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131.
132.
Alexander S. Shaplov Laurent Goujon Frédéric Vidal Elena I. Lozinskaya Franck Meyer Inna A. Malyshkina Claude Chevrot Dominique Teyssié Irina L. Odinets Yakov S. Vygodskii 《Journal of polymer science. Part A, Polymer chemistry》2009,47(17):4245-4266
Five ionic imidazolium based monomers, namely 1‐vinyl‐3‐ethylimidazolium bis(trifluoromethylsulfonyl)imide (ILM1), 1‐vinyl‐3‐(diethoxyphosphinyl)‐propylimidazolium bis(trifluoromethylsulfonyl)imide (ILM2), 1‐[2‐(2‐methyl‐acryloyloxy)‐propyl]‐3‐methylimidazolium bis(trifluoromethylsulfonyl)imide (ILM3), 1‐[2‐(2‐methyl‐acryloyloxy)‐undecyl]‐3‐methylimidazolium bis(trifluoromethylsulfonyl)imide (ILM4), 1‐vinyl‐3‐ethylimidazolium dicyanamide (ILM5) were prepared and used for the synthesis of linear polymeric ionic liquids (PILs), crosslinked networks with polyethyleneglycol dimethacrylate (PEGDM) and interpenetrating polymer networks (IPNs) based on polybutadiene (PB). The ionic conductivities of IPNs prepared using an in situ strategy were found to depend on the ILM nature, Tg and the ratio of the other components. Novel ionic IPNs are characterized by increased flexibility, small swelling ability in ionic liquids (ILs) along with high conductivity and preservation of mechanical stability even in a swollen state. The maximum conductivity for a pure IPN was equal to 3.6 × 10?5 S/cm at 20 °C while for IPN swollen in [1‐Me‐3‐Etim] (CN)2N σ reached 8.5 × 10?3 S/cm at 20 °C or 1.4 × 10?2 S/cm at 50 °C. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4245–4266, 2009 相似文献
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The analytic approach proposed by Sekerzh-Zenkovich [On the theory of standing waves of finite amplitude, Dokl. Akad. Nauk USSR 58 (1947) 551–554] is developed in the present study of standing waves. Generalizing the solution method, a set of standing wave problems are solved, namely, the infinite- and finite-depth surface standing waves and the infinite- and finite-depth internal standing waves. Two-dimensional wave motion of an irrotational incompressible fluid in a rectangular domain is considered to study weakly nonlinear surface and internal standing waves. The Lagrangian formulation of the problems is used and the fifth-order perturbation solutions are determined. Since most of the approximate analytic solutions to these problems were obtained using the Eulerian formulation, the comparison of the results, as an example the analytic frequency–amplitude dependences, obtained in Lagrangian variables with the corresponding ones known in Eulerian variables has been carried out in the paper. The analytic frequency–amplitude dependences are in complete agreement with previous results known in the literature. Computer algebra procedures were written for the construction of asymptotic solutions. The application of the model constructed in Lagrangian formulation to a set of different problems shows the ability to correctly reproduce and predict a wide range of situations with different characteristics and some advantages of Lagrangian particle models (for example, the bigger radius of convergence of an expansion parameter than in Eulerian variables, simplification of the boundary conditions, parametrization of a free boundary). 相似文献
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136.
Inna Rebane 《Journal of luminescence》2007,127(1):209-212
In a birefringent host crystal, the spontaneous emission rate of zero-phonon line of a single-impurity molecule depends on the angles between the transition dipole moment and the principal axes of the dielectric (permittivity) tensor and also on the main dielectric constants of a host crystal. In this paper, the spontaneous emission rate of the electric quadrupole transition of a single-impurity molecule is calculated for uniaxial host crystals with the ordinary reflective indices no=1.5, 2, 3 and a variable extraordinary reflective index, and for seven biaxial host crystals (anthracene, chrysene, diphenyl, fluorine, naphthalene, phenanthrene, terphenyl). For the above-mentioned biaxial crystals, differences in the values of spontaneous emission rate of the quadrupole transition in the same host crystal are up to 11%. 相似文献
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Nathalia I. Larionova Stepan S. Vartanov Nadezhda V. Sorokina Inna P. Gladysheva Sergey D. Varfolomeyev 《Applied biochemistry and biotechnology》1997,62(2-3):175-182
The classical Bowman-Birk soybean proteinase inhibitor was modified by hydroxyethylstarch. The modified inhibitor retained
the capacity for simultaneous binding of trypsin and human leukocyte elastase. The inhibition constants,K
i
, of bovine trypsin,α-chymotrypsin and human leukocyte elastase (HLE) increased not more than 10-, 1.5-, and 20-fold, respectively, on modification
of the inhibitor. The less effective inhibition is presumably due to the steric hindrance brought about by the conjugation
with polysaccharide molecules. The results obtained indicate the pronounced structure differences of the binding regions for
trypsin and chymotrypsin/leukocyte elastase in the modified preparation. 相似文献
139.
Simkhovich L Luobeznova I Goldberg I Gross Z 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(1):201-208
The aim of this research was to prepare mononuclear ruthenium corroles, because of the well-documented potency of analogous porphyrin complexes in catalysis. The syntheses of the mononuclear nitrosyl complexes [Ru(tpfc)(NO)] and [Ru(tdcc)(NO)] (tpfc=trianion of 5,10,15-tris(pentafluorophenyl)corrole, tdcc=trianion of 5,10,15-tris(2,6-dichlorophenyl)corrole), and of the binuclear [[Ru(tpfc)](2)] were achieved by using [[Ru(cod)Cl(2)](x)] (cod=cyclooctadiene) as the metal source. The NMR spectra of all three complexes clearly demonstrate that they are diamagnetic; this is consistent with a triple bond between the metal ions in [[Ru(tpfc)](2)] and is expected for classical [MNO](6) complexes. These features were further substantiated by the stretching frequencies of the [MNO] moieties, electrochemical measurements on all complexes, and the X-ray crystal structures of [Ru(tpfc)(NO)] and [[Ru(tpfc)](2)]. A comparison of the spectroscopic and structural characteristics of these new complexes with analogous iron corroles, as well as with iron and ruthenium porphyrins, suggests that it will be hard to obtain mononuclear ruthenium corroles without pi-accepting ligands. 相似文献
140.
A family of 16 salicylaldarylimine titanium(IV) dichloride complexes bearing diallylamino group, namely {2‐[3‐ or 4‐(CH2?CH? CH2)2NC6H4N?CH]‐6‐R1‐4‐R2‐C6H2O}2TiCl2 (R1 = t‐Bu, CMe2(Ph); R2 = H, Me, OMe, t‐Bu) have been used for polymerization of ethylene in the presence of methylaluminoxane. The effects of reaction conditions on the polymerization were examined in detail. All the pre‐catalyst are highly active (up to 14.0 × 106 g(PE) mol(Ti)?1 ?1 h?1) for ethylene polymerization at 30°С to 60°С with the activities and MM correlating with the R1‐substituent type and position of NAll2‐group: CMe2(Ph) > t‐Bu and meta‐NAll2 > para‐NAll2 for any R2. Highly linear polyethylenes (Tm's as high as 141.0°С) can be obtained with high molecular weights in the range 0.70 to 4.10 × 106 g mol?1 with disentangled morphology, suitable for technologically more advanced and greeny way to produce high‐modulus high‐strength fibers of ultrahigh molecular weight polyethylene via solid‐state (solvent‐free) deformation processing. 相似文献