Photoelectron-photoion momentum spectroscopy as a clock for chemical rearrangements: isomerization of the di-cation of acetylene to the vinylidene configuration

We have used complete correlated momentum mapping of the photoelectron and heavy ion products from the dissociation of the di-cation of acetylene, induced by photoionizing the carbon K shell of one of the atoms, to map out the angular correlation between the electron and the axis of the target molecule. The (quasi-) symmetric decay is found to proceed through both acetylene and vinylidene configurations. By using the strongly peaked photoelectron emission to "start a clock," an upper limit of 60 fs is placed on the isomerization time from the acetylene to the vinylidene configuration.     

Enhanced spatiotemporal laser-beam smoothing in gas-jet plasmas

Spatiotemporal smoothing of large-scale laser intensity fluctuations is observed for a laser beam focused into underdense helium plasmas. This smoothing is found to be severely enhanced when focusing the laser beam into a helium gas jet. In contrast to other experiments with preformed plasmas, the average and the peak laser intensities are well below the threshold for ponderomotive self-focusing. The coherence characteristics of the transmitted light are measured for various electron densities, and the smoothing effect is explained by multiple scattering of laser light on self-induced density perturbations.     

First-principles calculations of pseudolocal vibrational modes: the case of Cu and Cu pairs in Si

Pseudolocal vibrational modes (pLVMs) are defect-related vibrational modes which are localized despite being below the phonon maximum. Such modes are sometimes seen as phonon replicas in photoluminescence spectra. The pLVMs associated with two copper-related defects are calculated from first-principles density-functional theory in periodic supercells. The localization of the pLVMs is quantified using the magnitude of the eigenvectors of the dynamical matrix.     

Diode-pumped cw and Q-switched Nd:GdVO4 laser operating at 1.34 μm

A diode-pumped 1.34 m Nd:GdVO₄ laser operating in cw and active Q-switching modes has been demonstrated. 4.15 W of cw output power was obtained at the highest attainable pump power of 12.3 W, resulting in an optical conversion efficiency of 33.7%, the slope efficiency was determined to be 37.6%. In Q-switching operation, a maximum average output power of 2.7 W was generated at pulse repetition frequency (PRF) of 50 kHz, with an optical conversion efficiency of 22% and a slope efficiency of 29.2%. The laser pulses with shortest duration, highest energy and peak power were achieved at PRF of 10 kHz, the parameters being 15 ns, 160 J, and 10.7 kW, respectively. By intracavity frequency-doubling with a type II phased-matched KTP crystal, 0.62 W average power at 0.67 m was produced at a PRF of 15 kHz, the resulting pulse energy, peak power, and pulse width being 41.3 J, 2.2 kW, and 19 ns, respectively. A group of analytical formulae, based on rate equations, are presented to evaluate the operational parameters of an actively Q-switched laser. Calculated results were found to be in close consistency with the experimental data.     

Partial photoionization cross sections and angular distributions for double excitation of helium up to the N = 13 threshold

Partial photoionization cross sections sigmaN(Egamma) and photoelectron angular distributions betaN(Egamma) were measured for the final ionic states He+ (N > 4) in the region between the N = 8 and N = 13 thresholds (Egamma > 78.155 eV) using the cold target recoil ion momentum spectroscopy technique (COLTRIMS). Comparison of the experimental data with two independent sets of theoretical predictions reveals disagreement for the branching ratios to the various HeN(+) states. The angular distributions just below the double ionization threshold suggest an excitation process for highly excited N states similar to the Wannier mechanism for double ionization.     

Generation of radially polarized beams in a Nd:YAG laser with self-adaptive overcompensation of the thermal lens

Thermal effects such as lensing and birefringence negatively affect the beam quality and limit the power range of solid-state lasers. Self-adaptive overcompensation of the thermal lens is an answer to this problem. It provides a laser system with good beam quality and large stability range. Because the focal length of the thermally induced lens is different for the radial and the tangential polarization, overcompensation can be used to discriminate these two polarizations. Exploiting this method, we demonstrate the generation of radially polarized beams in a self-adaptively overcompensated high-power Nd:YAG laser with an output power of 155 W and an M2 of less than 10.     

Contrast-enhanced high-resolution magnetic resonance imaging of autologous cartilage implants of the knee joint

Over the past decade, a number of interventions for durable cartilage repair have emerged. Magnetic resonance (MR) tomography is an excellent noninvasive method for monitoring cartilage repair tissues throughout the postsurgical period. However, evaluating cartilage morphology after matrix-based autologous cartilage implantation (ACI) with MR imaging (MRI) still remains a challenge. In this study, we combined a high-resolution cartilage-sensitive fast-spin echo (FSE) sequence with intravenous application of a contrast agent for enhancing synovial fluid. Two independent musculoskeletal radiologists interpreted the pictures for the thickness, length and surface of the cartilage implants. A multivariate two-way analysis of variance with two repeated measures was performed and showed that evaluation of cartilage implant morphology was significantly improved after the application of gadodiamide on proton density FSE images. Contrast-enhanced MRI of articular cartilages is a promising technique in the postoperative follow-up of patients after ACI.     

Superconducting MgB2 films on MgO substrates

We report the preparation of homogeneous, polycrystalline MgB₂ films on single-crystalline MgO substrates by screen printing and airbrush methods. The superconducting material was obtained by the reaction of Mg vapor with boron precursor layers in special steel casings under argon/hydrogen atmosphere at 800 °C and ambient pressure. After polishing of the surface, films with a thickness of about 2 m were obtained. Electrolytic polishing improved the surface smoothness of the samples. Transition temperatures of about 33 K were measured with irreversibility fields of up to 6 T at 20 K. Transport critical current densities of 2×10⁹ Am^-2 were obtained at 4.2 K in self-field for a MgB₂ film on single-crystalline MgO. PACS 74.72.Yg; 74.76.Db; 74.60.Jg     

Receptor occupancy on an ellipsoidal cell in the presence of a point source of a chemoattractant

Diffusion of a chemoattractant from a micropipet is routinely used to examine the different aspects of a cell's chemotactic response. To quantify the effect of cell elongation on chemotactic sensitivity in the micropipet assay, the chemoattractant concentration at the cell plasma membrane was determined by solving the equation for diffusion from a point source in the presence of a prolate ellipsoid of varying eccentricity. The results show that cell elongation can significantly increase the difference in receptor occupancy between near and far cell ends and thereby enhance the sensitivity of chemotactic cells to shallow chemoattractant gradients.