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101.
The issue is that of following the path of a Brownian particle by a process of bounded total variation and subject to a reflecting barrier at the origin, in such a way as to minimize expected total cost over a finite horizon. We establish the existence of optimal processes and the dynamic programming equations for this question, and show (by purely probabilistic arguments) its relation to an appropriatefamily of optimal stopping problems with absorption at the origin.Work carried out during a visit by the second author at the University Pierre et Marie Curie (Paris VI), and at INRIA (Institut National de Recherche en Informatique et en Automatique). The hospitality of these institutions is gratefully acknowledged.Research supported in part by the U.S. Air Force Office of Scientific Research, under grant AFOSR-86-0203. 相似文献
102.
Roger Hunston Ioannis P. Gerothanassis Jürgen Lauterwein 《Magnetic resonance in chemistry : MRC》1982,18(2):120-121
The 17O NMR chemical shifts of five enriched amino acids have been measured under strictly controlled conditions of concentration, ionic strength, pH and temperature. The α, β and α, γ carboxyl resonances of aspartic and glutamic acid, respectively, have been resolved. Line widths were examined as a function of solution viscosity. 相似文献
103.
104.
Ioannis N. Lykakis 《Tetrahedron letters》2005,46(45):7835-7839
The homogeneous decatungstate catalyzed photooxygenation of 1,1-diphenylethane and 9-methyl-9H-fluorene has been studied mechanistically. The primary and β-secondary kinetic isotope effects provide strong evidence for a stepwise mechanism, with a hydrogen atom abstraction in the rate-determining step. 相似文献
105.
LC-NMR coupling technology: recent advancements and applications in natural products analysis 总被引:4,自引:0,他引:4
Exarchou V Krucker M van Beek TA Vervoort J Gerothanassis IP Albert K 《Magnetic resonance in chemistry : MRC》2005,43(9):681-687
An overview of recent advances in nuclear magnetic resonance (NMR) coupled with separation technologies and their application in natural product analysis is given and discussed. The different modes of LC-NMR operation are described, as well as how technical improvements assist in establishing LC-NMR as an important tool in the analysis of plant-derived compounds. On-flow, stopped-flow and loop-storage procedures are mentioned, together with the new LC-SPE-NMR configuration. The implementation of mass spectrometry in LC-NMR is also useful on account of the molecular weight and fragmentation information that it provides, especially when new plant species are studied. Cryogenic technology and capillary LC-NMR are the other important recent developments. Since the plant kingdom is endless in producing potential drug candidates, development and optimization of LC-NMR techniques convert the study of natural products to a less-time-consuming task, speeding up identification. 相似文献
106.
107.
We present a methodology for the investigation of dislocation energetics in segregated alloys based on Monte Carlo simulations which equilibrate the topology and composition of the dislocation core and its surroundings. An environment-dependent partitioning of the system total energy into atomic contributions allows us to link the atomistic picture to continuum elasticity theory. The method is applied to extract core energies and radii of 60 degrees glide dislocations in segregated SiGe alloys which are inaccessible by other methods. 相似文献
108.
We predict an anomalous bias dependence of the spin transfer torque parallel to the interface, Tparallel, in magnetic tunnel junctions, which can be selectively tuned by the exchange splitting. It may exhibit a sign reversal without a corresponding sign reversal of the bias or even a quadratic bias dependence. We demonstrate that the underlying mechanism is the interplay of spin currents for the ferromagnetic (antiferromagnetic) configurations, which vary linearly (quadratically) with bias, respectively, due to the symmetric (asymmetric) nature of the barrier. The spin transfer torque perpendicular to interface exhibits a quadratic bias dependence. 相似文献
109.
Ioannis Emmanouil 《Mathematische Zeitschrift》2006,253(4):709-733
Let G be a group and E an idempotent matrix with entries in the group algebra CG. In this paper, we consider the embedding of CG into the von Neumann algebra G and use the center-valued trace on the latter, in order to obtain some information about the coefficients of the Hattori-Stallings
rank of E. Our results generalize the inequalities obtained previously by Kaplansky [11], Passi, Passmann, Luthar and Alexander [1,10,12],
while providing at the same time a unified and coherent presentation of these, via the notion of moments that are associated
with E. 相似文献
110.
The location of the membrane lipid bilayer relative to a transmembrane protein structure is important in protein engineering. Since it is not present on the determined structures, it is essential to automatically define the membrane embedded protein region in order to test mutation effects or to design potential drugs. beta-Barrel transmembrane proteins, present in nature as outer membrane proteins (OMPs), comprise one of the two transmembrane protein fold classes. Lately, the number of their determined structures has increased and this enables the implementation and evaluation of structure-based annotation methods and their more comprehensive study. In this paper, we propose two new algorithms for (i) the geometric modelling of beta-barrels and (ii) the detection of the transmembrane region of a beta-barrel transmembrane protein. The geometric modelling algorithm combines a non-linear least square minimization method and a genetic algorithm in order to find the characteristics (axis, radius) of a shape with axial symmetry which best models a beta-barrel. The transmembrane region is detected by profiling the external residues of the beta-barrel along its axis in terms of hydrophobicity and existence of aromatic and charged residues. TbB-Tool implements these algorithms and is available in . A non-redundant set of 22 OMPs is used in order to evaluate the algorithms implemented and the results are very satisfying. In addition, we quantify the abundance of all amino acids and the average hydrophobicity for external and internal beta-stranded residues along the axis of beta-barrel, thus confirming and extending other researchers' results. 相似文献