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排序方式: 共有217条查询结果,搜索用时 15 毫秒
31.
Inga M. Arkhipova Angelo Luongo 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2016,67(3):69
The effect of damping on the re-stabilization of statically unstable linear Hamiltonian systems, performed via parametric excitation, is studied. A general multi-degree-of-freedom mechanical system is considered, close to a divergence point, at which a mode is incipiently stable and n ? 1 modes are (marginally) stable. The asymptotic dynamics of system is studied via the Multiple Scale Method, which supplies amplitude modulation equations ruling the slow flow. Several resonances between the excitation and the natural frequencies, of direct 1:1, 1:2, 2:1, or sum and difference combination types, are studied. The algorithm calls for using integer or fractional asymptotic power expansions and performing nonstandard steps. It is found that a slight damping is able to increase the performances of the control system, but only far from resonance. Results relevant to a sample system are compared with numerical findings based on the Floquet theory. 相似文献
32.
33.
Grigoraviciute I Yamauchi H Karppinen M 《Journal of the American Chemical Society》2007,129(9):2593-2596
Among high-Tc superconductive copper oxides, there have been known phases that contain fluorite-structured layers as an additional "blocking block" between adjacent CuO2 planes. Here, we report that even a phase with the CuO2 planes separated by a 12-A thick quadruple-fluorite-layer block can be synthesized in a single phase and strongly oxygenated form to exhibit superconductivity with a Tc value as high as 55 K. The new phase is the fourth member of the (Cu,Mo)Sr2(Ce,Y)sCu2O(5+2s+delta) or (Cu,Mo)-12s2 homologous series. Comparison with the previously known s = 1, 2, and 3 members of the series reveals the amazing conclusion that Tc remains essentially unaffected upon inserting additional fluorite-structured layers between the two CuO2 planes as long as the hole-doping level of the planes is kept constant. 相似文献
34.
We consider linearly ordered, Archimedean dimension groups (G,G+,u) for which the group G/u is torsion-free. It will be shown that if, in addition, G/u is generated by a single element (i.e., ), then (G,G+,u) is isomorphic to for some irrational number τ(0,1). This amounts to an extension of related results where dimension groups for which G/u is torsion were considered. We will prove, in the case of the Fibonacci dimension group, that these results can be used to directly construct an equivalence relation groupoid whose C*-algebra is the Fibonacci C*-algebra. 相似文献
35.
Janka M He W Haedicke IE Fronczek FR Frontier AJ Eisenberg R 《Journal of the American Chemical Society》2006,128(16):5312-5313
The first examples of a tandem Nazarov cyclization/Michael addition process are described. The sequence is efficiently catalyzed by Ir[Me(CO)(dppe)(DIB)]2+ and occurs with high diastereoselectivity, creating three contiguous stereocenters. The mechanistic factors controlling the reactivity and diastereoselectivity are discussed. 相似文献
36.
Bringmann G Kajahn I Reichert M Pedersen SE Faber JH Gulder T Brun R Christensen SB Ponte-Sucre A Moll H Heubl G Mudogo V 《The Journal of organic chemistry》2006,71(25):9348-9356
The isolation and structural elucidation of three novel-type naphthylisoquinoline alkaloids, ancistrocladinium A and B (the latter along with its atropisomer), from a Congolese Ancistrocladus species collected in the habitat Yeteto is reported. Their structures, including all stereochemical features, were elucidated by spectroscopic, chemical, and chiroptical methods. Ancistrocladinium A and B are the first N,C-coupled naphthyldihydroisoquinoline alkaloids found in nature, i.e., with an iminium-aryl axis. Although ancistrocladinium A, which is N,8'-coupled, is configurationally stable at this axis, ancistrocladinum B and its rotational isomer are based on a hitherto unprecedented N,6'-coupling type, with a slow rotation about the hetero biaryl axis at room temperature; they thus occur as a 46:54 mixture of two configurationally semistable atropo-diastereomers. For the isomerization of (P)-ancistrocladinium B to its (M)-diastereomer and for the opposite direction, the Gibbs free energies of activation were determined to be DeltaG double dagger1 = 105.8 kJ mol-1 and DeltaG double dagger2 = 105.7 kJ mol-1, respectively. In addition, the compounds were shown to have promising antileishmanial activities. 相似文献
37.
Andrius Garbaras Justina Šapolaitė Inga Garbarienė Žilvinas Ežerinskis Agnė Mašalaitė-Nalivaikė Raminta Skipitytė 《Isotopes in environmental and health studies》2018,54(5):463-474
In the present study, a combination of the stable carbon isotope ratio (13C/12C) with radiocarbon data (14C) allowed us to perform the aerosol source apportionment. Filter samples of PM1 were collected during the warm and cold periods in rural and urban sites in Lithuania. The 14C/12C ratio of total carbon (TC) was measured using the single stage accelerator mass spectrometer quantifying of fossil and non-fossil derived aerosol emissions. The δ13C value was measured using an elemental analyser interfaced with an isotope ratio mass spectrometer. We have found that the highest fraction of contemporary carbon (fc?=?0.82) was measured during a warm period in a rural location. A higher fraction of fossil fuel-derived carbon was observed for air masses transported from highly industrialized Western European regions during both seasons. Isotope mass balance calculations revealed that the traffic emissions composed 15 and 25?% in rural and urban sites, respectively, and did not change during either season. Input from coal-derived aerosol particles was estimated to be 15?% at an urban site during the cold period. The combination of the stable carbon isotope ratio with the radiocarbon data allowed us to distinguish coal, liquid fossil fuel combustion, and non-fossil derived aerosol particle emissions. 相似文献
38.
Lips F Hołyńska M Clérac R Linne U Schellenberg I Pöttgen R Weigend F Dehnen S 《Journal of the American Chemical Society》2012,134(2):1181-1191
Two K([2.2.2]crypt) salts of lanthanide-doped semimetal clusters were prepared, both of which contain at the same time two types of ternary intermetalloid anions, [Ln@Sn(7)Bi(7)](4-) and [Ln@Sn(4)Bi(9)](4-), in 0.70:0.30 (Ln = La) or 0.39:0.61 (Ln = Ce) ratios. The cluster shells represent nondeltahedral, fullerane-type arrangements of 14 or 13 main group metal atoms that embed the Ln(3+) cations. The assignment of formal +III oxidation states for the Ln sites was confirmed by means of magnetic measurements that reveal a diamagnetic La(III) compound and a paramagnetic Ce(III) analogue. Whereas the cluster anions with a 14-atomic main-group metal cage represent the second examples in addition to a related Eu(II) cluster published just recently, the 13-atomic cages exhibit a yet unprecedented enneahedral topology. In contrast to the larger cages, which accord to the Zintl-Klemm-Busmann electron number-structure correlation, the smaller clusters require a more profound interpretation of the bonding situation. Quantum chemical investigations served to shed light on these unusual complexes and showed significant narrowing of the HOMO-LUMO gap upon incorporation of Ce(3+) within the semimetal cages. 相似文献
39.
Andreas Zerr Nikolay Chigarev Ovidiu Brinza Sergey M. Nikitin Alexey M. Lomonosov Vitalyi Gusev 《固体物理学:研究快报》2012,6(12):484-486
The elastic moduli of the dense polycrystalline oxygen‐bearing η‐Ta2N3, a novel hard and tough high‐pressure (HP) material, were measured using the laser ultrasonic technique. The bulk modulus was determined to be B0 = 281(15) GPa which is only ~11% below that from HP compression measurements. Our value of the shear modulus G0 = 123(2) GPa is below those ones predicted theoretically for model structures. The discrepancies in G0 could be due to a substitution of an‐ ions and the formation of cation vacancies in η‐Ta2N3. Self‐healing behaviour of η‐Ta2N3 by mechanical polishing was observed and confirmed by two independent experimental methods. (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
40.
Summary: The analysis of the influence of ionic liquids (ILs) in polymer synthesis as an alternative for common organic solvents is still an active field of research. 1 Using ILs as solvents for free radical polymerizations implies a significant increase in polymerization rates and molecular weights which can be observed. In this work we examined the copolymerization behaviour of styrene (S) and methyl methacrylate (MMA), glycidyl methacrylate (GMA) and 2-hydroxypropyl methacrylate (HPMA) with acrylonitrile (AN) in 1-etyhl-3-methylimidazolium ethylsulfate ([EMIM]EtSO4). ILs are liquids with comparable high polarities and viscosities. These two characteristic properties are strongly correlated with the rate coefficients of propagation kp and termination kt. 2 - 4 The rate constant of termination kt decreases when the IL concentration and therefore the viscosity of the reaction mixture is increased, whereas the propagation rate coefficient kp increases with increasing IL content. The viscosity of the IL can be varied by either working with mixtures of IL with conventional organic solvents – here the IL [EMIM]EtSO4 was mixed with DMF – or by variation of the temperature. The influence of the viscosity of the IL ([EMIM]EtSO4) on polymerization kinetics of methyl methacrylate (MMA) and styrene/acrylonitrile (S/AN) was investigated. 相似文献