Capillary cavity flow past a circular cylinder

Cavity flow past a circular cylinder is considered accounting for the surface tension on the cavity boundary. The fluid is assumed to be inviscid and incompressible, and the flow is assumed to be irrotational. The solution is based on two derived governing expressions, which are the complex velocity and the derivative of the complex potential defined in an auxiliary parameter region. An integral equation in the velocity magnitude along the free surface is derived from the dynamic boundary condition. The Brillouin–Villat criterion is employed to determine the location of the point of flow separation. The cases of zero surface tension and zero cavitation number are obtained as limiting cases of the solution. Numerical results concerning the effects of surface tension and cavitation development on the cavity detachment, the drag force and the geometry of the free boundaries are presented over a wide range of the Weber and the cavitation numbers.     

Steady-state rotational motions of a rigid body with a strong magnet in an alternating magnetic field in the presence of dissipation

We consider steady-state rotational motions of a satellite, i.e., a rigid body with a passive magnetic attitude control system consisting of a strong constant magnet and a set of magnetic hysteresis rods. We use asymptotic methods to show that in the absence of dissipation there exists a one-parameter family of steady-state rotations of the rigid body with the strong magnet and that this one-parameter family passes into an isolated solution if a model dissipation is introduced. The motion thus obtained was discovered when processing the telemetry data from the first Russian nano-satellite TNS-0 launched in 2005.     

Anisotropic hardening and non-associated flow in proportional loading of sheet metals

Conventional isotropic hardening models constrain the shape of the yield function to remain fixed throughout plastic deformation. However, experiments show that hardening is only approximately isotropic under conditions of proportional loading, giving rise to systematic errors in calculation of stresses based on models that impose the constraint. Five different material data for aluminum and stainless steel alloys are used to calibrate and evaluate five material models, ranging in complexity from a von Mises’ model based on isotropic hardening to a non- associated flow rule (AFR) model based on anisotropic hardening. A new model is described in which four stress–strain functions are explicitly integrated into the yield criterion in closed form definition of the yield condition. The model is based on a non-AFR so that this integration does not affect the accuracy of the plastic strain components defined by the gradient of a separate plastic potential function. The model not only enables the elimination of systematic errors for loading along the four loading conditions, but also leads to a significant reduction of systematic errors in other loading conditions to no higher than 1.5% of the magnitude of the predicted stresses, far less that errors obtained under isotropic hardening, and at a level comparable to experimental uncertainty in the stress measurement. The model is expected to lead to a significant improvement in stress prediction under conditions dominated by proportional loading, and this is expected to directly improve the accuracy of springback, tearing, and earing predictions for these processes. In addition, it is shown that there is no consequence on MK necking localization due to the saturation of the yield surface in pure shear that occurs with the aluminum alloys using the present model.     

Ethylene/Norbornene Copolymerization with iPr(Cp)(Flu)ZrCl2 Catalyst: Effect of MAO Cocatalyst and 3rd Monomer

The copolymerization of ethylene and norbornene (N) was carried out with iPr(Cp)(Flu)ZrCl₂ catalyst and modified methylaluminoxane (MMAO) cocatalyst. The catalytic activity was dependent on the structure of MMAO, i.e., MMAO-4 exhibited higher catalyst activity than MMAO-3A containing more i-butyl groups. The glass transition temperature (T_g) and the composition of the produced copolymer were not affected by MMAO type. With styrene derivatives as 3^rd monomer, T_g of copolymer increased while the catalytic activity decreased. With the addition of 3^rd monomer, not only the content of 3^rd monomer but also the content of N increased.     

Growth behaviour of bulk GaN single crystals grown with various flux ratios using solvent‐thermal method

Bulk GaN single crystals were grown using a solvent‐thermal method. They were grown for 200 h at 600 °C and 800 °C using 8 MPa of N₂ gas and 1–3 mm sized pyramid GaN single crystals. Pure Na, NaN₃ and Ca were used as the flux. The mole fraction of the [flux]/([flux] + [Ga]) was 0.30–0.67. The growth behavior differed according to the flux ratio. The quality of the bulk GaN single crystals was improved by increasing the flux ratio. The bulk GaN single crystals formed by spontaneous nucleation were deposited on the BN crucible wall and bottom during the first step of synthesis. The wurtzite structure of the GaN grown single crystal was confirmed by x‐ray diffration. The chemical composition was analyzed by electron probe microanalysis. The quality and optical properties of the GaN single crystal were examined by Raman spectroscopy and photoluminesence analysis. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Observation of the second harmonic in the phase dependence of a superconducting current in Nb/Au/YBCO heterojunctions

The second harmonic in the dependence of a superconducting current on the phase difference of superconducting wave functions of the electrodes was observed experimentally in Nb/Au/(001)YBa₂Cu₃O_x heterojunctions. Possible reasons for its appearance were discussed within the framework of a mixed (d±s) symmetry order parameter of YBa₂Cu₃O_x.     

Changes in Isoflavone Profile from Soybean Seeds during Cheonggukjang Fermentation Based on High-Resolution UPLC-DAD-QToF/MS: New Succinylated and Phosphorylated Conjugates

In this study, thirty-eight isoflavone derivatives were comprehensively identified and quantified from the raw, steamed and fermented seeds of four selected soybean cultivars based on UPLC-DAD-QToF/MS results with reference to the previously reported LC-MS library and flavonoid database, and summarized by acylated group including glucosides (Glu), malonyl-glucosides (Mal-Glu), acetyl-glucosides (Ac-Glu), succinyl-glucosides (Suc-Glu) and phosphorylated conjugates (Phos) in addition to aglycones. Among them, Suc-Glu and Phos derivatives were newly generated due to fermentation by B. subtilis AFY-2 (cheonggukjang). In particular, Phos were characterized for the first time in fermented soy products using Bacillus species. From a proposed roadmap on isoflavone-based biotransformation, predominant Mal-Glu (77.5–84.2%, raw) decreased rapidly by decarboxylation and deesterification into Ac-Glu and Glu (3.5–8.1% and 50.0–72.2%) during steaming, respectively. As fermentation continued, the increased Glu were mainly succinylated and phosphorylated as well as gradually hydrolyzed into their corresponding aglycones. Thus, Suc-Glu and Phos (17.3–22.4% and 1.5–5.4%, 36 h) determined depending on cultivar type and incubation time, and can be considered as important biomarkers generated during cheonggukjang fermentation. Additionally, the changes of isoflavone profile can be used as a fundamental report in applied microbial science as well as bioavailability research from fermented soy foods.     

Identification of New Non-BBB Permeable Tryptophan Hydroxylase Inhibitors for Treating Obesity and Fatty Liver Disease

Serotonin (5-hydroxytryptophan) is a hormone that regulates emotions in the central nervous system. However, serotonin in the peripheral system is associated with obesity and fatty liver disease. Because serotonin cannot cross the blood-brain barrier (BBB), we focused on identifying new tryptophan hydroxylase type I (TPH1) inhibitors that act only in peripheral tissues for treating obesity and fatty liver disease without affecting the central nervous system. Structural optimization inspired by para-chlorophenylalanine (pCPA) resulted in the identification of a series of oxyphenylalanine and heterocyclic phenylalanine derivatives as TPH1 inhibitors. Among these compounds, compound 18i with an IC₅₀ value of 37 nM was the most active in vitro. Additionally, compound 18i showed good liver microsomal stability and did not significantly inhibit CYP and Herg. Furthermore, this TPH1 inhibitor was able to actively interact with the peripheral system without penetrating the BBB. Compound 18i and its prodrug reduced body weight gain in mammals and decreased in vivo fat accumulation.     

Diffraction of the Fundamental Waveguide Wave on an Inductive Cylinder in a Rectangular Waveguide

Computational Mathematics and Modeling - We apply the integral equation method to the diffraction of a waveguide wave on an impedance inductive cylinder in a rectangular waveguide. The...