排序方式: 共有98条查询结果,搜索用时 15 毫秒
11.
Roberto Rossi Andrea Marchi Adriano Duatti Luciano Magon Plinio Di Bernardo 《Transition Metal Chemistry》1985,10(4):151-153
Summary The rhenium(V) imido-complexes [Re(NR)Cl3(PPh3)2] have been obtained by heating the rhenium(V) derivative [ReOCl3(PPh3)2] with RNHCHNR R = Ph (1a), p-MeC6H4 (1b), p-ClC6H4 (1c) andp-FC6H4 (1d) in THF under reflux. [Re(NR)Cl3(PPh3)2] (R =p-MeQ6H4) has also been obtained by heating the rhenium(III)-triazenido complex [ReCl2(RN
N
NR)(PPh3)2] in CCl4 under reflux. 相似文献
12.
Ciprian Demeter Francesco Di Plinio 《Journal of Fourier Analysis and Applications》2013,19(4):836-856
It is a result by Lacey and Thiele (Ann. of Math. (2) 146(3):693–724, 1997; ibid. 149(2):475–496, 1999) that the bilinear Hilbert transform maps $L^{p_{1}}(\mathbb{R}) \times L^{p_{2}}(\mathbb{R}) $ into $L^{p_{3}}(\mathbb{R})$ whenever (p 1,p 2,p 3) is a Hölder tuple with p 1,p 2>1 and $p_{3}>\frac{2}{3}$ . We study the behavior of the quartile operator, which is the Walsh model for the bilinear Hilbert transform, when $p_{3}=\frac{2}{3}$ . We show that the quartile operator maps $L^{p_{1}}(\mathbb{R}) \times L^{p_{2}}(\mathbb{R}) $ into $L^{\frac{2}{3},\infty}(\mathbb{R})$ when p 1,p 2>1 and one component is restricted to subindicator functions. As a corollary, we derive that the quartile operator maps $L^{p_{1}}(\mathbb{R}) \times L^{p_{2},\frac{2}{3}}(\mathbb{R}) $ into $L^{\frac{2}{3},\infty}(\mathbb{R})$ . We also provide weak type estimates and boundedness on Orlicz-Lorentz spaces near p 1=1,p 2=2 which improve, in the Walsh case, the results of Bilyk and Grafakos (J. Geom. Anal. 16 (4):563–584, 2006) and Carro et al. (J. Math. Anal. Appl. 357(2):479–497, 2009). Our main tool is the multi-frequency Calderón-Zygmund decomposition from (Nazarov et al. in Math. Res. Lett. 17(3):529–545, 2010). 相似文献
13.
Mazaj M Costacurta S Zabukovec Logar N Mali G Novak Tusar N Innocenzi P Malfatti L Thibault-Starzyk F Amenitsch H Kaucic V Soler-Illia GJ 《Langmuir : the ACS journal of surfaces and colloids》2008,24(12):6220-6225
Mesoporous aluminophosphate thin films with 3D cubic (Im3m) pore arrangement were synthesized for the first time. Thin films were templated with block copolymer nonionic templates Pluronic F127 and F108 and deposited on a glass substrate by dip-coating. In situ SAXS investigations show the formation of a highly ordered mesostructure upon the dip-coating process, which remains stable up to at least 670 K. A cubic mesostructure was observed also by TEM. Template removal process was monitored by TG and FT-IR. A transition from an amorphous aluminophosphate gel to a well-defined aluminophosphate framework was observed by MAS NMR. 相似文献
14.
Mesoporous films containing organic or biological functions within an organised array of cavities are produced by combining sol-gel, self-assembly of supramolecular templates and surface chemistry. This paper reviews the essential physics and chemical concepts behind the synthesis of these complex multifunctional materials. 相似文献
15.
Porus M Maroni P Borkovec M 《Langmuir : the ACS journal of surfaces and colloids》2012,28(13):5642-5651
Polyelectrolyte monolayers on solid substrates are studied with optical reflectivity and the quartz crystal microbalance (QCM). In particular, we investigate the adsorption of anionic poly(styrene sulfonate) (PSS) on amino-functionalized silica as well as cationic poly(allylamine hydrochloride) (PAH) and poly-L-lysine (PLL) on bare silica. By comparing the dry and wet masses measured on identical substrates with these two techniques, we obtain information on the layer thickness and water content of these layers. Monolayers typically feature an adsorbed dry mass of about 0.1-2 mg/m(2), a layer thickness of 0.5-2 nm, and a water content of 20-50%. One finds that the layer thickness increases with increasing concentrations of monovalent salts and polyelectrolytes. 相似文献
16.
Signorini Raffaella Meneghetti Moreno Bozio Renato Brusatin Giovanna Innocenzi Plinio Guglielmi Massimo Negra Federico Della 《Journal of Sol-Gel Science and Technology》2001,22(3):245-253
Hybrid organic-inorganic materials are investigated as suitable materials for inclusion of fullerene derivatives and for fabrication of laser protection devices. A specific synthesis has been developed in order to optimize non-linear optical performances of fullerene derivatives. 3-glicydoxypropyltrymethoxysilane has been used as an inorganic and organic network former to obtain the host material. The sol-gel synthesis consists of the hydrolysis and condensation in acidic conditions of the inorganic network. Epoxy polymerization has been achieved by using zirconium or BF3 alkoxides precursors. Bulk and multilayer materials doped with a fullerene derivative have been fabricated. They show good optical requirements: high fullerenes concentration, high microstructural homogeneity, high laser damage threshold and high optical limiting efficiency. Optical limiting (OL) mechanisms have been investigated. The most effective in the sol-gel materials is the reverse saturable absorption (RSA) one. However, different mechanisms, like non-linear (NL) scattering and NL refraction contribute to a different extent. Open- and closed-aperture OL and z-scan measurements on sol-gel samples show the contribution of NL scattering and NL refraction at 690 nm. Laser damage threshold has been characterized as a function of the structure of the samples and of the optical configurations (f/66 and f/5). 相似文献
17.
Guogang Jia G. Torri P. Innocenzi R. Ocone A. Di Lullo 《Journal of Radioanalytical and Nuclear Chemistry》2006,267(3):505-514
Summary A method for the determination of low-level radium isotopes in mineral and environmental water samples by alpha-spectrometry
has been developed. Radium-225, which is in equilibrium with its mother 229Th, was used as a yield tracer. Radium were preconcentrated from water samples by coprecipitation with BaSO4and iron (III) hydroxide at pH 8-9 using ammonia solution, then isolated from uranium, thorium and iron using a Microthene-TOPO
chromatography column at 8M HCl, separated from barium in a cation-exchange resin column using 0.05M 1,2-cyclohexylenedinitrilotetraacetic
acid monohydrate at pH 8.5 as an eluant, and finally electrodeposited on a stainless steel disc in a medium of 0.17M (NH4)2C2O4at pH 2.6 and current density of 400 mA. cm-2, and counted bya-spectrometry. Optimum experimental conditions for radium separation, purification and electrodeposition
have been studied and discussed in the paper. The lower limits of detection of the method are 0.11 mBq. l-1for 226Ra, 228Ra and 224Ra, respectively, if 2 l of water are analyzed. The method has been checked with a certified reference material IAEA-Soil-6
supplied by the International Atomic Energy Agency and reliable results were obtained. Eighteen water samples collected in
Italy have been analyzed with the method, the mean radiochemical yields for radium were 86.2±6.5%. The obtained radium concentrations
were in the range of 0.50-60.8 mBq. l-1for 226Ra, of 0.10-25.7 mBq. l-1for 228Ra, and of£LLD-7.97 mBq. l-1for 224Ra. The 228Ra/226Ra and 224Ra/226Ra ratios were in the range of 0.189-4.45 and£LLD-0.941, respectively. 相似文献
18.
Top-down patterning of zeolitic imidazolate framework composite thin films by deep X-ray lithography
Dimitrakakis C Marmiroli B Amenitsch H Malfatti L Innocenzi P Grenci G Vaccari L Hill AJ Ladewig BP Hill MR Falcaro P 《Chemical communications (Cambridge, England)》2012,48(60):7483-7485
For the first time a top-down process was used to control the spatial location of Metal-Organic Frameworks on a surface. Deep X-ray lithography was utilised to micropattern a Zeolitic Imidazolate Framework layer on a sol-gel surface, with exposure hardening the sol-gel by inducing crosslinking while leaving the frameworks intact. 相似文献
19.
Plinio Innocenzi Giovanna Brusatin Alessandro Abbotto Luca Beverina Giorgio A. Pagani Mauro Casalboni Felice Sarcinelli Roberto Pizzoferrato 《Journal of Sol-Gel Science and Technology》2003,26(1-3):967-970
A new class of heterocycle-based push-pull chromophores showing enhanced nonlinear properties characterized by an aromatic and highly zwitterionic ground state and a quinoid/neutral excited state have been synthesized to be incorporated in sol-gel hybrid systems. This class of compounds shows very large first molecular hyperpolarizabilities ( as high as 27000 × 10–48 esu) and is a promising candidate for photonic applications where large second order non-linearities are required. In spite of their very large hyperpolarizability and chemical and thermal stability, these chromophores are decomposed in presence of light and oxygen (photobleaching) and are sensitive to acidic environments due to the carbanionic nature of the donor moiety. A hybrid matrix, based on N-[(3-trimethoxysilyl)propyl]ethylenediamine and 3-glycidoxypropyltrimethoxysilane, has been specifically designed to allow the incorporation of such zwitterionic compounds assuring at the same time a good temporal stability of the optical properties. Amine functionalisation has been found very effective in reducing the photobleaching by acting on these chromophores via the singlet oxygen. Second harmonic generation has been observed on poled films, and an order parameter, , of 0.17 has been estimated. The nonlinear coefficient deff of the samples has been thus estimated at a value two times larger than for d11 of quartz that, from literature data, is about 0.335 pm/V. 相似文献
20.
In this paper, we derive an approximation for throughput of TCP Compound connections under random losses. Throughput expressions for TCP Compound under a deterministic loss model exist in the literature. These are obtained assuming that the window sizes are continuous, i.e., a fluid behavior is assumed. We validate this model theoretically. We show that under the deterministic loss model, the TCP window evolution for TCP Compound is asymptotically periodic and is independent of the initial window size. We then consider the case when packets are lost randomly and independently of each other. We discuss Markov chain models to analyze performance of TCP in this scenario. We use insights from the deterministic loss model to get an appropriate scaling for the window size process and show that these scaled processes, indexed by p, the packet error rate, converge to a limit Markov chain process as p goes to 0. We show the existence and uniqueness of the stationary distribution for this limit process. Using the stationary distribution for the limit process, we obtain approximations for throughput, under random losses, for TCP Compound when packet error rates are small. We compare our results with ns2 simulations which show a good match and a better approximation than the fluid model at low p. 相似文献