全文获取类型
收费全文 | 534篇 |
免费 | 33篇 |
国内免费 | 2篇 |
专业分类
化学 | 408篇 |
晶体学 | 5篇 |
力学 | 19篇 |
数学 | 42篇 |
物理学 | 95篇 |
出版年
2024年 | 6篇 |
2023年 | 11篇 |
2022年 | 50篇 |
2021年 | 46篇 |
2020年 | 33篇 |
2019年 | 29篇 |
2018年 | 29篇 |
2017年 | 21篇 |
2016年 | 34篇 |
2015年 | 17篇 |
2014年 | 23篇 |
2013年 | 46篇 |
2012年 | 42篇 |
2011年 | 43篇 |
2010年 | 35篇 |
2009年 | 21篇 |
2008年 | 10篇 |
2007年 | 17篇 |
2006年 | 11篇 |
2005年 | 12篇 |
2004年 | 3篇 |
2003年 | 10篇 |
2002年 | 5篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1984年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有569条查询结果,搜索用时 19 毫秒
151.
Applied Mathematics and Mechanics - This study deals with the features of the mass and heat transport mechanism by adopting a modified version of Fourier and Fick’s model known as the... 相似文献
152.
Rehman Samiya Keefover-Ring Ken Haq Ihsan ul Dilshad Erum Khan Mohammad Imran Akhtar Nosheen Mirza Bushra 《Applied biochemistry and biotechnology》2019,188(3):893-895
Applied Biochemistry and Biotechnology - The original version of this article unfortunately contained a mistake in the image of Figure 1 and in Table 4. The corrected version of the figure... 相似文献
153.
Bernd Trathnigg Muhammad Imran Malik Nicole Pircher Stephan Hayden 《Journal of separation science》2010,33(14):2052-2059
In ternary mobile phases consisting of acetone, methanol, and water, the retention of PEG on reversed‐phase columns is independent on molar mass at certain compositions of the mobile phase. Along this critical adsorption line, the retention of polypropylene glycol varies quite strongly, which can be utilized in the separation of block copolymers. Gradient elution along the critical line allows a baseline separation of all oligomers in polypropylene glycol up to approximately 25 propylene oxide units. The same resolution can be achieved in the separation of ethylene oxide‐propylene oxide block copolymers, regardless of the length of the ethylene oxide block. 相似文献
154.
155.
156.
157.
Trevisan J Angelov PP Patel II Najand GM Cheung KT Llabjani V Pollock HM Bruce SW Pant K Carmichael PL Scott AD Martin FL 《The Analyst》2010,135(12):3266-3272
The Syrian hamster embryo (SHE) assay (pH 6.7) is an in vitro candidate to replace in vivo carcinogenicity tests. However, the conventional method of visual scoring of foci (non-transformed vs. transformed colonies) can be time-consuming and is open to subjectivity. Infrared (IR) spectroscopy has the potential to provide objective assessment of such SHE colonies with the added advantage of potentially providing mechanistic information. In this study, SHE cells were treated with one of eight different chemical regimens, allowed in culture to attach and form foci on IR-reflective glass slides; these were subsequently interrogated by attenuated total reflection (ATR) Fourier-transform IR (FTIR) spectroscopy. Derived mid-IR spectra (n = 13,406) were subjected to chemometric analysis focusing primarily on the extraction of biochemical information related to test agent treatment and/or morphological transformation. The use of ATR-FTIR spectroscopy with chemometrics to analyze the SHE assay is a novel approach to toxicological assessment. 相似文献
158.
The [4+2] cycloaddition of 3‐(arylsulfanyl)‐1‐(trimethylsilyloxy)buta‐1,3‐dienes with dimethyl penta‐2,3‐dienedioate provides a convenient and regioselective approach to a variety of 4‐(arylsulfanyl)‐2‐hydroxyhomophthalates. 相似文献
159.
Muhammad Imran Malik Bernd Trathnigg Karin Bartl Robert Saf 《Analytica chimica acta》2010,658(2):217-8378
Polyoxyalkylene diblock copolymers (consisting of PEO as hydrophilic block and PBO or PHO as hydrophobic block) are characterized by combination of two dimensional liquid chromatography and MALDI-TOF-MS. Liquid chromatography under critical conditions (LCCC) is used as first dimension and fractions are collected, mobile phase evaporated and diluted in the mobile phase used in the second dimension (SEC, LCCC or LAC). This two-dimensional chromatography in combination of MALDI-TOF-MS gives information about purity of reaction products, presence of the byproducts, chemical composition and molar mass distribution of all the products. 相似文献
160.
Immobilized polysaccharide-based chiral stationary phases (CSPs) are gaining importance in the resolution of racemic compounds due to their stable nature on working with normal solvents and those prohibited for use with coated phases (tetrahydrofuran, chloroform, dichloromethane, acetone, 1,4-dioxane, ethyl acetate, and certain other ethers). This review discusses the use of immobilized polysaccharide CSPs in the chiral resolution of various racemates by liquid chromatography. The discussion includes immobilization methodologies, enantioselectivities, efficiencies, and a comparison of chiral recognition capabilities of coated vs. immobilized CSPs. Some applications of immobilized CSPs to the chiral resolution of racemic compounds are also presented. 相似文献