Vortex pattern of the turbulent flow around a single cube on a flat surface and its heat transfer at different attack angles

Experimental results on convective heat transfer from a single cube on a flat surface are presented for different attack angles to the incident flow and Reynolds numbers. The character of vortex formation and the effect of flow structure on heat transfer at detached flow around a cube were studied by visualization. Local heat transfer and heat transfer averaged over the separate faces and the whole lateral surface of the cube were studied. Contribution of separate cube faces to total heat transfer depending on the attack angle was estimated. Data obtained were compared with those published in literature. The reasons for observed differences caused by the effect of many factors: boundary layer thickness, turbulence level of the incident flow, channel constraint, etc., are analysed.     

Parametric generation of low-frequency waves by plasma electrons accelerated under electron cyclotron resonance conditions

It has been shown experimentally that the diamagnetic effect appearing when electrons of a magnetized plasma in the antenna near field are accelerated under electron cyclotron resonance conditions can be used to generate low-frequency waves. The amplitude modulation of a signal supplied to the antenna is accompanied by the modulation of the diamagnetic effect and leads to the emission of waves at the modulation frequency to the surrounding plasma. In this process, the extended plasma region containing accelerated electrons serves as a parametric bodiless antenna. The results of the model laboratory experiments make it possible to propose a method for the parametric generation of low-frequency whistler waves in the Earth’s ionosphere by a powerful amplitude-modulated signal supplied to the satellite-borne antenna.     

Higgs boson mass bounds in the Standard Model with type III and type I seesaw

In type III seesaw utilized to explain the observed solar and atmospheric neutrino oscillations the Standard Model (SM) particle spectrum is extended by introducing three SU(2)_L triplet fermion fields. This can have important implications for the SM Higgs boson mass (MH$M_H$) bounds based on vacuum stability and perturbativity arguments. We compute the appropriate renormalization group equations for type III seesaw, and then proceed to identify regions of the parameter space such that the SM Higgs boson mass window is enlarged to 125 GeV?MH?174 GeV$125\text{GeV}?M_H?174\text{GeV}$, with the type III seesaw scale close to TeV. We also display regions of the parameter space for which the vacuum stability and perturbativity bounds merge together for large neutrino Yukawa couplings. Comparison with type I seesaw is also presented.     

Harmonic measure and winding of random conformal paths: A Coulomb gas perspective

We consider random conformally invariant paths in the complex plane (SLEs). Using the Coulomb gas method in conformal field theory, we rederive the mixed multifractal exponents associated with both the harmonic measure and winding (rotation or monodromy) near such critical curves, previously obtained by quantum gravity methods. The results also extend to the general cases of harmonic measure moments and winding of multiple paths in a star configuration.     

Divergent 2-Chloroquinazolin-4(3H)-one Rearrangement: Twisted-Cyclic Guanidine Formation or Ring-Fused N-Acylguanidines via a Domino Process

A highly efficient 2-chloroquinazolin-4(3H)-one rearrangement was developed that predictably generates either twisted-cyclic or ring-fused guanidines in a single operation, depending on the presence of a primary versus secondary amine in the accompanying diamine reagent. Exclusive formation of twisted-cyclic guanidines results from pairing 2-chloroquinazolinones with secondary diamines. Use of primary amine-containing diamines permits a domino quinazolinone rearrangement/intramolecular cyclization, gated through (E)-twisted-cyclic guanidines, to afford ring-fused N-acylguanidines. This scalable, structurally tolerant transformation generated 55 guanidines and delivered twisted-cyclic guanidines with robust plasma stability and an abbreviated total synthesis of an antitumor ring-fused guanidine (4 steps, 55 % yield).     

The gross beta activity of surface sediment in different urban landscape areas

Journal of Radioanalytical and Nuclear Chemistry - A castable polyurethane (PUR) with soft segment made by polytetrahydrofuran polyol (or polytretramethylene ether glycol?=?PTMEG)...     

Catalytic Behavior of Mono-N-Protected Amino-Acid Ligands in Ligand-Accelerated C−H Activation by Palladium(II)

Mono-N-protected amino acids (MPAAs) are increasingly common ligands in Pd-catalyzed C−H functionalization reactions. Previous studies have shown how these ligands accelerate catalytic turnover by facilitating the C−H activation step. Here, it is shown that MPAA ligands exhibit a second property commonly associated with ligand-accelerated catalysis: the ability to support catalytic turnover at substoichiometric ligand-to-metal ratios. This catalytic role of the MPAA ligand is characterized in stoichiometric C−H activation and catalytic C−H functionalization reactions. Palladacycle formation with substrates bearing carboxylate and pyridine directing groups exhibit a 50–100-fold increase in rate when only 0.05 equivalents of MPAA are present relative to Pd^II. These and other mechanistic data indicate that facile exchange between MPAAs and anionic ligands coordinated to Pd^II enables a single MPAA to support C−H activation at multiple Pd^II centers.     

Study of a Pulsed Air Flow in a Large Vacuum Chamber by Means of a Commercial Ionization Gauge

Technical Physics - A method for creating a pressure gradient by pulsed injection of air into a large vacuum chamber for laboratory simulation of plasma phenomena in a vertically nonuniform...