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51.
Iraj Rezaeian Seyed Hassan Jafari Payam Zahedi Mehdi Ghaffari Shirin Afradian 《先进技术聚合物》2009,20(5):487-492
In this work, ethylene–vinyl acetate (EVA) copolymer foams were prepared and crosslinked by using high‐energy electron beam (e‐beam) radiation (10 MeV). The effect of parameters such as irradiation dose, the contents of foaming agent, radiation activator, and radiation sensitizer on improvement of physical and mechanical properties of the EVA foamed samples were investigated. The foams were obtained through a four‐step process of melt mixing, forming, crosslinking, and foaming. During the melt mixing process EVA was compounded with different amounts of azodicarbonamide (ADCA) as a blowing agent, zinc oxide (ZnO) as a radiation activator, and trimethylol propane‐trimethacrylate (TMPTMA) as a radiation sensitizer. The samples were compression molded into flat sheets at low temperature (110°C) and were then radiation‐crosslinked by 20–80 kGy e‐beam. Finally, the crosslinked samples were converted to foams by a high temperature (210°C) compression molding process. The foamed samples were analyzed in terms of gel content, density, compression molding set, tensile properties, and micro‐structural features. It was found that an increase in absorbed radiation dosage increases crosslink density, elasticity, percentage recovery, tensile strength, and compression properties of the EVA foams. Due to the increased recovery the percentage of compression set was reduced. Similarly increasing the TMPTMA content in the formulation increased the crosslink density and the resulting mechanical properties. Contrary to these findings, addition of ADCA led to the formation of extra gases which in turn reduced the crosslink density, and resulted in the deterioration of the mechanical properties and hence an increase in the compression set. However, addition of ZnO and TMPTMA led to the formation of smaller and more uniform cell size with improved mechanical properties. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
52.
Majid Moghadam Iraj Mohammadpoor‐Baltork Shahram Tangestaninejad Valiollah Mirkhani Ahmad Reza Khosropour S. Abdolmanaf Taghavi 《应用有机金属化学》2011,25(9):687-694
In the present work, the application of electron‐deficient tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate, [VIV(TPP)(OTf)2], in the trimethylsilylation of alcohols and phenols with hexamethydisilazane (HMDS) is reported. This new V(IV) catalyst was used as an efficient catalyst for silylation of not only primary alcohols but also sterically hindered secondary and tertiary alcohols with HMDS. Trimethylsilylation of phenols with HMDS was also performed to afford the desired Trimethylsilyl ethers (TMS) ethers. The chemoselectivity of this method was also investigated. This catalyst can be reused several times without loss of its activity. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
53.
Omid Bagheri Faranak Sadegh Majid Moghadam Shahram Tangestaninejad Valiollah Mirkhani Iraj Mohammadpoor‐Baltork Mahsa Safiri 《应用有机金属化学》2014,28(5):337-346
The tetrakis(4‐N‐methylpyridinium)porphyrinatopalladium(II) iodide, [Pd(TMPyP)]I4, supported on Dowex 50WX8 and Amberlite IR‐120 ion‐exchange resins, was used as heterogeneous, recyclable and active catalyst for the Suzuki–Miyaura and Heck cross‐coupling reactions. These catalysts were applied to coupling of various aryl halides with phenylboronic acid and styrene in Suzuki and Heck reactions, respectively, and the corresponding products were obtained in excellent yields and short reaction times. The catalysts could be recovered easily by simple filtration and reused several times without significant loss of their catalytic activity. The catalysts were characterized by diffuse‐reflectance UV–visible spectroscopy and scanning electron microscopy, and their stability was confirmed by TGA. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
54.
Iraj Mohammadpoor-Baltork Majid Moghadam Shahram Tangestaninejad Valiollah Mirkhani Zohre Eskandari 《Ultrasonics sonochemistry》2010,17(5):857-862
Montmorillonite K-10 and KSF were found to be highly efficient, environmentally friendly and recyclable heterogeneous catalysts for the selective synthesis of a variety of 2-aryl-5,6-dihydro-4H-1,3-oxazines from arylnitriles and 3-amino-1-propanol under ultrasound irradiation. This new methodology provides excellent yields in short reaction times (10–25 min). The reaction work-up is very simple and the catalysts can be easily separated from the reaction mixture and reused several times in subsequent reactions. This catalytic system also exhibits excellent chemoselectivity in the synthesis of mono-oxazines from dinitriles. 相似文献
55.
Maryamalsadat Lajvardi Jafar Moghimi-Rad Iraj Hadi Anwar Gavili Taghi Dallali Isfahani Fatemeh Zabihi Jamshid Sabbaghzadeh 《Journal of magnetism and magnetic materials》2010,322(21):3508-3513
This paper reports an experimental work on the convective heat transfer of ferrofluid flowing through a heated copper tube in the laminar regime in the presence of magnetic field. Significant enhancement on the heat transfer of ferrofluid by applying various orders of magnetic field is observed in this experiment. Also in this experiment, the effect of magnetic nanoparticles concentrations and magnet position have been investigated. The main reason for the enhancement of heat transfer coefficient could be caused due to remarkable changes in thermophysical properties of ferrofluid under the influence of applied magnetic field. 相似文献
56.
Iraj Mohammadpoor-Baltork Majid Moghadam Shahram Tangestaninejad Valiollah Mirkhani Ahmad Reza Khosropour Arsalan Mirjafari 《Monatshefte für Chemie / Chemical Monthly》2010,14(1):1083-1088
Abstract
1-Methylimidazolium hydrogensulfate, [Hmim][HSO4], a Br?nsted acidic room temperature ionic liquid, is used as a catalyst and reaction medium for facile and eco-friendly deprotection of methoxymethyl (MOM) and ethoxymethyl (EOM) ethers to their corresponding alcohols under thermal conditions (Δ) and microwave irradiation (MW). Furthermore, one-pot interconversion to the respective acetates and trimethylsilyl (TMS) ethers was also achieved. 相似文献57.
Iraj Mohammadpoor-Baltork Majid Moghadam Shahram Tangestaninejad Valiolah Mirkhani Arsalan Mirjafari 《Comptes Rendus Chimie》2010,13(12):1468-1473
In the present work, the catalytic activity of 12-tungstophosphoric acid immobilized on [bmim][FeCl4] ionic liquid as a highly efficient and eco-friendly catalytic system for rapid and chemoselective direct conversion of MOM- or EOM-ethers into their corresponding nitriles, bromides and iodides under microwave irradiation is reported. In these reactions, the products are obtained in high yields. The catalyst exhibited remarkable reactivity and was reused several times. 相似文献
58.
Majid Moghadam Shahram Tangestaninejad Valiollah Mirkhani Iraj Mohammadpoor‐Baltork Naghmeh Sadat Mirbagheri 《应用有机金属化学》2010,24(10):708-713
In the present work, highly efficient epoxidation of alkenes catalyzed by Mo(CO)6 supported on multi‐wall carbon nanotubes modified by 2‐aminopyrazine, APyz‐MWCNTs, is reported. The prepared catalyst was characterized by elemental analysis, scanning electron microscopy, FT IR and diffuses reflectance UV–vis spectroscopic methods. This new heterogenized catalysts, [Mo(CO)6@APyz‐MWCNT], was used as a highly efficient catalyst for epoxidation of alkenes with tert‐BuOOH. This robust catalyst was reused several times without loss of its catalytic activity. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
59.
Iraj Mohammadpoor-Baltork Ahmad R. Khosropour 《Monatshefte für Chemie / Chemical Monthly》2002,45(7):189-193
A variety of TMS and THP ethers are efficiently converted to their corresponding acetates and benzoates with acetic and benzoic anhydrides in the presence of catalytic amounts of Bi(III) salts such as BiCl3, Bi(TFA)3, and Bi(OTf)3. The present method is also effective for the selective acetylation and benzoylation of TMS and THP ethers of alcohols in the presence of phenolic ethers. 相似文献
60.
Various types of 2-imidazolines are efficiently oxidized to the corresponding imidazoles using potassium permanganate supported on silica gel under mild conditions at room temperature. 2-Alkylimidazolines are selectively converted to their corresponding imidazoles in the presence of 2-arylimidazolines. Chemoselective oxidation of 2-imidazolines in the presence of other oxidizable functional groups such as sulfide, ether, aldehyde, acetal, and THP ether was also achieved by this reagent system. 相似文献