N1...N3 hydrogen bonds of A:U base pairs of RNA are stronger than those of A:T base pairs of DNA

Trans-hydrogen-bond deuterium isotope effects of Watson-Crick A:U and A:T base pairs of 10 homologous RNA and DNA duplexes are compared. The isotope effect at 13C2 of adenosine residues due to deuterium/protium substitution at the imino H3 site, 2hDelta13C2, is larger in RNA than in DNA. The virtually consistent larger isotope effects in RNA suggest that the N1...N3 hydrogen bonds of A:U base pairs of RNA are stronger than those of the A:T base pairs of DNA.     

On the role of organic adlayers in the anomalous water sorptivity of Lépine limestone

Sorptivity data are reported for the capillary absorption of water, ethanol, propan-2-ol, and n-heptane by the calcitic limestone Lépine (Lavoux à grain). The data confirm that the water sorptivity is anomalously low, an indication of partial wetting by water. Results are expressed in terms of a wetting index. The water sorptivity increases after heat treatment and chemical oxidation by hydrogen peroxide bleaching, while the sorptivity with organic liquids is unchanged. These treatments, therefore, increase the water wetting index. The results provide strong evidence that the presence of a natural organic adlayer is responsible for the anomalously low water sorptivity of this particular limestone. This natural water repellency effect may be exploited in developing chemical treatments to modify the water transport properties of stone.     

Isolation and characterization of kallosin A,a novel rearranged pseudopterane diterpenoid from the Caribbean sea plume Pseudopterogorgia kallos (Bielschowsky)

The Caribbean alcyonacean Pseudopterogorgia kallos is shown to contain a novel rearranged pseudopterane diterpene, kallosin A (1), possessing several unusual structural features. In addition to having two distinct 2(3H)- and 2(5H)-furanone moieties, kallosin A is based on a new carbon skeleton. The structural assignment of 1 was based mainly on 1D and 2D NMR spectral data and was further supported by accurate mass measurement and single-crystal X-ray diffraction analysis.     

Expeditious copper-catalyzed conjugate 1,4-addition of bromo[2-(1,3-dioxolan-2-yl)ethyl]magnesium to alpha,beta-cycloalkenones and subsequent transformations

Expeditious CuI-catalyzed conjugate 1,4-addition of bromo[2-(1,3-dioxolan-2-yl)ethyl]magnesium to the five-, six-, seven-, and eight-membered alpha,beta-cycloalkenones is described. The reaction times are decreased dramatically compared to CuBr-(CH(3))(2)S catalysis. The resulting ketoacetals were subsequently cyclized to bicyclic beta-hydroxy ketones and alpha,beta-enones, followed by further transformations.     

Traces and idempotents in group algebras

Let G be a group and E an idempotent matrix with entries in the complex group algebra C G. In this paper, we study arithmetic properties of the coefficients r _E (g), gG, of the Hattori-Stallings rank r _E of E. Bass proved in [2] that the r _E (g)s are algebraic numbers. Following Zaleskii, we proceed by reduction to positive characteristic and give an alternative proof of that assertion, while obtaining at the same time an upper bound for the degree of the minimum polynomial of r _E (g) over Q.     

Finitary Spacetime Sheaves of Quantum Causal Sets: Curving Quantum Causality

A locally finite, causal, and quantal substitute for a locally Minkowskian principal fiber bundle of modules of Cartan differential forms over a bounded region X of a curved C -smooth spacetime manifold M with structure group G that of orthochronous Lorentz transformations L ⁺ := SO(1,3), is presented. is usually regarded as the kinematical structure of classical Lorentzian gravity when the latter is viewed as a Yang-Mills type of gauge theory of a sl(2, {})-valued connection 1-form . The mathematical structure employed to model this replacement of is a principal finitary spacetime sheaf of quantum causal sets with structure group G _n, which is a finitary version of the continuous group G of local symmetries of General Relativity, and a finitary Lie algebra g _n-valued connection 1-form on it, which is a section of its subsheaf . is physically interpreted as the dynamical field of a locally finite quantum causality, whereas its associated curvature as some sort of finitary and causal Lorentzian quantum gravity.     

Spaces with Dual Order-Isomorphic to ℓ1

We establish that an ordered Banach space is order-isomorphic to c₀ if and only if it is a -Dedekind complete vector lattice and its norm dual is order-isomorphic to ₁.