Synthesis of cyclic α-hydrazino acids

Synthesis of five-, six-, seven-, eight-, and nine-membered cyclic α-hydrazino acids from a common starting material ‘diethylmalonate’ with 26, 16, 34, 13.5, and 13.33% overall yields is described. Sequential allylation or homoallylation and electrophilic amination followed by cyclization gave the desired rings. The methyl esters of eight- and nine-membered rings were synthesized by RCM and the corresponding free acids were generated after hydrolysis in the presence of 1 M BBr₃ solution in DCM.     

Differential operators on a polarized abelian variety

Let be an ample line bundle over a complex abelian variety . We show that the space of all global sections over of and are both of dimension one. Using this it is shown that the moduli space of rank one holomorphic connections on a compact Riemann surface does not admit any nonconstant algebraic function. On the other hand, is biholomorphic to the moduli space of characters of , which is an affine variety. So is algebraically distinct from the character variety if is of genus at least one.

     

Projective Structure,Symplectic Connection and Quantization

Let X be a connected Riemann surface equipped with a projective structure . Let E be a holomorphic symplectic vector bundle over X equipped with a flat connection. There is a holomorphic symplectic structure on the total space of the pullback of E to the space of all nonzero holomorphic cotangent vectors on X. Using , this symplectic form is quantized. A moduli space of Higgs bundles on a compact Riemann surface has a natural holomorphic symplectic structure. Using , a quantization of this symplectic form over a Zariski open subset of the moduli space of Higgs bundles is constructed.     

Derivation of muon spectrum at high energies from the recent JACEE primary cosmic-ray spectrum using Fermilab data on meson production

Summary The energy spectrum of sea level muons in the range (10²÷10⁴) GeV has been calculated from the latest directly measured JACEE primary spectrum using Fermilab results on pp→π^± X and pp→K^± X inclusive reactions. The conventional pion atmospheric diffusion equation after Bugaevet al. has been used in this analysis to account the flux of muons emerged from the multiple generation of mesons in air. The derived muon spectrum has been compared with the earlier magnetic spectrograph data of Durham and Kiel groups. The latest BAKSAN scintillator telescope data is well in agreement with the calculated integral spectrum originated from the meson decays in the range (1÷10⁴) GeV.     

Thermal instability of a horizontal layer of micropolar fluid with heat source

The thermal instability of a horizontal layer of micropolar fluid which loses heat throughout its volume at a constant rate has been considered. The influence of the various micropolar fluid parameters on the onset of convection have been analysed. It is found that heat source and heat sink have the same destabilising effect in micropolar fluid. It is observed that the horizontal dimension of the cells remains insensitive to the changes in the micropolar fluid parameters and also to the heat source parameterQ except forQ values near zero, where the change is drastic. Further, it is observed that though the vertical component of velocity and the curl of microrotation do not vanish anywhere between the two boundaries forQ=0, they vanish at a point nearer to the lower boundary even for a small change in theQ value.     

Generalized Euler transformation in extracting useful information from divergent (asymptotic) perturbation series and the construction of Padé approximants

Euler transformation for accelerating convergence of a series is considered in the context of handling divergent (asymptotically convergent) perturbation series. A generalized (parametrized) version of this transformation is developed, based on the conjecture of Dalgarno and Stewart, which works better. Viewed from this standpoint, the Padé approximants follow as a special case of the parametrized Euler transformation (PET ), as is the case with the μ transformation procedure of Feenberg in a perturbative context. The PET is shown to serve as a more general method of handling a divergent series and is able to appreciate the construction and convergence behavior of specific sequences of Padé approximants. The role of parametrization in the context of the Z^?1 perturbation theory of atoms is also noted and the workability of the adopted strategy is demonstrated by choosing some specific test cases.     

Molecular inversion in the nπ* states: A theoretical investigation of some model systems in a semiempirical molecular orbital framework

The considerations of Walsh rules are extended to rationalize the loss of planarity in the ^1,3nπ* states of simple carbonyl and thiocarbonyl molecules. The role of Fermi correlation in shaping the differences between conformations in the singlet and the triplet state is emphasized. The role played by the π* orbital is also considered.     

Energy spectra of cosmic pions and nucleons at the top of the atmosphere

The production spectra of cosmic pions and their primaries have been derived from the experimental muon spectrum by using the theories of Barrettet al. and Feynman. The calculated pion production spectrum takes the formI(E _π)d E _π = 0.206E _π ^{? 2.65} d E _πper cm² sec str GeV in the energy range 3<E _π<1500 GeV and the nucleon spectrum follows the relationN(E _p)d E _p = 2.7 × 10⁴ (E _p/GeV)^2.65 d E _pper m² sec str GeV in the range 5 <E _p <3000 Gev.     

A soft-segmentation visualization scheme for magnetic resonance images

Prevalent visualization tools exploit gray value distribution in images through modified histogram equalization and matching technique, referred to as the window width/window level-based method, to improve visibility and enhance diagnostic value. The window width/window level tool is extensively used in magnetic resonance (MR) images to highlight tissue boundaries during image interpretation. However, the identification of different regions and distinct boundaries between them based on gray-level distribution and displayed intensity levels is extremely difficult because of the large dynamic range of tissue intensities inherent in MR images. We propose a soft-segmentation visualization scheme to generate pixel partitions from the histogram of MR image data using a connectionist approach and then generate selective visual depictions of pixel partitions using pseudo color based on an appropriate fuzzy membership function. By applying the display scheme in clinical examples in this study, we could demonstrate additional overlapping regions between distinct tissue types in healthy and diseased areas (in the brain) that could help improve the tissue characterization ability of MR images.