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51.
We have investigated the structure of spider dragline silk by X-ray diffraction over a broad temperature range from room temperature
up to thermal denaturation conditions. The dominating signal from the β-sheet crystallites is analyzed. Pronounced changes
of scattering intensity starting at temperatures around 150 °C are observed. These changes are discussed in view of the respective
lattice constants, crystal size, size distribution, crystallite number density and amino acid composition.
PACS 87.68.+z; 87.15.-v; 87.64.Bx 相似文献
52.
Tibor Cserháti 《Analytical and bioanalytical chemistry》1994,349(10-11):751-755
The interaction between 23 anticancer drugs and acetyl-β-cyclodextrin (acetyl-β-CD) was studied by reversed-phase charge-transfer thin-layer chromatography and the relative strength of interaction was calculated. Acetyl-β-CD formed inclusion complexes with 16 compounds, the complex always being more hydrophilic than the uncomplexed drug. The inclusion forming capacity of drugs differed considerably according to their chemical structure. The significant linear correlation between the hydrophobicity and specific hydrophobic surface area of anticancer drugs indicated that they can be considered as a homologous series of compounds, however, their chemical structures are highly different. 相似文献
53.
54.
The validity of local parton-hadron duality within the framework of HERWIG and JETSET event generators is investigated. We concentrate one
+
e
– annihilations in LEP 2 energy range as these interactions provide theoretically the cleanest condition for the discussion of this concept. We conclude that the concept of local parton-hadron duality is not valid in either of the two generators considered. 相似文献
55.
Š. Jakševičius 《Lithuanian Mathematical Journal》1992,32(2):174-180
Kaunas Academy of Agriculture, 4324 Noreikiškés, Lithuania. Translated from Lietuvos Matematikos Rinkinys, Vol. 32, No. 2,
pp. 221–228, April–June, 1992. 相似文献
56.
Igor V. Bliznets Grigory G. Aleksandrov Sergey M. Lukyanov 《Tetrahedron letters》2004,45(49):9127-9130
2-Methyl-3-cyanopyridines were converted into the corresponding 2-azidomethyl derivatives, which then underwent an intramolecular cycloaddition reaction. A novel heterocyclic system containing a 3-(tetrazol-5-yl)pyridine unit was obtained in this way. 相似文献
57.
František Toman Ludvík Beneš 《Journal of inclusion phenomena and macrocyclic chemistry》2007,59(3-4):231-236
Differential molar adsorption enthalpies (DMAE) were determined by gas chromatographic measurements of specific retention
volume of vapors on the surface of two forms of Mg–Al hydrotalcite. A linear dependence of the DMAE on the number of the carbon
atoms in hydrocarbons was observed for both form of hydrotalcite. The dependence of the differential molar adsorption enthalpies
on the number of chlorine atoms in organic molecules is discussed. A linear dependence of DMAE on the molecular weight of
chloroderivatives of methane and ethylene on the basic form in an order monochloromethane < dichloromethane < trichloromethane
or vinylidene chloride < 1,1-dichloroethylene < trichloroethylene was found. 相似文献
58.
In this paper we construct the linear support vector machine (SVM) based on the nonlinear rescaling (NR) methodology (see
[Polyak in Math Program 54:177–222, 1992; Polyak in Math Program Ser A 92:197–235, 2002; Polyak and Teboulle in Math Program
76:265–284, 1997] and references therein). The formulation of the linear SVM based on the NR method leads to an algorithm
which reduces the number of support vectors without compromising the classification performance compared to the linear soft-margin
SVM formulation. The NR algorithm computes both the primal and the dual approximation at each step. The dual variables associated
with the given data-set provide important information about each data point and play the key role in selecting the set of
support vectors. Experimental results on ten benchmark classification problems show that the NR formulation is feasible. The
quality of discrimination, in most instances, is comparable to the linear soft-margin SVM while the number of support vectors
in several instances were substantially reduced. 相似文献
59.
For the first time, the fractional order disturbance observer (FO-DOB) is proposed for vibration suppression applications such as hard disk drive servo control. It has been discovered in a recently published US patent application (US20010036026) that there is a tradeoff between phase margin loss and strength of the low frequency vibration suppression. Given the required cutoff frequency of the low pass filter, also known as the Q-filter, it turns out that the relative degree of the Q-filter is the major tuning knob for this tradeoff. The solution in US20010036026 was based on an integer order Q-filter with a variable relative degree. This actually motivated the use of a fractional order Q-filter. The fractional order disturbance observer is based on the fractional order Q-filter. The implementation issue is also discussed. The nice point of this paper is that the traditional DOB is extended to the fractional order DOB with the advantage that the FO-DOB design is now no longer conservative nor aggressive, i.e., given the cutoff frequency and the desired phase margin, we can uniquely determine the fractional order of the low pass filter. 相似文献
60.
The paper is devoted to the research of large deviation probabilities in the approximation by compound Poisson law. 相似文献