全文获取类型
收费全文 | 1021篇 |
免费 | 34篇 |
国内免费 | 9篇 |
专业分类
化学 | 745篇 |
晶体学 | 17篇 |
力学 | 20篇 |
数学 | 49篇 |
物理学 | 233篇 |
出版年
2024年 | 2篇 |
2023年 | 11篇 |
2022年 | 22篇 |
2021年 | 34篇 |
2020年 | 20篇 |
2019年 | 22篇 |
2018年 | 15篇 |
2017年 | 16篇 |
2016年 | 32篇 |
2015年 | 31篇 |
2014年 | 40篇 |
2013年 | 76篇 |
2012年 | 92篇 |
2011年 | 90篇 |
2010年 | 63篇 |
2009年 | 38篇 |
2008年 | 77篇 |
2007年 | 59篇 |
2006年 | 56篇 |
2005年 | 62篇 |
2004年 | 41篇 |
2003年 | 36篇 |
2002年 | 37篇 |
2001年 | 20篇 |
2000年 | 17篇 |
1999年 | 12篇 |
1998年 | 9篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 7篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1992年 | 6篇 |
1991年 | 1篇 |
1989年 | 5篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有1064条查询结果,搜索用时 15 毫秒
971.
This work demonstrates the synthesis of hydrophilic and hydrophobic high surface area silica aerogel beads with a large pore volume. Wet gel silica beads were modified and heat-treated under atmospheric pressure after modification of the surface by trimethychlorosilane (TMCS). The effects of heat treatment on the physical (hydrophobicity) and textural properties (specific surface area, pore volume, and pore size) of silica aerogel beads were investigated. The results indicated that hydrophobicity of the silica aerogel beads can be maintained up to 400 °C. The hydrophobicity of the silica aerogel beads decreased with increasing temperature in the range of 200-500 °C, and the beads became completely hydrophilic after heat treatment at 500 °C. The specific surface area, cumulative pore volume, and pore size of the silica aerogel beads increased with increasing temperature. Heating the TMCS modified bead gel at 400 °C for 1 h resulted in silica aerogel beads with high surface area (769 m2/g), and large cumulative pore volume (3.10 cm3/g). The effects of heat treatment on the physical and textural properties of silica aerogel beads were investigated by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), thermogravimetric and differential analysis (TG-DTA), Fourier-transform infrared spectroscopy (FT-IR), and Brunauer, Emmett and Teller (BET) and BJH nitrogen gas adsorption and desorption methods. 相似文献
972.
Three‐pole electrospinning devices integrated with a blade‐cage collector were developed to fabricate well‐aligned nano‐fiberous membranes. The proposed three‐pole configuration with a channel electrode can be a powerful tool in aligning nano‐fibers with regular diameter because the generated electric field can be accurately controlled without severe fluctuation in comparison with other methods. The three‐pole electrospinning method is also valid for industrial mass production and accurate diameter control of the aligned nano‐fibers.
973.
Hasegawa M Aliu E Andringa S Aoki S Argyriades J Asakura K Ashie R Berns H Bhang H Blondel A Borghi S Bouchez J Burguet-Castell J Casper D Cavata C Cervera A Chen SM Cho KO Choi JH Dore U Espinal X Fechner M Fernandez E Fukuda Y Gomez-Cadenas J Gran R Hara T Hasegawa T Hayashi K Hayato Y Helmer RL Hill J Hiraide K Hosaka J Ichikawa AK Iinuma M Ikeda A Inagaki T Ishida T Ishihara K Ishii T Ishitsuka M Itow Y Iwashita T Jang HI Jeon EJ Jeong IS Joo KK Jover G Jung CK Kajita T Kameda J Kaneyuki K 《Physical review letters》2005,95(25):252301
We report the result from a search for charged-current coherent pion production induced by muon neutrinos with a mean energy of 1.3 GeV. The data are collected with a fully active scintillator detector in the K2K long-baseline neutrino oscillation experiment. No evidence for coherent pion production is observed, and an upper limit of is set on the cross section ratio of coherent pion production to the total charged-current interaction at 90% confidence level. This is the first experimental limit for coherent charged pion production in the energy region of a few GeV. 相似文献
974.
Several heavyweight impact sources have been used in applying standardized excitation forces to evaluate the noise generation characteristics of building floors. In this study, heavyweight sources (a bang machine and an impact ball) were filmed with a high-speed camera on the period of deformation and restitution of the impact. The generated impact force was measured, and the effects of the taken deforming shapes were investigated. Experimental modal analysis was performed to determine the natural frequencies and mode shapes of the impact sources. With respect to deforming shapes during impacts, the influence of the mode shapes was clearly demonstrated, especially for the impact ball. Using the measured modal properties, the impact force was predicted and compared to the measured excitation force. By comparing the transient variation of the excitation force and its frequency spectrum, the influence of the modal characteristics of the source on the generated impact force was investigated. 相似文献
975.
Han Zhang Qiang Xiao Xianghai Guo Najun Li Prashant Kumar Neel Rangnekar Mi Young Jeon Shaeel Al‐Thabaiti Katabathini Narasimharao Sulaiman Nasir Basahel Berna Topuz Frank J. Onorato Christopher W. Macosko K. Andre Mkhoyan Michael Tsapatsis 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2016,128(25):7123-7123
976.
977.
978.
For more than 20 years nuclear physicists have used the GEANT code to simulate particle-matter interaction. In most recent version, GEANT4 is a toolkit for simulating the passage of particles though matter, which contains a complete range of functionality including tracking, geometry, physics models, and hits. In this article, an attempt to use GEANT4 to model a double-gap resistive plate chamber (RPC) with its improved efficiency is presented. The efficiencies of the double-gap RPC have been evaluated as a function of gamma energy range 0.005-1000MeV. A comparison to available previous simulation package GEANT3 data is also performed. 相似文献
979.
Airborne fungi pose a serious threat to public health. Alternaria alternata (A. alternata) is a fungus that has been associated with the development of asthma. Detection using redox-active species excreted from fungi is an effective method for a simple electrochemical fungal biosensor. The achievable electrochemical signal in most fungi, however, is exceptionally low because of the low amount of excreted redox-active species and their slow excretion rates. Herein, we report that A. alternata excretes an exceptionally large amount of a redox-active species that can be used for sensitive and selective detection of A. alternata. The excretion rate is enhanced in Tris buffer, and the electrochemical-chemical redox cycling involving excreted redox-active species significantly increases the electrochemical signals. Only A. alternata among five common airborne fungi provides large electrochemical signals, which allows selective detection of A. alternata. The calculated detection limit for A. alternata is ~20 spores/mL with an incubation period of 10 min, indicating that the detection method is highly sensitive and rapid. The detection method does not require complicated procedures or harsh pretreatment and is optimal for point-of-care testing of A. alternata. 相似文献
980.
Seung Ho Jeon Taikyue Ree 《Journal of polymer science. Part A, Polymer chemistry》1988,26(5):1419-1428
The solid state of the complex between poly(acrylic acid) (PAA) and poly(ethylene oxide) (PEO), and that between poly(methacrylic acid) (PMAA) and PEO formed via hydrogen-bonding was studied by differential-scanning calorimetric (DSC) and by Fourier-transform infrared (FT–IR) spectroscopic measurements. Melting temperature Tm and the degree of the crystallinity Xc of PEO in the systems PAA (or PMAA)/PEO blends obtained from aqueous or dimethyl sulfoxide (DMSO) medium were measured in various unit mol % of PEO ([PEO]100/{[PAA(or PMAA)] + [PEO]}) where [ ] is the unit mole concentration. It was found that 50 unit mol % of PEO is a critical composition, which gives new evidence for the 1 : 1 complex formation between PAA (or PMAA) and PEO. From the FT–IR spectroscopic analysis in conjunction with DSC measurements we also found that the effects of solvent and of hydrophobic interaction (due to the α-methyl group of PMAA) are the important factors controlling the complexation in the solution and solid systems. These factors also affect the crystallization behavior and the microstructure of the PAA (or PMAA)/PEO blend in solid state. 相似文献