全文获取类型
收费全文 | 500篇 |
免费 | 29篇 |
国内免费 | 5篇 |
专业分类
化学 | 333篇 |
晶体学 | 3篇 |
力学 | 10篇 |
数学 | 77篇 |
物理学 | 111篇 |
出版年
2022年 | 12篇 |
2021年 | 19篇 |
2020年 | 7篇 |
2019年 | 12篇 |
2018年 | 11篇 |
2017年 | 12篇 |
2016年 | 18篇 |
2015年 | 18篇 |
2014年 | 18篇 |
2013年 | 43篇 |
2012年 | 27篇 |
2011年 | 40篇 |
2010年 | 23篇 |
2009年 | 21篇 |
2008年 | 34篇 |
2007年 | 27篇 |
2006年 | 16篇 |
2005年 | 18篇 |
2004年 | 17篇 |
2003年 | 18篇 |
2002年 | 21篇 |
2001年 | 9篇 |
2000年 | 11篇 |
1999年 | 10篇 |
1998年 | 12篇 |
1996年 | 4篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 3篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 5篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1948年 | 2篇 |
1947年 | 2篇 |
1943年 | 3篇 |
排序方式: 共有534条查询结果,搜索用时 0 毫秒
41.
采用相对论和非相对论理论模型可描述奇异核的性质 .相对论平均场理论预言了2 6,2 7,2 8P存在一个质子晕 ,而27,28,29S存在两个质子晕 .最近 ,MSU的最新的实验发现了2 6,2 7,2 8P核存在一个质子晕.采用相对论 Hartree- Fock理论研究了 Fock项和矢量介子对奇异核性质的贡献,研究表明交换项和矢量介子对非常丰中子核性质的影响非常不同于对稳定线附近核性质的影响.同时,采用形变的Hartree- Fock- Bogoliubov理论研究了某些轻核同位素链的性质和形变. 相似文献
42.
A simple method is proposed leading to reasonable approximations of the partition function of Morse oscillators in terms of
elementary functions. 相似文献
43.
Bennis and O’Toole [Bennis, W.G., O’Toole, J., 2005. How business schools lost their way. Harvard Business Review 83, 96–104] have recently argued that decision makers need guidance in ‘making decisions in the absence of clear facts’. As such, decision makers must be able to resourcefully use whatever limited information is available and advantageously portray its implications. Based on recently published theory which directly addresses this requirement, this paper demonstrates, through a practical example, how decision makers can make systemic decisions in situations characterized by extremely limited information and, furthermore, what form such decisions can take. Evidence is provided, therefore, that operational research can effectively address what appears to be a gap in management training. 相似文献
44.
45.
William R. Dolbier Jr. Yian Zhai Wei Xu Will Wheelus Florian Dulong Efram Goldberg Ion Ghiviriga Merle A. Battiste 《Journal of fluorine chemistry》2008,129(12):1133-1138
When 4-nitro-AF4 is treated with nucleophiles such as alkoxides and cyanide, a novel ring opening, cyclophane destroying reaction is observed whereby, via an SNAr mechanism, the nucleophile attacks the bridgehead aryl carbon vicinal to the nitro group with subsequent aryl-CF2 bond cleavage. 相似文献
46.
Niculina D. Bogdan Eric Condamine Yvan Ramondenc Ion Grosu 《Tetrahedron letters》2008,49(35):5204-5207
The synthesis, the X-ray, NMR and molecular modeling structure determination of a new orthopara[4.4]cyclophane are reported. The similarity of the π(CO)-π(Ar) driven conformational equilibrium of this compound to the work of an amusement ride machinery is also revealed. 相似文献
47.
A new C2-symmetric chelating di-N-heterocyclic carbene (NHC) ligand is reported. The stable free di-carbene (+/−)[DEAM-BY] (3) forms upon treating the imidazolium salt (+/−)[DEAM-BI][OTf]2 (2) with potassium bis-trimethylsilylamide (where DEAM-BY = trans-9,10-dihydro-9,10-ethanoanthracene-11,12-bis(1-benzyl)imidaz-2-ylidene and DEAM-BI = trans-9,10-dihydro-9,10-ethanoanthracene-11,12-bis(1-benzyl)imidazolium). Metalation reactions of 2 with [Rh(COD)Cl]2 and [Ir(COD)Cl]2 are carried out under mild conditions to produce either mono- or bimetallic complexes. Each compound is characterized by NMR spectroscopy, combustion analysis, and single-crystal X-ray crystallography. 相似文献
48.
The phonon spectrum of the high-pressure simple cubic phase of calcium, in the harmonic approximation, shows imaginary branches that make it mechanically unstable. In this Letter, the phonon spectrum is recalculated by using density-functional theory ab initio methods fully including anharmonic effects up to fourth order at 50 GPa. Considering that the perturbation theory cannot be employed with imaginary harmonic frequencies, a variational procedure based on the Gibbs-Bogoliubov inequality is used to estimate the renormalized phonon frequencies. The results show that strong quantum anharmonic effects make the imaginary phonons become positive even at zero temperature so that the simple cubic phase becomes mechanically stable, as experiments suggest. Moreover, our calculations find a superconducting T(c) in agreement with experiments and predict an anomalous behavior of the specific heat. 相似文献
49.
Here we demonstrate a novel quantitative procedure to pursue statistical studies on the geometric properties of photonic crystals and photonic quasicrystals (PQCs) which consist of separate dielectric particles. The geometric properties are quantified and correlated to the size of the photonic band gap (PBG) for wide permittivity range using three characteristic parameters: shape anisotropy, size distribution, and feature-feature distribution. Our concept brings statistical analysis to the photonic crystal research and offers the possibility to predict the PBG from a morphological analysis. 相似文献
50.
The characteristics of ion beam extraction and focused to a volume as small as possible were investigated with the aid of computer code SIMION 3D version 7. This has been used to evaluate the extraction characteristics (accel-decel system) to generate an ion beam with low beam emittance and high brightness. The simulation process can provide a good study for optimizing the extraction and focusing system of the ion beam without any losses and transported to the required target. Also, a study of a simulation model for the extraction system of the ion source was used to describe the possible plasma boundary curvatures during the ion extraction that may be affected by the change in an extraction potential with a constant plasma density meniscus. 相似文献