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981.
A synthetic method for oligo(ethylene glycol) toward 44-mer (FW = 1956.35) is described. Reiteration of Williamson's ether synthesis and hydrogenation to remove protecting benzyl group affords desired oligo(ethylene glycol) toward 44-mer in moderate yields. The advantages in this method are use of commercially easily available materials as starting materials and procedures avoiding difficulty in purification of the products as much as possible. 相似文献
982.
Fast imaging using the STimulated Echo Acquisition Mode (STEAM) sequence can produce cine images of the heart with black-blood contrast. Nevertheless, correction of deformation-related artifacts is required in order to maintain myocardial signal throughout the cardiac cycle. Recent work by our group has eliminated this artifact by combining two STEAM sequences acquired with two different demodulation gradients. Unfortunately, these two STEAM sequences were acquired on two separate breath-holds; thus, scan time doubled. In this work, we present a technique to reduce the total scan time by one half, without sacrificing image quality. The technique is based on interleaving two demodulations within one acquisition in order to obtain quality cine images of the heart in a single breath-hold. The technique was tested on animal models and human subjects, and the impact of interleaved acquisition on image quality was studied using quantitative and qualitative measures. 相似文献
983.
Multibubble standing wave patterns can be generated from a flat piezoceramic transducer element radiating into water. By adding a second transducer positioned at 90 degrees from the transducer generating the standing wave, a 3-dimensional volume of stable single bubbles can be established. Further, the addition of the second transducer stabilizes the bubble pattern so that individual bubbles may be studied. The size of the bubbles and the separation of the standing waves depend on the frequency of operation. Two transducers, operating at frequencies above 500 kHz, provided the most graphic results for the configuration used in this study. At these frequencies stable bubbles exhibit a bright sonoluminescence pattern. Whereas stable SBSL is well-known, stable MBSL has not been previously reported. This paper includes discussions of the acoustic responses, standing wave patterns, and pictorial results of the separation of individual bubble sonoluminescence in a multibubble sonoluminescence environment. 相似文献
984.
The three-dimensional spin-1 Ising superlattice consisting of two different ferromagnetic materials with two different crystal fields Δ1 and Δ2 is considered in the mean field approximation. The phase diagrams are considered in the (t,d2) plane for different ranges of variation of d1(t=T/J,d1=Δ1/J, d2=Δ2/J are the reduced temperature and crystal fields respectively). The phase diagrams exhibit a variety of multicritical points and reentrant and double reentrant behaviours. They are found to depend qualitatively and/or quantitatively on the thicknesses of the materials in a supercell. This has direct consequences on the nature of the magnetic states of superlattices with different thicknesses. 相似文献
985.
David Gendron Pierre‐Olivier Morin Ahmed Najari Mario Leclerc 《Macromolecular rapid communications》2010,31(12):1090-1094
New aromatic compounds with a pyridazine core have been synthesized. Four electron‐withdrawing monomers have been easily prepared from simple condensation reactions and ring closure procedures. Optimized HOMO, LUMO, and bandgap energy levels have been obtained. The resulting conjugated polymers have been tested in organic solar cells. First studies have revealed power conversion efficiencies up to 0.5% for an active area of 1.0 cm2.
986.
Longitudinal and transverse structure functions in decaying nearly homogeneous and isotropic turbulence 下载免费PDF全文
Streamwise evolution of longitudinal and transverse velocity structure functions in a decaying homogeneous and nearly isotropic turbulence is reported for Reynolds numbers Reλ up to 720. First, two theoretical relations between longitudinal and transverse structure functions are examined in the light of recently derived relations and the results show that the low-order transverse structure functions can be well approximated by longitudinal ones within the sub-inertial range. Reconstruction of fourth-order transverse structure functions with a recently proposed relation by Grauer et al. is comparatively less valid than the relation already proposed by Antonia et al. Secondly, extended self-similarity methods are used to measure the scaling exponents up to order eight and the streamwise evolution of scaling exponents is explored. The scaling exponents of longitudinal structure functions are, at first location, close to Zybin’s model, and at the fourth location, close to She–Leveque model. No obvious trend is found for the streamwise evolution of longitudinal scaling exponents, whereas, on the contrary, transverse scaling exponents become slightly smaller with the development of a steamwise direction. Finally, the stremwise variation of the order-dependent isotropy ratio indicates the turbulence at the last location is closer to isotropic than the other three locations. 相似文献
987.
A substructuring technique is presented for transient dynamic analysis of systems composed of interconnected rigid and elastic bodies that undergo large angular displacements. Displacement of elastic bodies is represented by superposition of local linear elastic deformation on large displacement of body reference coordinate systems. Elastic bodies are thus represented by combined sets of reference and local elastic generalized coordinates. Modal analysis and substructuring of individual elastic components allow for elimination of insignificant modes. Equations of motion and constraint are formulated in terms of mixed sets of modal and reference generalized coordinates. Planar and spatial linkages with flexible elements are presented to illustrate use of the method developed. 相似文献
988.
Anis Hamza Fakeeha Muhammad Awais Naeem Wasim Ullah Khan Ahmed Elhag Abasaeed Ahmed Sadeq Al-Fatesh 《化学物理学报(中文版)》2014,27(2):214-220
用浸渍法制备γ-Al2O3负载的Ni-Mn双金属催化剂.在500-700。C按照17:17:2的C02/CHa/N2比例,以36mL/min的载气流速进行甲烷二氧化碳重整反应,利用甲烷二氧化碳的转化率、生成的合成气H2/CO比例以及长期稳定性等指标评价了催化剂的催化性能.实验表明,添加Mn提高催化性能并使双金属催化剂的稳定性更高,比单金属催化剂更好地抑制焦炭生成,Mn最合适的添加量为0.5wt%.通过BET、C02-TPD、TGA、XRD、SEM、EDX和FTIR各种技术对催化剂进行了表征. 相似文献
989.
The Absolute Nodal Coordinate Formulation (ANCF) has been initiated in 1996 by Shabana (Computational Continuum Mechanics,
3rd edn., Cambridge: Cambridge University Press, 2008). It introduces large displacements of planar and spatial finite elements relative to the global reference frame without
using any local frame. A sub-family of beam, plate and cable finite elements with large deformations are proposed and employed
the 3D theory of continuum mechanics. In the ANCF, the nodal coordinates consist of absolute position coordinates and gradients
that can be used to define a unique rotation and deformation fields within the element. In contrast to other large deformation
formulations, the equations of motion contain constant mass matrices as well as zero centrifugal and Coriolis inertia forces.
The only nonlinear term is a vector of elastic forces. This investigation concerns a way to generate new finite element in
the ANCF for laminated composite plates. This formulation utilizes the assumption that the bonds between the laminae are thin
and shear is non-deformable. Consequently, the Equivalent Single Layer, ESL model, is implemented. In the ESL models, the
laminate is assumed to deform as a single layer, assuming a smooth variation of the displacement field across the thickness.
In this paper, the coupled electromechanical effect of Piezoelectric Laminated Plate is imposed within the ANCF thin plate
element, in such a way as to achieve the continuity of the gradients at the nodal points, and obtain a formulation that automatically
satisfies the principle of work and energy. Convergence and accuracy of the finite-element ANCF Piezoelectric Laminated Plate
is demonstrated in geometrically nonlinear static and dynamic test problems, as well as in linear analysis of natural frequencies.
The computer implementation and several numerical examples are presented in order to demonstrate the use of the formulation
developed in this paper. A comparison with the commercial finite element package COMSOL MULTIPHYSICS () is carried out with an excellent agreement. 相似文献
990.
Magdy?A.?EzzatEmail author Ahmed?S.?El Karamany Mohsen?A.?Fayik 《Archive of Applied Mechanics (Ingenieur Archiv)》2012,82(4):557-572
In this work, the field equations of the linear theory of thermoelasticity have been constructed in the context of a new consideration
of Fourier law of heat conduction with time-fractional order and three-phase lag. A uniqueness and reciprocity theorems are
proved. One-dimensional application for a half-space of elastic material in the presence of heat sources has been solved using
Laplace transform and state space techniques Ezzat (Canad J Phys Rev 86:1241–1250, 2008). According to the numerical results and its graphs, conclusion about the new theory has been established. 相似文献