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991.
992.
993.
1 Besicovitch Inner ProductIll this paper, we consider Dirichlet serie8where an, tL = 1, 2,' ', are complex nunlbers. They are Besicovitch almost periodic functionsWe see the 8ystenl {e.(t); e.(t) = e--it Iog 1l, 71 = l, 2,' .} fOrnis a1l orthollor11la1 systelll witl1respect to tI1e BesicovitcI1 iIl1ler productThell we call fOrm the gelleralized trigouolnetrical polynolIlialsAccording to tl1e idea developed il1 [l],[2], auy Dirichlet seriesis weakly convergent over K witll respect to … 相似文献
994.
Synthesis and Characterization of A Novel Cholesteric Liquid Crystalline Containing Carboxyl Group 总被引:1,自引:0,他引:1
JingMA YingNanXUAN YongHUANG 《中国化学快报》2005,16(1):127-130
A novel liquid crystal compound with a carboxyl group at one end, cholest-5-en-3-ol-(3β) hydrogen decanedioate (1) was successfuly prepared by the reaction of cholesterol with sebacoxl chloride. Its chemical structure and liquid crystalline properties were characterized by FTIR.CNMR,HNMR,POM and DSC. The compound with an active carboxyl group shows themortropic liquid crystalline behaviour. 相似文献
995.
Ch. Krüger M. v. Löwis of Menar R. Donau 《Fresenius' Journal of Analytical Chemistry》1990,338(5):593-596
Summary A method for the separation of mass spectra of mixtures is developed. The technique is essential for analysis of chromatographically unseparated components and it relies on the time-varying mass spectra during evaporation. It is shown to be possible, under certain insignificant restrictions, to separate the data from these mass spectra of mixtures into the mass spectra of the pure components and to give their respective concentrations. Even with no component-specific m/z-signals, the parent mass spectra, under favorable conditions, can also be calculated. The mass spectra of a mixture (carbamazepine and its 10-bromo- and 10,11-dibromo-derivative) are used to illustrate the method. 相似文献
997.
Xue Sen FAN Yan Zhen LI Xin Ying ZHANG Xue Yuan HU Jian Ji WANG School of Chemical Environmental Sciences Henan Key Laboratory for Environmental Pollution Control Henan Normal University Xinxiang 《中国化学快报》2005,(7)
Room temperature ionic liquids with low melting point (<100℃) salts represent a new class of non-molecular, ionic solvents. Especially those based on the 1-N-alkyl-3- methylimidazolium cations, have shown great promise as an attractive alternative to conventional solvents for catalytic reactions1. On the other hand, FeCl3·6H2O was considered to be an environmentally benign Lewis acid and has been used successfully in several kinds of organic reactions2. Recently we have focused our interes… 相似文献
998.
Chin‐San Wu 《Journal of polymer science. Part A, Polymer chemistry》2005,43(8):1690-1701
In this study, a silicic acid and tetra isopropyl ortho titanate ceramic precursor and a metallocene polyethylene‐octene elastomer (POE) or acrylic acid grafted metallocene polyethylene‐octene elastomer (POE‐g‐AA) were used in the preparation of hybrids (POE/SiO2? TiO2 and POE‐g‐AA/SiO2? TiO2) using an in situ sol‐gel process, with a view to identifying a hybrid with improved thermal and mechanical properties. Hybrids were characterized using Fourier transform infrared spectroscopy, 29Si solid‐state nuclear magnetic resonance (NMR), X‐ray diffraction, differential scanning calorimetry, thermogravimetry analysis, dynamic mechanical thermal analysis, and Instron mechanical testing. Properties of the POE‐g‐AA/SiO2? TiO2 hybrid were superior to those of the POE/SiO2? TiO2 hybrid. This was because the carboxylic acid groups of acrylic acid acted as coordination sites for the silica‐titania phase to allow the formation of stronger chemical bonds. 29Si solid‐state NMR showed that Si atoms coordinated around SiO4 units were predominantly Q3 and Q4. The 10 wt % SiO2? TiO2 hybrids gave the maximum values of tensile strength and glass transition temperature in both POE/SiO2? TiO2 and POE‐g‐AA/SiO2? TiO2. It is proposed that above this wt %, excess SiO2? TiO2 particles caused separation between the organic and inorganic phases. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1690–1701, 2005 相似文献
999.
Fang‐Chyou Chiu Chin‐Yu Kan Jen‐Chang Yang 《Journal of Polymer Science.Polymer Physics》2009,47(15):1497-1510
The thermal properties and phase morphology of poly(L ‐lactide) (PLLA)‐based blends have been studied. Two poly(ethylene glycol)s (PEGs) with molecular weight (MW) of about 1,500 (1.5k) g/mol and 2,000,000 (2M) g/mol, respectively, were used as counterparts. The blends were annealed at a preselected temperature of 200 °C for either 2 min or 30 min before the characterizations. Both PEGs were determined to enhance the crystallizability of PLLA. After a 2‐min process of annealing, the PEG(1.5k)'s crystallization efficiency on PLLA has been noted to increase with the increase of its content. Conversely, PEG(2M)'s crystallization efficiency declined with the increase of its content. Extending the annealing time has evidently changed the PEGs' crystallization effect on PLLA. Moreover, the PEG(1.5k) has, to a greater extent, brought about the depression of PLLA's melting temperature by increasing its content, and this depression increased with the annealing time. The blends exhibited lower thermal stability than those of the parent components, particularly for the PEG(1.5k)‐included system with a higher PEG content. Regardless of the annealing time, the PEG(1.5k)‐included blends have shown homogeneous melt morphology under light microscope, whereas the PEG(2M)‐included blends have displayed phase‐separated melt morphology. In addition to the composition, PEG's MW and annealing time influence the crystalline morphology of the blends. The ringed PLLA spherulites have appeared mostly in the 2‐min annealed PEG(1.5k)‐included blends. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 1497–1510, 2009 相似文献
1000.
Xinjian Cheng Sie Chin Tjong Qiang Zhao Robert K. Y. Li 《Journal of polymer science. Part A, Polymer chemistry》2009,47(18):4547-4554
This article presents a facile method to prepare silver/polystyrene composite microspheres. In this approach, monodispersed polystyrene (PS) particles were synthesized with carboxyl acid groups on the surfaces of the PS particles via dispersion polymerization at first. With the addition of [Ag(NH3)2]+ to the PS dispersion, [Ag(NH3)2]+ was absorbed to the surfaces of the PS particles, and then by heating the system, [Ag(NH3)2]+ complex ions were reduced to silver to form the Ag/PS composite microspheres. In the synthesis of PS dispersion, PVP was used as dispersant to stabilize the PS particles, it also acted as reducing agent in the reduction of [Ag(NH3)2]+ complex ions to silver, so no additional reducing agent was needed. The resulting composite microspheres were characterized by TEM, SEM, XPS, and XRD. The catalytic properties and surface‐enhance Raman scattering (SERS) was studied as well. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4547–4554, 2009 相似文献