Precise and accurate isotope ratio measurements are an important task in many applications such as isotope-dilution mass spectrometry, bioavailability studies, or the determination of isotope variations in geological or nuclear samples. The technique of MC-ICP–MS has attracted much attention because it permits the precise measurement of isotope compositions for a wide range of elements combined with excellent detection limits due to high ionisation efficiencies. However, the results are based mainly on measurements using continuous sample introduction. In the present study the determination of isotope ratios on various transient signals with a time duration of 30 to 60 s has been achieved by coupling high-performance liquid chromatography to a multicollector inductively coupled plasma mass spectrometer. In order to investigate the origin of ratio drifts across the transient signals for this hyphenated technique, measurements with the same standard solutions were also carried out using a flow-injection device for sample introduction. As a result of this application it could be concluded that the main source of the bias in the measured isotope ratios is within the ICP–MS instead of fractionation effects on the chromatographic column material. Preliminary studies on short transient signals of gaseous samples (dry plasma) showed a reverse fractionation effect compared with wet plasma conditions (flow injection and HPLC).Presented at the 2003 European Winter Conference on Plasma Spectrochemistry, Garmisch-Partenkirchen, Germany, January 2003 相似文献
The analysis and identification of a wide range of secondary metabolites biosynthesized by different algal taxa and cyanobacteria has been performed through a selective and sensitive methodology, mainly based on reversed-phase HPLC coupled both to UV photodiode array detection and to atmospheric pressure mass spectrometric techniques (HPLC-DAD-APIMS). Results are reported here with special attention to the analyses carried out both on the natural phytoplankton (mixed populations) of Lake Tovel (Northern Italy, Brenta Dolomites) and on enclosure-produced biomass of the dinoflagellate Glenodinium sanguineum Marchesoni (1941). This analytical procedure might represent a powerful tool for the fast screening of the taxonomic composition (broad groups, e.g. divisions) of natural mixed populations of phytoplankton, by providing a reliable distribution of accessory pigments extracted from microalgae, such as carotenoids and chlorophyll derivatives. Furthermore, we showed that in the same chromatographic analysis other classes of natural products, such as galactolipids, alkaloids, sterols and mycosporine-like amino acids, can be detected by using combined optical and mass spectrometric techniques. These metabolites represent distinctive biochemical signatures, sometimes even at the species level. 相似文献
In most cases the pharmacological activity of plant extracts is not assigned to single components and often not all active ingredients are known. Approaches other than those considering single compounds only to analyze plant material have proven helpful for a better characterization of extracts in their entirety. In this study extracts of willow bark are analyzed by high-performance thin-layer chromatography (HPTLC) and two different pharmacological tests [the 2,2'-azobis (2-amidinopropane) dihydrochloride reaction and the xanthine/xanthine oxidase reaction] with the help of multivariate data analysis. Described are two models using the results of the chromatographic study of 22 various extracts of willow bark and their pharmacological properties. The chromatographic data are obtained by a special TLC scanner that enables measurement of HPTLC tracks simultaneously in the range of lambda = 200-400 nm. Additionally, the developed models are used to predict the activity of another three extracts of willow bark demonstrating the quality of the model. 相似文献
Growing plants under microgravity conditions in a space ship is essential for future long-term missions to supply needs for food and oxygen. Although plant growth modules for microgravity have been developed and tested for more than 40 years, creating optimal saturation conditions for plant growth in the absence of gravity still remains a challenge. In this study, we present results from a series of spontaneous imbibition experiments designed to approximate microgravity conditions by using density-matched fluid pairs. Porous media with patterned wettability characteristics are used to manipulate macroscopic fluid saturation and microscopic fluid interfacial configurations. These are compared to an additional experiment under Earth gravity, wherein we observe spontaneous imbibition of water into common potting soil. Patterning grains of different wettabilities under microgravity conditions proves to be an effective method to manipulate spatial distributions and saturations of fluids. These wettability patterns can be optimised to fine-tune residual fluid characteristics, e.g. non-wetting phase saturation, connectivity and interfacial area. Furthermore, we present tomographic evidence supporting previous work which was suggesting enhanced snap-off and disconnection of the gas phase in porous media under microgravity.
Annals of Global Analysis and Geometry - This paper is devoted to the classification of 4-dimensional Riemannian spin manifolds carrying skew Killing spinors. A skew Killing spinor $$\psi $$ is a... 相似文献
Journal of Radioanalytical and Nuclear Chemistry - Determination of fraction of biogenic component in liquid fuels by a direct radiocarbon measurement in liquid scintillation counter (direct-LSC... 相似文献
A route of synthesizing triblock terpolymers in a one‐pot, “one‐step” polymerization approach is presented. The combination of two distinct polymerization techniques through orthogonal catalyst/initiator functionalities attached to a polymeric linker furnishes novel pathways to ABC‐terpolymers. Both polymerizations have to be compatible regarding mechanisms, chosen monomers, and solvents. Here, an α,ω‐heterobifunctional poly(ethylene glycol) serves as polymeric catalyst/initiator to obtain triblock terpolymers of poly(norbornene)‐b‐poly(ethylene glycol)‐b‐poly(l ‐lactic acid) PNB‐PEG‐PLLA via simultaneous ring opening metathesis polymerization and ring opening polymerization in a fast one‐pot polymerization. Structural characterization of the polymers is provided via 1H‐, DOSY‐, and 1H,1H‐COSY‐NMR, while solution and thin film self‐assembly are investigated by dynamic light scattering and atomic force microscopy.
Porous hollow silica particles (HSPs) are presented as new templates to control the product morphology in metallocene‐catalyzed olefin polymerization. By selectively immobilizing catalysts inside the micrometer‐sized porous hollow silica particles, the high hydraulic forces resulting from polymer growth within the confined geometries of the HSPs cause its supporting shell to break up from the inside. As the shape of the support is replicated during olefin polymerization, perfectly spherical product particles with very narrow size distribution can be achieved by using HSPs exhibiting a monomodal size distribution. Furthermore, the size of the obtained product particles can be controlled not only by the polymerization time but also by the size of the support material.