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71.
Bimal P. Singh Jayadev Jena Laxmidhar Besra Sarama Bhattacharjee 《Journal of nanoparticle research》2007,9(5):797-806
The dispersion characteristics of nanosize silicon carbide (SiC) suspension were investigated in terms of surface charge,
particle size, rheological measurement and adsorption study. Ammonium polycarboxylate has been used as dispersant to stabilize
the suspension. It was found that the isoelectric point (iep) of SiC powder was pHiep (4.9). The surface charge of powder changed significantly in presence of the ammonium polycarboxylate dispersant and iep
shifted significantly towards lower acidic pH (3.6). The shift in iep has been quantified in terms of ΔG
0
SP, the specific free energy of adsorption between the surface sites and the adsorbing polyelectrolyte (APC). The values of
ΔG
0
SP (−10.85 RT unit) estimated by the electro kinetic data compare well with those obtained from adsorption isotherms (−9.521 RT unit). The experimentally determined optimum concentration of dispersant required for maximizing the dispersion was found
to be 2.4 mg/g of SiC (corresponding to an adsorbed amount of 1.10 mg/g), at pH 7.5. This is much below the full monolayer
coverage (corresponding to adsorbed amount of 1.75 mg/g) of the particles surface by the dispersant. The surface charge quantity,
rheological, pH, electro kinetic and adsorption isotherm results were used to explain and correlate the stability of the nanosize
silicon carbide in aqueous media. At pH 7.5, where both SiC surface and APC are negatively charged, the adsorption of APC
was low because of limited availability of favourable adsorption sites. In addition, the brush-like configuration of the adsorbed
polymer prevented close approach of any additional dispersant; hence stabilization of the slurry happens at a comparatively
lower concentration than the monolayer coverage. 相似文献
72.
Sudip K. De Manish Bhattacharjee 《Journal of polymer science. Part A, Polymer chemistry》2011,49(18):3920-3927
An early transition metal metallocene compound, Cp2ZrCl2, with an anionic surfactant, sodium n‐dodecyl sulfate (SDS) as emulsifier and NaBPh4 as cocatalyst has been found to be an effective catalytic system for polymerization and copolymerization of monomers like styrene and methyl methacrylate in aqueous medium. The diameters of the latex particles were found to be in between 20 and 40 nm. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
73.
We investigate orthogonal and symplectic bundles with parabolic structure, over a curve. 相似文献
74.
C. Raghu Indranil Rudra Diptiman Sen S. Ramasesha 《Journal of Chemical Sciences》2001,113(5-6):459-486
One of the fascinating fields of study in magnetism in recent years has been the study of quantum phenomena in nanosystems.
While semiconductor structures have provided paradigms of nanosystems from the stand point of electronic phenomena, the synthesis
of high nuclearity transition metal complexes have provided examples of nano magnets. The range and diversity of the properties
exhibited by these systems rivals its electronic counterparts. Qualitative understanding of these phenomena requires only
a knowledge of basic physics, but quantitative study throws up many challenges that are similar to those encountered in the
study of correlated electronic systems. In this article, a brief overview of the current trends in this area are highlighted
and some of the efforts of our group in developing a quantitative understanding of this field are outlined. 相似文献
75.
We introduce a single step memory dependence in the fully chaotic logistic map. This makes it a two dimensional system in general. However, we show that by using composite functions to define two one dimensional maps, it is possible to obtain some analytic results for the bifurcation structure. Numerical results support the calculated bifurcation scheme and, in addition, yield a further insight which allows the calculation of the convergence ratio for a new period adding scenario. 相似文献
76.
Estrogen induced proliferation of existing mutant cells is widely understood to be the major risk determining factor in the
development of breast cancer. Hence determination of the Estrogen Receptor[ER] status is of paramount importance. We have
carried out the synthesis and characterization of a novel NIR fluorescent dye conjugate aimed at measuring ER+ve status in-vivo.
The conjugate was synthesized by ester formation between 17-β estradiol and a cyanine dye namely: bis-1, 1-(4-sulfobutyl)
indotricarbocyanine-5-carboxylic acid, sodium salt. The replacement of the sodium ion in the ester by a larger glucosammonium
ion was found to enhance the hydrophilicity and reduce the toxic effect on cell lines. The excitation and emission peaks for
the dye were recorded as 750 and 788 nm respectively; ideal for non-invasive optical imaging owing to minimal tissue attenuation
and auto-fluorescence at these wavelengths. The dye (NIRDC1) has a significant drop in plasma-protein binding therefore leading to marked improvement in pharmacokinetic profile such
as dye evacuation in comparison to ICG. In addition the dye showed enhanced fluorescence quantum yield, molar extinction coefficient
and linearity in fluorescence relative to ICG. This dye can be potentially used as a target specific exogenous contrast agent
in molecular optical imaging for early detection of breast cancer. 相似文献
77.
We consider the Sel’kov model of glycolytic oscillator for a quantitative study of the limit cycle oscillations in the system.
We identify a region of parameter space where perturbation theory holds and use both Linstedt Poincaré technique and harmonic
balance to obtain the shape and frequency of the limit cycle. The agreement with the numerically obtained result is excellent.
We also find a different extreme, where the limit cycle is of the relaxation oscillator variety, has a large time period and
it is seen that, as a particular parameter in the model is varied, the time period increases indefinitely. We characterize
this divergence numerically. A calculational method is devised to capture the divergence approximately. 相似文献
78.
Dipsikha Bhattacharya Sumanta K. Sahu Indranil Banerjee Manasmita Das Debashish Mishra Tapas K. Maiti Panchanan Pramanik 《Journal of nanoparticle research》2011,13(9):4173-4188
In this article, we report the design and synthesis of a series of well-dispersed superparamagnetic iron oxide nanoparticles
(SPIONs) using chitosan as a surface modifying agent to develop a potential T
2 contrast probe for magnetic resonance imaging (MRI). The amine, carboxyl, hydroxyl, and thiol functionalities were introduced
on chitosan-coated magnetic probe via simple reactions with small reactive organic molecules to afford a series of biofunctionalized
nanoparticles. Physico-chemical characterizations of these functionalized nanoparticles were performed by TEM, XRD, DLS, FTIR,
and VSM. The colloidal stability of these functionalized iron oxide nanoparticles was investigated in presence of phosphate
buffer saline, high salt concentrations and different cell media for 1 week. MRI analysis of human cervical carcinoma (HeLa)
cell lines treated with nanoparticles elucidated that the amine-functionalized nanoparticles exhibited higher amount of signal
darkening and lower T
2 relaxation in comparison to the others. The cellular internalization efficacy of these functionalized SPIONs was also investigated
with HeLa cancer cell line by magnetically activated cell sorting (MACS) and fluorescence microscopy and results established
selectively higher internalization efficacy of amine-functionalized nanoparticles to cancer cells. These positive attributes
demonstrated that these nanoconjugates can be used as a promising platform for further in vitro and in vivo biological evaluations. 相似文献
79.
Cooperative relaying is considered as an effective technique to enlarge the coverage area and enhance the system capacity for the future wireless systems. In this paper, an infrastructure based multi-antenna cooperative relay network has been investigated. Closed form expressions of outage probability and average error rate have been derived, when the relay and the destination perform selection combining of the signals. The relay is assumed to operate in the adaptive decode and forward mode. The effect of number of antennas installed on the relay and their placement has also been studied. 相似文献
80.
Subrata Bhattacharjee Shuhei Takahashi Kazunori Wakai Christopher P. Paolini 《Proceedings of the Combustion Institute》2011,33(2):2465-2472
Numerical analysis and scale analysis are combined in a novel manner in this work to develop closed-form expressions for flame geometry in opposed-flow flame spread over condensed fuels. A scale analysis is used to relate different geometric attributes to appropriate non-dimensional parameters. A comprehensive numerical model is then used to generate a large set of numerical data for flame height, flame length, and pyrolysis length as functions of different fuel and oxidizer parameters for flame spread in the thermal, kinetic, and radiative regimes. The numerical data is then correlated to scaled expressions and the unknown coefficients are numerically determined. It is shown that flame length, flame height, and pyrolysis length can be expressed in terms of the preheat length in different regimes of flame spread. An experimental approach is outlined to measure the preheat length necessary for accurately predicting the flame structure. Experimental images obtained from interferometry in two different regimes – downward spreading configuration and quiescent microgravity environment – are consistent with the proposed flame height correlation. 相似文献