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131.
Crystalline Isotactic Polar Polypropylene from the Palladium‐Catalyzed Copolymerization of Propylene and Polar Monomers 下载免费PDF全文
Yusuke Ota Dr. Shingo Ito Dr. Minoru Kobayashi Dr. Shinichi Kitade Kazuya Sakata Takao Tayano Prof. Kyoko Nozaki 《Angewandte Chemie (International ed. in English)》2016,55(26):7505-7509
Moderately isospecific homopolymerization of propylene and the copolymerization of propylene and polar monomers have been achieved with palladium complexes bearing a phosphine‐sulfonate ligand. Optimization of substituents on the phosphorus atom of the ligand revealed that the presence of bulky alkyl groups (e.g. menthyl) is crucial for the generation of high‐molecular‐weight polypropylenes (Mw≈104), and the substituent at the ortho‐position relative to the sulfonate group influences the molecular weight and isotactic regularity of the obtained polypropylenes. Statistical analysis suggested that the introduction of substituents at the ortho‐position relative to the sulfonate group favors enantiomorphic site control over chain end control in the chain propagation step. The triad isotacticity could be increased to mm=0.55–0.59, with formation of crystalline polar polypropylenes, as supported by the presence of melting points and sharp peaks in the corresponding X‐ray diffraction patterns. 相似文献
132.
Satoshi Kamiguchi Ikuko Takahashi Sayoko Nagashima Atsushi Nakamura Teiji Chihara 《Journal of Cluster Science》2007,18(4):935-945
Piperidine was reacted with methanol under a hydrogen stream in the presence of (H3O)2[(W6Cl8)Cl6]·6H2O supported on silica gel. When the temperature was raised above 200 °C, the catalytic activity of the cluster appeared. Piperidine N-methylation proceeded yielding N-methylpiperidine in 95% selectivity at 350 °C. The corresponding halide clusters of niobium, molybdenum, and tantalum supported on silica gel also catalyzed the reaction. Primary alcohols such as ethanol and 1-propanol produced the corresponding N-alkyl products of piperidine; however, secondary and tertiary alcohols did not. Selective N-methylation of pyrrolidine, hexamethyleneimine, butylamine, and aniline also proceeded. Thus, the clusters catalyzed alkylation of aliphatic, alicyclic, and aromatic amines with primary alcohols. A Brønsted acid site attributable to a hydroxo ligand, which is formed on the cluster complex by thermal activation, is proposed as the active site of the catalyst. 相似文献
133.
Antje Ota Ronald Beyer Ulrich Hageroth Alexandra Müller Patricija Tomasic Frank Hermanutz Michael R. Buchmeiser 《先进技术聚合物》2021,32(1):335-342
We describe the wet and dry‐wet spinning of multifilament cellulosic composite fibers, namely chitin/cellulose fibers. The direct solution process for the two biopolymers based on an ionic liquid as solvent represents an environmentally friendly and alternative technology to the industrially applied viscose and lyocell process. Both cellulose and chitin possess good solubility in 1‐ethyl‐3‐methylimidazolium propionate ([C2C1Im][OPr]) and were spun into multifilament composite fibers. Moreover, for the first time, pure chitin multifilament fibers were obtained by dry‐wet spinning. The effect of chitin addition on the filament properties was investigated and evaluated by microscopic, spectroscopic, and mechanical analyses. 相似文献
134.
Development of a neutron generating target for compact neutron sources using low energy proton beams
135.
Matsuoka S Ota Y Washio A Katada A Ichioka K Takagi K Suzuki M 《Organic letters》2011,13(14):3722-3725
Highly selective tail-to-tail dimerization of methyl methacrylate has been realized by an N-heterocyclic carbene catalyst, giving dimethyl 2,5-dimethyl-2-hexenedioate with an E/Z ratio of 95:5 in 86% isolated yield. The umpolung mechanism is proposed on the basis of interception of the intermediates using ESI-MS analyses and deuterium-labeling experiments. 相似文献
136.
The abilities of multifunctional polyelectrolytes to enhance aluminum hydroxide dispersion and inhibit silica scale formation were examined in a pilot cooling water system. The following multifunctional polyelectrolytes were studied: a terpolymer of acrylic acid (AA), 2-acrylamide-2-methyl propane sulfonic acid (SA) and N-vinylpyrrolidone (NVP) (P(AA/SA/NVP)), acrylic acid homopolymer (P(AA)) and a copolymer of AA and SA (P(AA/SA)). The order of inhibition ability was P(AA/SA/NVP)>P(AA/SA)>P(AA), and was consistent with that of the dispersing ability for aluminum hydroxide. Other terpolymers incorporating different nonionic monomers were also examined and factors affecting their inhibition abilities were investigated, based on interaction energies calculated by density functional theory. Based on the correlation between scale inhibition abilities and interaction energies, we elucidated that the effective nonionic monomer of terpolymer for silica scale inhibition had low affinity for aluminum hydroxide and high affinity for H(2)O and Si(OH)(3)O(-). The affinities of nonionic monomer for aluminum hydroxide and H(2)O suggested that there was proper conformation of polyelectrolyte adsorbed for effectively dispersing aluminum hydroxide. Also, high affinity of nonionic monomer for Si(OH)(3)O(-) suggested that interacting Si(OH)(3)O(-) is an important role of inhibition of silica scale formation. 相似文献
137.
138.
Shibata M Hashi S Nakanishi H Masuda S Katsura T Yano I 《Biomedical chromatography : BMC》2012,26(12):1519-1528
The purpose of this study was to develop an ultra‐performance liquid chromatography tandem mass spectrometry (UPLC‐MS/MS) method of 22 antiepileptics for routine therapeutic monitoring. The antiepileptics used in the analyses were carbamazepine, carbamazepine‐10,11‐epoxide, clobazam, N‐desmethylclobazam, clonazepam, diazepam, N‐desmethyldiazepam, ethosuximide, felbamate, gabapentin, lamotrigine, levetiracetam, N‐desmethylmesuximide, nitrazepam, phenobarbital, phenytoin, primidone, tiagabine, topiramate, valproic acid, vigabatrin and zonisamide. After protein precipitation of 50 μL plasma with methanol, the supernatant was diluted with water or was evaporated to dryness and reconstituted with mobile phase in the case of benzodiazepines. Separation was achieved on an Acquity UPLC BEH C18 column with a gradient mobile phase of 10 mm ammonium acetate containing 0.1% formic acid and methanol at a flow rate of 0.4 mL/min. An Acquity TQD instrument in multiple reaction monitoring mode with ion mode switching was used for detection. All antiepileptics were detected and quantified within 10 min, with no endogenous interference. All the calibration curves showed good linearity in the therapeutic range (r2 < 0.99). The precision and accuracy values for intra‐ and inter‐assays were within ±15% except for phenobarbital and tiagabine. A good correlation was observed between the concentration of clinical samples measured by the new method described here and the conventional methods. The values of carbamazepine and phenytoin by UPLC‐MS/MS were lower than those detected by the immunoassays, which might be caused by the cross‐reaction of antibodies with their metabolites. In conclusion, we developed a simple and selective UPLC‐MS/MS method suitable for routine therapeutic monitoring of antiepileptics. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
139.
Y. Ichikawa H. C. Bhang S. Bufalino H. Ekawa P. Evtoukhovitch A. Feliciello H. Fujioka S. Hasegawa S. Hayakawa R. Honda K. Hosomi K. Imai S. Ishimoto C. W. Joo S. Kanatsuki R. Kiuchi T. Koike H. Kumawat Y. Matsumoto K. Miwa M. Moritsu T. Nagae M. Naruki M. Niiyama Y. Nozawa R. Ota A. Sakaguchi H. Sako V. Samoilov S. Sato K. Shirotori H. Sugimura S. Suzuki T. Takahashi T. N. Takahashi H. Tamura T. Tanaka K. Tanida A. O. Tokiyasu Z. Tsamalaidze B. J. Roy M. Ukai T. O. Yamamoto S. B. Yang 《Few-Body Systems》2013,54(7-10):1191-1194
In the J-PARC E27 experiment, we search for a K ? pp bound state via the d(π +, K +) reaction at 1.7 GeV/c at the K1.8 beam line. The binding energy and decay width of the K ? pp bound state can be obtained in the missing mass measurement with a good energy resolution of 2 MeV/c 2. A range counter array (RCA) was constructed to detect the two high-momentum protons from the K ? pp decay and to reduce the background such as quasi-free hyperon production. Recently, we have carried out a pilot run in June, 2012. The d(π +, K +) missing-mass spectrum has been obtained for the first time. In this report, an overview of the E27 experiment and a preliminary result on this pilot run are presented. 相似文献
140.
K. Uchida T. Ota K. Harii S. Takahashi S. Maekawa Y. Fujikawa E. Saitoh 《Solid State Communications》2010,150(11-12):524-528
The spin-Seebeck effect (SSE) converts a heat current into a spin current, a flow of spin angular momentum, and spin voltage, the driving force for nonequilibrium spin currents, in a ferromagnetic metal. In this study, the SSE in a ferromagnetic Ni81Fe19 film has been investigated by means of the inverse spin-Hall effect (ISHE) in a Pt film at room temperature. The experimental results measured in the Ni81Fe19/Pt system show that the sign of the thermally induced spin voltage is reversed between the higher- and lower-temperature ends of the Ni81Fe19 film. The ISHE in the Pt film allows us to detect the SSE signal with high sensitivity and to separate it from extrinsic thermoelectric effects. 相似文献