butadiene, and styrene) have been polymerized over HSO3 F-SbF3 to yield an oily oligomer with a molecular weight ranging from 100 to 700. The NMR spectra of each polymer showed a sharp peak at or near 1.25 &, suggesting the presence of block methylene in the polymer. The formation of block methylene is surprising considering the fact that the polymerization reaction is carbonium ion in nature. A primary cation has been invoked to explain the results. The formation of this primary cation must involve some extraordinary stabilization by some component in the acid. 相似文献
136.
G.W. SWENSON JR 《Journal of sound and vibration》2002,255(3):519-529
A directional microphone system for field recording of sounds in the air often involves a parabolic reflector to focus the sound waves on the microphone (transducer) element. Some deficiencies of such a system are noted with respect to reproduction of spectra. The reflector system, involving as it does a structure comparable to a wavelength in linear dimension, is not susceptible to traditional high- or low-frequency approximate methods of computation. Modern numerical techniques now permit precise calculation of the directional responses of small reflectors of various shapes. One result is a proposal for a very economical and effective system involving a plane reflector. Other baffle shapes are also investigated, which may be of interest in special applications. 相似文献
137.
H Pledger JR. G.-S. Wu T. S. Young T. E. Hogen-esch G. B. Butler 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(9):1297-1307
Graft copolymers of acrylamide and yellow dextrin were prepared using cerium(IV) as initiator. The yellow dextrin had a very broad molecular weight distribution but was fractionated utilizing dialysis and ultrafiltration membranes. Initiator efficiencies were determined using size exclusion chromatography and were found to be between 2.4 and 34%. Initiator efficiency increased with acrylamide concentration at constant cerium (IV) and yellow dextrin concentrations, and decreased with increasing cerium(IV) concentration at constant acrylamide and yellow dextrin concentrations. Plots of acrylamide conversion and intrinsic viscosity vs initial acrylamide concentration at constant yellow dextrin and ceric ion concentrations showed a maximum at about 2.0 M. 相似文献
138.
Peter M. Ireland 《Journal of Electrostatics》2009,67(2-3):462-467
The cumulative triboelectrification of solids by repeated contact and separation is not completely understood. For nominally identical contact, the transferred charge often requires multiple cycles to saturate, and in some cases does not saturate at all. Several explanations have been proposed for this behaviour, but quantitative validation is complicated by the potentially dominant role of separation discharge. This paper presents a new method for controlling or suppressing the discharge, without affecting the initial transferred charge. The phenomenon of separation discharge is described, and its effect on charge accumulation speculated upon. The proposed charge measurement technique is then discussed quantitatively. Lastly, the design and construction of a prototype experimental apparatus are described. 相似文献
139.
140.
This paper is concerned with the construction and analysis ofcompact finite difference approximations to the model linearsource problem (pu')' + qu = f where the functions p,q, and f can have jump discontinuities at a finite number ofpoints. Explicit formulae that give O(h2) O(h3) and O(h4) accuracyare derived, and a procedure for computing three-point schemesof any prescribed order of accuracy is presented. A rigoroustruncation and discretization error analysis is offered. Numericalresults are also given. 相似文献