全文获取类型
收费全文 | 83篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 66篇 |
力学 | 7篇 |
数学 | 6篇 |
物理学 | 13篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 8篇 |
2021年 | 7篇 |
2020年 | 4篇 |
2019年 | 4篇 |
2018年 | 4篇 |
2017年 | 2篇 |
2016年 | 4篇 |
2015年 | 4篇 |
2014年 | 6篇 |
2013年 | 5篇 |
2012年 | 5篇 |
2009年 | 3篇 |
2008年 | 1篇 |
2007年 | 3篇 |
2006年 | 7篇 |
2005年 | 2篇 |
2004年 | 3篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 2篇 |
1995年 | 2篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
排序方式: 共有92条查询结果,搜索用时 15 毫秒
71.
Kulkarni SA Kakade BA Mulla IS Pillai VK 《Journal of colloid and interface science》2006,299(2):777-784
The passivating behavior of self-assembled monolayers (SAMs) of octadecyltrichlorosilane (OTS) on an n-type Si(100) electrode with and without a redox species like ferrocene in a polar non-aqueous medium has been investigated using techniques like contact angle measurements, Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS) to understand the role of the monolayer. The electron-transfer behavior of ferrocene is found to be drastically affected by the presence of monolayer and the reasons for these are analyzed as a function of the change in resistance, dielectric thickness and coverage of the monolayer. Electrochemical impedance analysis in the presence of ferrocene gives the monolayer coverage as 0.998 and the apparent rate constant calculated from this gives 4.85 x 10(-12) cm s(-1) in comparison with 4.4 x 10(-8) cm s(-1) for a similar electrode without any monolayer. A positive shift of 200 mV in the flat-band potential after monolayer formation also suggests the covalent coupling of the silane monolayer offering a protective barrier. 相似文献
72.
Shape selective synthesis of ZnO micropencils and microhexagonal cones has been demonstrated using a controlled method of modified vapor deposition. A plausible growth mechanism based on the results of scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetry, and differential thermal analysis is proposed. Our results suggest that growth of micropencil takes place as per the vapor-liquid-solid progression while the microhexagonal cones grow in two steps following a vapor-solid/vapor-liquid-solid mechanism. Moreover, the geometry, the location of substrate and temperature are found to have key roles in governing the morphology. XPS studies clearly demonstrate the presence of Si species as SiO and SiO2, which act as catalysts enabling nucleating sites for ZnO microstructural growth. 相似文献
73.
Imtiaz U. Khairuddin Ian C. Hunter Alok K. Rastogi 《International Journal of Infrared and Millimeter Waves》1995,16(9):1541-1560
A simple theoretical model for predicting the resonant frequencies of the modes of the whispering — gallery (WG) mode dielectric resonators MICs (Microwave Integrated Circuits) at microwave and millimetre wave frequencies is presented. The unsymmetric field distribution for WGE mode in the axial direction is taken into account. The theoretical results are found to be in good agreement with the practical results taken at microwaves C-X bands. In addition, the variation of resonant modes against dielectric resonator's dimensions and dielectric constant is modelled. The effect of the width of dielectric substrate on resonant modes is also illustrated. 相似文献
74.
Salimuzzaman Siddiqui S.Imtiaz Haider S.Salman Ahmad B.S. Siddiqui 《Tetrahedron》1985,41(20):4577-4580
A new dihydroindole alkaloid sandwicolidine has been isolated from Rauwolfia serpentina and its structure elucidated through chemical and spectroscopic studies. 相似文献
75.
Several dissimilar types of tin oxide microstructures including bipyramids, cubes, and wires synthesized effectively by means of a simple approach were investigated using X-ray diffraction (XRD), thermogravimetry/differential thermometric analysis (TG-DTA), and X-ray photoelectron spectroscopy (XPS). A possible growth mechanism is proposed using the results of these studies. The texture coefficient values of all the structures, indexed to a tetragonal lattice, exhibit amazing variation in the preferred orientation with respect to their shapes. Although XPS data indicate that wires and cubes have a strong SnO(2) type signal, bipyramids interestingly exhibit both SnO and SnO(2) signals and a correlation of the binding energy helps in understanding the growth kinetics of such submicron structures. The results suggest that the bipyramids are formed because of the vapor-solid process (VS) while wires and cubes are formed by the vapor-liquid-solid (VLS) progression. 相似文献
76.
Liaqat Ali Imtiaz Hussain Tania Shamim Rizvi Abdul Latif Khan Shaukat Shujah Jawahar Mohammed Salim Al‐Sahi Ahmed Al‐Harrasi Javid Hussain 《Helvetica chimica acta》2015,98(10):1462-1465
A new trihydroxy sesquiterpene, rel‐(1R,4aR,5S,6S,7S,8aR)‐decahydro‐6,8a‐dimethyl‐5‐(propan‐2‐yl)naphthalene‐1,6,7‐triol ( 1 ), has been isolated as a result of the phytochemical investigation on the CH2Cl2 extract of Teucrium mascatense. The structure elucidation of the new constituent was carried out by the combined use of 1D‐ (1H‐ and 13C‐NMR) and 2D‐NMR (HMBC and HSQC) spectroscopic analysis, along with mass spectrometric techniques. In addition to the new constituent 1 , the known metabolite 2 , previously isolated from Crataegus pinnatifida, was also identified. 相似文献
77.
Faisal Usman Hamid Saeed Shah Sumera Zaib Sirikhwan Manee Jahanzeb Mudassir Ajmal Khan Gaber El-Saber Batiha Khamael M. Abualnaja Dalal Alhashmialameer Imtiaz Khan 《Molecules (Basel, Switzerland)》2021,26(21)
Type 2 diabetes mellitus has been a major health issue with increasing morbidity and mortality due to macrovascular and microvascular complications. The urgent need for improved methods to control hyperglycemic complications reiterates the development of innovative preventive and therapeutic treatment strategies. In this perspective, xanthone compounds in the pericarp of the mangosteen fruit, especially α-mangostin (MGN), have been recognized to restore damaged pancreatic β-cells for optimal insulin release. Therefore, taking advantage of the robust use of nanotechnology for targeted drug delivery, we herein report the preparation of MGN loaded nanosponges for anti-diabetic therapeutic applications. The nanosponges were prepared by quasi-emulsion solvent evaporation method. Physico-chemical characterization of formulated nanosponges with satisfactory outcomes was performed with Fourier transform infra-red (FTIR) spectroscopy, differential scanning calorimetry (DSC), and scanning electron microscopy (SEM). Zeta potential, hydrodynamic diameter, entrapment efficiency, drug release properties, and stability studies at stress conditions were also tested. Molecular docking analysis revealed significant interactions of α-glucosidase and MGN in a protein-ligand complex. The maximum inhibition by nanosponges against α-glucosidase was observed to be 0.9352 ± 0.0856 µM, 3.11-fold higher than acarbose. In vivo studies were conducted on diabetic rats and plasma glucose levels were estimated by HPLC. Collectively, our findings suggest that MGN-loaded nanosponges may be beneficial in the treatment of diabetes since they prolong the antidiabetic response in plasma and improve patient compliance by slowly releasing MGN and requiring less frequent doses, respectively. 相似文献
78.
Qureshi Umair Imtiaz Beenish Jamal Yousuf 《Journal of Thermal Analysis and Calorimetry》2020,140(4):1745-1758
Journal of Thermal Analysis and Calorimetry - With rapid urbanization and industrialization, cheap energy supply from fossil fuels has become a problem of great extent, due to the rising fuel... 相似文献
79.
Sr2IrO4 is a weak ferromagnet where the spin arrangement is canted anti-ferromagnetic (AF). Moreover, the spin-structure coupling plays an important role in magnetic behavior of Sr2IrO4. In this concern the magnetization under zero applied field i.e. spontaneous magnetization would be interesting to study and would give insight into the novel magnetic behavior of Sr2IrO4. Sophisticated techniques like neutron diffraction, μSR etc has been used to understand the magnetic behavior of Sr2IrO4 under zero applied field. To understand the magnetic behavior we have performed field and temperature dependent magnetization study. The measured field and temperature dependent magnetic data is analyzed rigorously. We have attempted to understand the temperature dependance of spontaneous magnetization, remanent magnetization and coercive force. We observe that the spontaneous magnetization extracted from Arrott plot shows that the Sr2IrO4 is not an ideal ferromagnet. The temperature dependent coercive field follows Guant's model of strong domain wall pinning. Our investigation explicit the temperature dependence of various magnetic properties shows the magnetic transitions from paramagnetic to ferromagnetic phase with around 225 K and a low temperature evolution of magnetic moment around K. 相似文献
80.
Usman Ghani Shah Hussain Maria Imtiaz Shahid Ali Khan 《Journal of Saudi Chemical Society》2021,25(3):101198
In the present study, the role of calcination of a low iron lateritic clay sample was investigated to synthesize the geopolymer. The analyses like X-ray fluorescence (XRF) spectroscopy for chemical composition, X-ray diffractometry (XRD) for mineral composition, and Fourier transform infrared (FT-IR) spectroscopy & scanning electron microscopy (SEM) for structural changes upon calcination at 500, 700 and, 900 °C were used to assess the suitability of selected lateritic clay sample for geopolymer. The drop in electrical conductivity and greater consumption of calcium hydroxide by CS-900 confirmed its potential reactivity than CS-700, CS-500, and CS-Control. The quality of geopolymer derived from un-calcined and calcined lateritic clay samples by alkali activation was evaluated by comparing results of compressive strength, water absorption test, and stability in the aggressive environment of chloride, FT-IR, XRD, and SEM analyses. The experimental results reveal that the quality of geopolymer enhances as the calcination temperature of the lateritic clay sample increases, However, calcination of the lateritic clay sample at 900 °C gives significant results and yield good quality geopolymer with 24.8 MPa of compressive strength, 7.07% of water absorption and 2.22% loss in mass in an aggressive environment. 相似文献