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611.
Yamanaka T 《Physical review letters》2008,101(13):136101
Active sites for a thermally induced bimolecular two-step catalytic reaction (O2-->2O, O + CO-->CO2) that occurs on a Pt(113)(1 x 2) structure at around 160 K were studied by angular distribution measurements of desorbing product CO2. It was found that the intrinsic activity level of two-atom-wide (001) facets is significantly higher than that of two-atom-wide (111) facets, while the activity of (111) facets was also significant when this reaction was induced by irradiation of 193 nm photons. Possible mechanisms for the difference in activities of the two facets are discussed. 相似文献
612.
Kanai T Sawada T Yamanaka J Kitamura K 《Langmuir : the ACS journal of surfaces and colloids》2005,21(17):7633-7637
We report an elegant method using centrifugal sedimentation for determining the critical particle concentration for colloidal crystallization. A small amount of a dilute suspension of monodispersed particles stored in a flat capillary cell was centrifuged to temporarily generate a nonequilibrium gradient of the particle concentration including a crystalline-noncrystalline phase boundary in the cell. In the recovering process after the centrifugation, the particle concentration of the crystalline phase at the boundary was found to always have the equilibrium value, although the global concentration distribution evolved with time. The critical concentration was determined based on spatially resolved spectrometry. The present method requires only one batch of a suspension of the order of microliters and is applicable up to high concentration regions near the closest packing without the effect of the particle aggregation. 相似文献
613.
Yamanaka K. Nishiwaki Y. Iio K. Kato T. Mitsui T. Tojo T. Atake T. 《Journal of Thermal Analysis and Calorimetry》2002,70(2):371-378
The complex phase transitions involving dielectricity and magnetism on distorted triangular lattice antiferromagnets, "KNiCl3-family" crystals, which have the crystal structures derived from the prototype CsNiCl3, were studied through the heat capacity measurements. These crystals are classified into characteristic three groups from
the viewpoint of magnetic and structural properties clarified so far. The results of the dielectric constant measurement as
a function of temperature are also presented in detail. The present calorimetric study reveaed that the structural successive
phase transitions rather than the magnetic transitions in these crystals are recognized more distinctly as the presence of
specific heat anomalies at the respective phase transition points.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
614.
Zheng J Tanaka KA Sato T Yabuuchi T Kurahashi T Kitagawa Y Kodama R Norimatsu T Yamanaka T 《Physical review letters》2004,92(16):165001
Hot electrons and optical emission are measured from the rear surface of a metallic foil. The spectra of the optical emission in the near infrared region have a sharp spike around the wavelength of the incident laser pulse. The optical emission is ascribed to coherent transition radiation due to microbunching in the hot electron beam. It is found that the optical emission closely correlates with the hot electrons accelerated in resonance absorption. 相似文献
615.
Evdokimov AV Akgun U Alkhazov G Amaro-Reyes J Atamantchouk AG Ayan AS Balatz MY Bondar NF Cooper PS Dauwe LJ Davidenko GV Dersch U Dolgolenko AG Dzyubenko GB Edelstein R Emediato L Endler AM Engelfried J Eschrich I Escobar CO Filimonov IS Garcia FG Gaspero M Giller I Golovtsov VL Gouffon P Gülmez E Kangling H Iori M Jun SY Kaya M Kilmer J Kim VT Kochenda LM Konorov I Kozhevnikov AP Krivshich AG Krüger H Kubantsev MA Kubarovsky VP Kulyavtsev AI Kuropatkin NP Kurshetsov VF Kushnirenko A Kwan S 《Physical review letters》2004,93(24):242001
We report the first observation of a charm-strange meson D(+)(sJ)(2632) at a mass of 2632.5+/-1.7 MeV/c(2) in data from SELEX, the charm hadro-production experiment E781 at Fermilab. This state is seen in two decay modes, D(+)(s)eta and D0K+. In the D(+)(s)eta decay mode we observe a peak with 101 events over a combinatoric background of 54.9 events at a mass of 2635.4+/-3.3 MeV/c(2). There is a corresponding peak of 21 events over a background of 6.9 at 2631.5+/-2.0 MeV/c(2) in the decay mode D0K+. The decay width of this state is <17 MeV/c(2) at 90% confidence level. The relative branching ratio Gamma(D0K+)/Gamma(D(+)(s)eta) is 0.14+/-0.06. The mechanism that keeps this state narrow is unclear. Its decay pattern is also unusual, being dominated by the D(+)(s)eta decay mode. 相似文献
616.
Kanai T Sawada T Yamanaka J Kitamura K 《Journal of the American Chemical Society》2004,126(41):13210-13211
We show that a crystalline-noncrystalline boundary that temporarily appeared in a sediment centrifuged from a relatively dilute colloidal suspension can be regarded to be at a phase equilibrium. On the basis of this, we can determine the critical particle concentration for colloidal crystallization using an extremely small amount of specimen by spatially resolved spectroscopy. 相似文献
617.
Sato K Sekiguchi T Ishihara T Konno T Yamanaka H 《The Journal of organic chemistry》2004,69(15):5041-5047
The reductive coupling reaction of N-methoxy-N-methyl-2-bromo-2,3,3,3-tetrafluoropropanamide (Weinreb amide) with various aldehydes under the influence of the combined reagent, 1.2 equiv each of triphenylphosphine and titanium(IV) isopropoxide, took place smoothly at ambient temperature to give the corresponding alpha-fluoro-alpha-(trifluoromethyl)-beta-hydroxy amides in a highly erythro-selective manner. The high erythro selectivity was also obtained even by employing a combination of triphenylphosphine (1.2 equiv) and a catalytic amount of titanium(IV) isopropoxide. 相似文献
618.
Abouzaid E Alexopoulos T Arenton M Barbosa RF Barker AR Bellantoni L Bellavance A Blucher E Bock GJ Cheu E Coleman R Corcoran MD Cox B Erwin AR Escobar CO Glazov A Golossanov A Gomes RA Gouffon P Hanagaki K Hsiung YB Huang H Jensen DA Kessler R Kotera K LaDue J Ledovskoy A McBride PL Monnier E Nelson KS Nguyen H Niclasen R Ping H Prasad V Qi XR Ramberg EJ Ray RE Ronquest M Santos E Shields J Slater W Smith D Solomey N Swallow EC Toale PA Tschirhart R Velissaris C Wah YW Wang J White HB 《Physical review letters》2005,95(8):081801
The xi0 muon semileptonic decay has been observed for the first time with nine identified events using the KTeV beam line and detector at Fermilab. The decay is normalized to the xi0 beta decay mode and yields a value for the ratio of decay rates gamma(xi0 --> sigma+ mu- nu(mu))/gamma(xi0 --> sigma+ e- nu(e)) of [1.8(-0.5)(+0.7)(stat) +/- 0.2(syst)] x 10(-2). This is in agreement with the SU(3) flavor symmetric quark model. 相似文献
619.
Koichiro Kase Tsutomu Konno Hiroki Yamanaka John T Gupton 《Journal of fluorine chemistry》2003,120(1):33-39
β-Trifluoroethoxy vinamidinium salts 1 reacted smoothly with various types of the carbanions, generated by treatment of ketones, esters, amide and nitriles with LDA, to give the corresponding trifluoroethoxylated multifunctional dienamine derivatives 3 in moderate to good yields. On the other hand, the reaction of 1 with lithium acetylide and other carbanions derived from methyl compounds bearing sulfonyl, sulfinyl, and phosphonyl groups produced the corresponding α,β-unsaturated aldehydes 5 in good yields. 相似文献
620.
Raman scattering spectra from the ac face of thick MgB2 single crystals were measured in zz, xz, and xx polarizations. In zz and xz polarizations a threshold at around 29 cm(-1) forms in the below T(c) continuum but no pair-breaking peak is seen, in contrast to the sharp pair-breaking peak at around 100 cm(-1) in xx polarization. The zz and xz spectra are consistent with Raman scattering from a dirty superconductor while the sharp peak in the xx spectra argues for a clean system. Analysis of the spectra resolves this contradiction, placing the larger and smaller gap magnitudes in the sigma and pi bands and indicating that relatively strong impurity scattering is restricted to the pi bands. 相似文献