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排序方式: 共有591条查询结果,搜索用时 46 毫秒
81.
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Leandro F. Gil‐Silva Raquel Santamaría‐Fernández Prof. Dr. Armando Navarro‐Vázquez Prof. Roberto R. Gil 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(2):472-476
A new DMSO‐compatible aligning gel based on cross‐linked poly(2‐hydroxylethyl methacrylate) (poly‐HEMA) has been developed. Due to a significant difference in bulk magnetic susceptibility between the DMSO inside and outside the gel, it is possible to simultaneously collect isotropic and anisotropic NMR data, such as residual dipolar couplings (RDC), in the same NMR tube. RDC‐assisted structural analysis of menthol and the alkaloid retrorsine is reported as proof of concept. 相似文献
83.
Xinyue Li Sergey Semin Leandro A. Estrada Chunqing Yuan Yulong Duan Jonathan Cremers Paul Tinnemans Paul Kouwer Alan E. Rowan Theo Rasing Jialiang Xu 《中国化学快报》2018,29(2):297-300
The polymorphs of a phenylethynyl functionalized fluorenone derivative, and their controlled self-assembly for microstructures with different morphologies have been studied. These polymorphic microcrystals exhibit very distinctive NLO properties, which are highly correlated to their electronic and supramolecular structures. 相似文献
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Lianet Aguilera Priscila Carvalho Machado Aguiar Yurimiler Leyet Eduardo Padrón-Hernández Raimundo Ribeiro Passos Leandro Aparecido Pocrifka 《Journal of Solid State Electrochemistry》2018,22(12):3845-3852
In the present work, CoOOH films are synthesized from the electrochemical oxidation of α-Co(OH)2 as precursor. The substrate influences on the material electrochemical properties are studied. The samples are structural and morphologically characterized using techniques of X-ray diffraction (XRD) and scanning electronic microscopy (SEM). The cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy techniques are used for the electrochemical characterization. The films deposited on steel substrate grew in the vertical hexagonal platelet form. Meanwhile, films on Ti plate presented morphology in agglomerated sphere form. After electrochemical oxidation, the film initial morphology is maintained. The films deposited on steel plate have a structure which favors charge storage showing a high specific capacity value (110.92 mA h g?1) and cyclic stability of 92% after 1000 cycles. Finally, the relaxation time constant value calculated was 5.6 s. This fact is making this material as a possible good candidate for application as electrode material or additive for other materials, in energy storage devices. 相似文献
87.
Carvalho Leandro L. Tanaka Auro A. Colmati Flavio 《Journal of Solid State Electrochemistry》2018,22(5):1471-1481
Journal of Solid State Electrochemistry - Carbon-supported Pd, Pt, Pt1Pd1, and Pt3Pd1 electrocatalysts were prepared by metal ion chemical reduction with borohydride. The electrocatalysts were... 相似文献
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Dr. Cristian Guerra Dr. Leandro Ayarde-Henríquez Dr. Yeray A. Rodríguez-Núñez Prof. Adolfo Ensuncho Prof. Dr. Eduardo Chamorro 《Chemphyschem》2023,24(11):e202200867
In this study, we revealed the significance of chemical bonding for the photochemically induced mechanism of 2-phenyl tetrazole derivatives generating nitrile imines. The correlated electron localization function shows that the formation of imine nitrile involves two key bond events: (i) the heterolytic C−N breakage taking place in the T1 state and (ii) the homolytic N−N rupture occurring in the T2 excited state. In particular, a cation-radical specie results from the C−N cleavage, whereas the N−N rupture creates a biradical resonant form of imine nitrile. Additionally, we noticed that the substantial pair delocalization of the C−C-N bonded structure could play a significant role in the conversion of the biradical imine nitrile into both the propargylic and allenic forms via the T1→S0 deactivation. 相似文献
90.
Given a partition \(\lambda \) of n, the Schur functor \({\mathbb {S}}_\lambda \) associates to any complex vector space V, a subspace \({\mathbb {S}}_\lambda (V)\) of \(V^{\otimes n}\). Hermite’s reciprocity law, in terms of the Schur functor, states that \({\mathbb {S}}_{(p)}\left( {\mathbb {S}}_{(q)}({\mathbb {C}}^2)\right) \simeq {\mathbb {S}}_{(q)}\left( {\mathbb {S}}_{(p)}({\mathbb {C}}^2)\right) . \) We extend this identity to many other identities of the type \({\mathbb {S}}_{\lambda }\left( {\mathbb {S}}_{\delta }({\mathbb {C}}^2)\right) \simeq {\mathbb {S}}_{\mu }\left( {\mathbb {S}}_{\epsilon }({\mathbb {C}}^2)\right) \). 相似文献