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231.
Rodica Olar Gina Vasile Scaeteanu Ioana Dorina Vlaicu Luminita Marutescu Mihaela Badea 《Journal of Thermal Analysis and Calorimetry》2014,118(2):1195-1202
Three new coordinative compounds of the type [Co(en)2CO3]·0.75H2O (1) and [M(en)2(H2O)2]CO3 ((2) M:Ni, (3) M:Cu; en: ethylenediamine) were synthesized and characterized. The IR and UV–Vis spectral data indicate that ethylenediamine acts as chelate, while carbonate ions act as bidentate chelate ligand for (1)/counter ion for (2) and (3) generating complexes with octahedral stereochemistry. The thermal behavior provided confirmation of the complexes composition, as well as the number and the nature of water molecules and the intervals of thermal stability. The biological assays revealed a good activity against Enterococcus faecium for copper complex. 相似文献
232.
Mihaela Alexandra Bogdan Simona Bungau Delia Mirela Tit Dana Carmen Zaha Aurelia Cristina Nechifor Tapan Behl Dorina Chambre Andreea Ioana Lupitu Lucian Copolovici Dana Maria Copolovici 《Molecules (Basel, Switzerland)》2021,26(14)
Chemical composition, antioxidant capacity, and antimicrobial activity of lavender essential oils (LEOs) extracted from three different varieties of Lavandula angustifolia Mill. (1-Moldoveanca 4, 2-Vis magic 10, and 3-Alba 7) have been determined. These plants previously patented in the Republic of Moldova were cultivated in an organic agriculture system in the northeastern part of Romania and then harvested in 3 consecutive years (2017–2019) to obtain the essential oils. From the inflorescences in the complete flowering stage, the LEOs were extracted by hydrodistillation. Then, their composition was analyzed by gas chromatography coupled with mass spectrometry (GC-MS) and by Fourier Transformed Infrared spectroscopy (FT-IR). The major identified constituents are as follows: linalool (1: 32.19–46.83%; 2: 29.93–30.97%; 3: 31.97–33.77%), linalyl acetate (1: 17.70–35.18%; 2: 27.55–37.13%; 3: 28.03–35.32%), and terpinen-4-ol (1: 3.63–7.70%; 2: 3.06–7.16%; 3: 3.10–6.53%). The antioxidant capacity as determined by ABTS and DPPH assays indicates inhibition, with the highest activity obtained for LEO var. Alba 7 from 2019. The in vitro antimicrobial activities of the LEOs and combinations were investigated as well, by using the disk diffusion method and minimum inhibitory concentration (MIC) against the Gram-positive bacterial strain Staphylococcus aureus (ATCC 6538), Gram-negative Pseudomonas aeruginosa (ATCC 27858), Escherichia coli (ATCC 25922), the yeast Candida albicans (ATCC 10231), and clinical isolates. Our results have shown that LEOs obtained from the three studied varieties of L. angustifolia manifest significant bactericidal effects against tested microorganisms (Staphylococcus aureus and Escherichia coli), and antifungal effects against Candida albicans. The mixture of LEOs (Var. Alba 7) and geranium, respectively, in tea tree EOs, in different ratios, showed a significant enhancement of the antibacterial effect against all the studied strains, except Pseudomonas aeruginosa. 相似文献
233.
Julien Ducamp Alain Bengaouer Pierre Baurens Ioana Fechete Philippe Turek François Garin 《Comptes Rendus Chimie》2018,21(3-4):427-469
This review summarizes the statu quo and the perspectives of chemical methanation. CO2 methanation, including catalyst deactivation, reactors, mechanisms, and thermodynamics are presented. This reaction serves as a test bed for our fundamental understanding of heterogeneous catalysis and is used in various industrial processes, including the removal of oxo-compounds (COx) in the feed gas for the ammonia synthesis, in connection with the gasification of coal, where it can be used to produce methane from synthesis gas, and in relation to Fischer–Tropsch's synthesis. Moreover, CO2 methanation became of interest as a renewable energy storage system based on a “power-to-gas” conversion process by SNG (synthetic natural gas) production integrating water electrolysis and CO2 methanation as a highly effective way to store the energy produced by renewables sources. The effectiveness and efficiency of the “power-to-gas” plants strongly depends on the CO2-methanation process. 相似文献
234.
In this review article, we analyze the state of the art and future developments in three important domains of heterogeneous catalysis, namely ring opening, biocatalysis, and partial oxidation on metal oxides. After recollecting the scientific bases of each domain, we consider several examples, some recent improvements/developments, and some prospective views. 相似文献
235.
We prove that the empirical spectral distribution of a (dL, dR)‐biregular, bipartite random graph, under certain conditions, converges to a symmetrization of the Mar?enko‐Pastur distribution of random matrix theory. This convergence is not only global (on fixed‐length intervals) but also local (on intervals of increasingly smaller length). Our method parallels the one used previously by Dumitriu and Pal (2012). © 2014 Wiley Periodicals, Inc. Random Struct. Alg., 48, 313–340, 2016 相似文献
236.
In a recent paper, Ghenciu and Lewis studied strong Dunford-Pettis sets and made the following two assertions:
While the statements are correct, the proofs are flawed. The difficulty with the proofs is discussed, and a fundamental result
of Elton is used to establish a simple lemma which leads to quick proofs of both (1) and (2).
The online version of the original article can be found at . 相似文献
(1) | The Banach space X * contains a nonrelatively compact strong Dunford-Pettis set if and only if ℓ∞ ↪ X *. |
(2) | If c 0 ↪ Y and H is a complemented subspace of X so that H * is a strong Dunford-Pettis space, then W(X, Y) is not complemented in L(X, Y). |
237.
Taban IM Altelaar AF van der Burgt YE McDonnell LA Heeren RM Fuchser J Baykut G 《Journal of the American Society for Mass Spectrometry》2007,18(1):145-151
Analytical methods are pursued to measure the identity and location of biomolecules down to the subcellular (microm) level. Available mass spectrometric imaging methods either compromise localization accuracy or identification accuracy in their analysis of surface biomolecules. In this study, imaging FTICR-MS is applied for the spatially resolved mass analysis of rat brain tissue with the aim to optimize protein identification by the high mass accuracy and online MS/MS capabilities of the technique. Mass accuracies up to 6 ppm were obtained in the direct MALDI-analysis of the tissue together with a spatial resolution of 200 microm. The spatial distributions of biomolecules differing in mass by less than 0.1 Da could be resolved, and are shown to differ significantly. Online MS/MS analysis of selected ions was demonstrated. A comparison of the FTICR-MS imaging results with stigmatic TOF imaging on the same sample is presented. To reduce the extended measuring times involved, it is recommended to restrict the FTICR-MS analyses to areas of interest as can be preselected by other, faster imaging methods. 相似文献
238.
It is important for many industrial processes to design new materials with improved selective permeability properties. Besides diffusion, the molecule's solubility contributes largely to the overall permeation process. This study presents a method to calculate solubility coefficients of gases such as O2, H2O (vapor), N2, and CO2 in polymeric matrices from simulation methods (Molecular Dynamics and Monte Carlo) using first principle predictions. The generation and equilibration (annealing) of five polymer models (polypropylene, polyvinyl alcohol, polyvinyl dichloride, polyvinyl chloride-trifluoroethylene, and polyethylene terephtalate) are extensively described. For each polymer, the average density and Hansen solubilities over a set of ten samples compare well with experimental data. For polyethylene terephtalate, the average properties between a small (n = 10) and a large (n = 100) set are compared. Boltzmann averages and probability density distributions of binding and strain energies indicate that the smaller set is biased in sampling configurations with higher energies. However, the sample with the lowest cohesive energy density from the smaller set is representative of the average of the larger set. Density-wise, low molecular weight polymers tend to have on average lower densities. Infinite molecular weight samples do however provide a very good representation of the experimental density. Solubility constants calculated with two ensembles (grand canonical and Henry's constant) are equivalent within 20%. For each polymer sample, the solubility constant is then calculated using the faster (10x) Henry's constant ensemble (HCE) from 150 ps of NPT dynamics of the polymer matrix. The influence of various factors (bad contact fraction, number of iterations) on the accuracy of Henry's constant is discussed. To validate the calculations against experimental results, the solubilities of nitrogen and carbon dioxide in polypropylene are examined over a range of temperatures between 250 and 650 K. The magnitudes of the calculated solubilities agree well with experimental results, and the trends with temperature are predicted correctly. The HCE method is used to predict the solubility constants at 298 K of water vapor and oxygen. The water vapor solubilities follow more closely the experimental trend of permeabilities, both ranging over 4 orders of magnitude. For oxygen, the calculated values do not follow entirely the experimental trend of permeabilities, most probably because at this temperature some of the polymers are in the glassy regime and thus are diffusion dominated. Our study also concludes large confidence limits are associated with the calculated Henry's constants. By investigating several factors (terminal ends of the polymer chains, void distribution, etc.), we conclude that the large confidence limits are intimately related to the polymer's conformational changes caused by thermal fluctuations and have to be regarded--at least at microscale--as a characteristic of each polymer and the nature of its interaction with the solute. Reducing the mobility of the polymer matrix as well as controlling the distribution of the free (occupiable) volume would act as mechanisms toward lowering both the gas solubility and the diffusion coefficients. 相似文献
239.
240.