Activation energy and nonequilibrium effects in thermal reactions

Calculations of the nonequilibrium rate constant for the model system H₂O₂ + M → 2 OH + M over the temperature range of 300–1900°K, assuming that only vibrational, or that both vibrational and rotational, energy is transferred in a collision, show that (1) inefficient energy transfer leads to a distinctly non-Arrhenius temperature dependence, the nonlinearity being in principle different for different M, and (2) despite different activation energies for different M, the order of M efficiencies is preserved throughout the temperature range. A reversal of M efficiencies can occur only if there is a change of mechanism of the reaction over the temperature range investigated.     

Bernstein-Greene-Kruskal modes in a three-dimensional plasma

Bernstein-Greene-Kruskal modes in a three-dimensional (3D) unmagnetized plasma are constructed. It is shown that 3D solutions that depend only on energy do not exist. However, 3D solutions that depend on energy and additional constants of motion (such as angular momentum) do exist. Exact analytical as well as numerical solutions are constructed assuming spherical symmetry, and their properties are contrasted with those of 1D solutions. Possible extensions to solutions with cylindrical symmetry with or without a finite magnetic guide field are discussed.     

Opers and theta functions

We construct natural maps (the Klein and Wirtinger maps) from moduli spaces of semistable vector bundles over an algebraic curve X to affine spaces, as quotients of the nonabelian theta linear series. We prove a finiteness result for these maps over generalized Kummer varieties (moduli space of torus bundles), leading us to conjecture that the maps are finite in general. The conjecture provides canonical explicit coordinates on the moduli space. The finiteness results give low-dimensional parametrizations of Jacobians (in for generic curves), described by 2Θ functions or second logarithmic derivatives of theta.We interpret the Klein and Wirtinger maps in terms of opers on X. Opers are generalizations of projective structures, and can be considered as differential operators, kernel functions or special bundles with connection. The matrix opers (analogues of opers for matrix differential operators) combine the structures of flat vector bundle and projective connection, and map to opers via generalized Hitchin maps. For vector bundles off the theta divisor, the Szegö kernel gives a natural construction of matrix oper. The Wirtinger map from bundles off the theta divisor to the affine space of opers is then defined as the determinant of the Szegö kernel. This generalizes the Wirtinger projective connections associated to theta characteristics, and the associated Klein bidifferentials.     

Equivariant Reduction to Torus of a Principal Bundle

Let M be an irreducible projective variety, over an algebraically closed field k of characteristic zero, equipped with an action of a connected algebraic group S over k. Let E _G be a principal G-bundle over M equipped with a lift of the action of S on M, where G is a connected reductive linear algebraic group. Assume that E _G admits a reduction of structure group to a maximal torus TG. We give a necessary and sufficient condition for the existence of a T-reduction of E _G which is left invariant by the action of S on E _G .     

Complete spectrum of kinetic eigenmodes for plasma oscillations in a weakly collisional plasma

Kinetic eigenmodes of plasma oscillations in a weakly collisional plasma, described by a collision operator of the Fokker-Planck type, are obtained in closed form for initial-value as well as for boundary-value problems. These eigenmodes, which are smooth and compose a complete discrete spectrum, play the same role for weakly collisional plasmas as the Case-Van Kampen modes do for collisionless plasmas.     

Nonlinear theory of void formation in colloidal plasmas

A nonlinear time-dependent model for void formation in colloidal plasmas is proposed. For experimentally relevant initial conditions, the model describes the nonlinear evolution of a zero-frequency linear instability that grows rapidly in the nonlinear regime and subsequently saturates to form a void. A number of features of the model are consistent with experimental observations under laboratory and microgravity conditions.     

On the symplectic structures on moduli space of stable sheaves over a K3 or abelian surface and on Hilbert scheme of points

Fix a smooth very ample curve C on a K3 or abelian surface X. Let $ \mathcal{M} $ denote the moduli space of pairs of the form (F, s), where F is a stable sheaf over X whose Hilbert polynomial coincides with that of the direct image, by the inclusion map of C in X, of a line bundle of degree d over C, and s is a nonzero section of F. Assume d to be sufficiently large such that F has a nonzero section. The pullback of the Mukai symplectic form on moduli spaces of stable sheaves over X is a holomorphic 2-form on $ \mathcal{M} $. On the other hand, $ \mathcal{M} $ has a map to a Hilbert scheme parametrizing 0-dimensional subschemes of X that sends (F, s) to the divisor, defined by s, on the curve defined by the support of F. We prove that the above 2-form on $ \mathcal{M} $ coincides with the pullback of the symplectic form on the Hilbert scheme.     

Studies on CdS nanoparticles dispersed in silica matrix prepared by sol-gel technique

SiO₂/CdS-nanoparticle composite films (SiO₂:CdS=85:15, 80:20, 75:25 and 70:30) were prepared by the sol-gel route. The films were characterized by studying microstructural (XRD and TEM) and optical (transmittance and photoluminescence) properties. Band gaps of these films annealed at different temperatures (373-473 K) for different times (10-120 min) indicated that the signature of nanocrystallinity is retained throughout the range of our experimental conditions. A thermal diffusion process controlled growth in the crystallite size with increasing annealing time and temperature. The average radii of the nanoparticles varied as the cube root of the annealing time but showed exponential dependence on the inverse of annealing temperature. Photoluminescence (PL) studies of the composite films indicated excitonic transitions. Theoretical analysis of the line shapes of the PL peaks recorded at 300 K and 80 K could be accounted for by the combined effects of size distribution and phonon broadening. It was observed that the deformation potential (E _d) effectively controlled the line shapes of the PL measurements. Received 24 May 2002 Published online 27 January 2003 RID="a" ID="a"e-mail: msakp@mahendra.iacs.res.in     

Search for heavy particles decaying into electron-positron pairs in pp collisions

We present results of searches for technirho (rho(T)), techniomega (omega(T)), and Z' particles, using the decay channels rho(T),omega(T),Z'-->e(+)e(-). The search is based on 124.8 pb(-1) of data collected by the D0 detector at the Fermilab Tevatron during 1992-1996. In the absence of a signal, we set 95% C.L. upper limits on the cross sections for the processes pp-->rho(T),omega(T),Z'-->e(+)e(-) as a function of the mass of the decaying particle. For certain model parameters, we exclude the existence of degenerate rho(T) and omega(T) states with masses below about 200 GeV. We exclude a Z' with mass below 670 GeV, assuming that it has the same couplings to fermions as the Z boson.     

A Quantization on Riemann Surfaces with Projective Structure

Let X be a Riemann surface equipped with a projective structure. Let be a square-root of the holomorphic cotangent bundle K _X . Consider the symplectic form on the complement of the zero section of obtained by pulling back the symplectic form on K _X using the map ². We show that this symplectic form admits a natural quantization. This quantization also gives a quantization of the complement of the zero section in K _X equipped with the natural symplectic form.