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991.
Biljana Jančić-Stojanović Igor Popović Anđelija Malenović Darko Ivanović Mirjana Medenica 《Chromatographia》2010,71(9-10):799-804
In this paper optimization of chromatographic retention of ramipril and its five impurities employing factorial design is presented. On the basis of preliminary experiments three factors were chosen as inputs (acetonitrile content, pH of the mobile phase and buffer concentration) and retention factor as output. As optimal full factorial design 23 was chosen, factors were examined at two different levels “low” and “high”. Three replications at zero level were added in order to check linearity and complete statistical tests. Relationship between inputs and output is presented in form of second order interaction model. Adequacy of model was explained using analysis of variance. After analysis of results optimal chromatographic conditions were set. Separations were conducted on a C18 column with a mixture of acetonitrile and water phase (TEA in potassium dihydrogen phosphate) in ratio 23:77 v/v. Finally, the LC method was validated and applied for quality control analysis of commercially available tablets. The proposed method is simpler and faster as compared to existing official methods and therefore more adequate for routine control of ramipril during shelf life. Also a general approach which includes factorial design in method optimization offers a possibility for predicting and following the chromatographic behavior of such complex mixtures. 相似文献
992.
Magnetic resonance imaging (MRI) is a very powerful instrument used extensively in modern medical diagnostics because of its ability to look inside a body in a non-invasive and non-destructive way. Furthermore, MRI is more than just a single tool for extracting structural information. It is more of a sophisticated and versatile toolkit able to provide all sorts of useful information about the internal properties of an object under study and various processes within it, including heat and mass transport, composition and chemical transformations, in a spatially resolved mode. While a living body is different from a catalyst body or a reactor, the in situ and Operando studies in catalysis can clearly benefit from the use of this non-destructive toolkit as a powerful complement to other available spectroscopic tools. This tutorial review gives an introduction to the field and describes the examples of the applications of MRI to the studies of the preparation, deactivation and regeneration of solid catalysts and to the spectroscopy, thermometry and imaging studies of heterogeneous catalysts and model catalytic reactors performed during actual catalytic processes. 相似文献
993.
Buha J Arčon D Niederberger M Djerdj I 《Physical chemistry chemical physics : PCCP》2010,12(47):15537-15543
A simple route to niobium, hafnium and tantalum oxide nanocrystals using a nonaqueous sol-gel route based on the solvothermal reaction of the corresponding metal chlorides with benzyl alcohol is presented. This approach can easily be extended to the preparation of high quality Co-doped HfO(2) nanoparticles of uniform size and shape and with a homogenous distribution of the magnetic ions. The structural characterization of all these nanomaterials as well as the magnetic properties of pure and doped hafnia, with special attention to the doping efficiency, are discussed. The obtained Co-doped hafnia exhibits paramagnetic properties with very weak antiferromagnetic interactions between Co ions moments. 相似文献
994.
NMR modulated gradient spin echo method, which allows the quantification of polymer segmental displacement via the measurement of the velocity autocorrelation, requires the formulation of theoretical predictions in the frequency domain in order to test their validity. We worked out the velocity autocorrelation spectrum of the segmental motion according to the Rouse and the tube/reptation model to compare it to the experimental results obtained by the new NMR technique. The analysis of polybutadiene shows the segmental velocity autocorrelation spectrum typical for the reptation-like motion of polymer in a “tube”. The measurement of bulk water indicates a kind of Rouse motion in a network of hydrogen bonds. 相似文献
995.
The use of semiconductor quantum dots (QDs) in biological sensing and labeling continues to grow with each year. Current and
projected applications include use as fluorescent labels for cellular labeling, intracellular sensors, deep-tissue and tumor
imaging agents, sensitizers for photodynamic therapy, and more recently interest has been sparked in using them as vectors
for studying nanoparticle-mediated drug delivery. Many of these applications will ultimately require the QDs to undergo targeted
intracellular delivery, not only to specific cells, but also to a variety of subcellular compartments and organelles. It is
apparent that this issue will be critical in determining the efficacy of using QDs, and indeed a variety of other nanoparticles,
for these types of applications. In this review, we provide an overview of the current methods for delivering QDs into cells.
Methods that are covered include facilitated techniques such as those that utilize specific peptide sequences or polymer delivery
reagents and active methods such as electroporation and microinjection. We critically examine the benefits and liabilities
of each strategy and illustrate them with selected examples from the literature. Several important related issues such as
QD size and surface coating, methods for QD biofunctionalization, cellular physiology and toxicity are also discussed. Finally,
we conclude by providing a perspective of how this field can be expected to develop in the future. 相似文献
996.
We consider solutions to the linear wave equation □g? = 0 on a (maximally extended) Schwarzschild spacetime with parameter M > 0, evolving from sufficiently regular initial data prescribed on a complete Cauchy surface Σ, where the data are assumed only to decay suitably at spatial infinity. (In particular, the support of ? may contain the bifurcate event horizon.) It is shown that the energy flux F(??) of the solution (as measured by a strictly timelike T? that asymptotically matches the static Killing field) through arbitrary achronal subsets ?? of the black hole exterior region satisfies the bound F(??) ≤ C E(v + u), where v and u denote the infimum of the Eddington‐Finkelstein advanced and retarded time of ??, v+ denotes max{1, v}, and u+ denotes max{1, u}, where C is a constant depending only on the parameter M, and E depends on a suitable norm of the solution on the hypersurface t ? u + v = 1. (The bound applies in particular to subsets ?? of the event horizon or null infinity.) It is also shown that ? satisfies the pointwise decay estimate |?| ≤ C Ev in the entire exterior region, and the estimates |r?| ≤ CR?E(1 + |u|)?1/2 and |r1/2?| ≤ CR?Eu in the region {r ≥ R?} ∩ J+(Σ) for any R? > 2M. The estimates near the event horizon exploit an integral energy identity normalized to local observers. This estimate can be thought to quantify the celebrated red‐shift effect. The results in particular give an independent proof of the classical result |?| ≥ C E of Kay and Wald without recourse to the discrete isometries of spacetime. © 2009 Wiley Periodicals, Inc. 相似文献
997.
998.
An approach based on cavity compliance contribution tensor is utilized for evaluation of effective stiffness of anisotropic materials with irregularly shaped pores. The shapes considered in the present work were extracted from the X-ray computed microtomography of a carbon/carbon composite sample. The cavity contribution tensors of individual pores were calculated numerically and then employed in the micromechanical modeling procedure. It was shown that presence of pores with total porosity of p = 9.13% results in approximately 20% reduction in the material's Young's moduli. (© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
999.
Igor Vigdorovich 《PAMM》2011,11(1):605-606
Self-similar flows in a turbulent boundary layer when the free-stream velocity is specified as a power function of longitudinal coordinate are investigated. The self-similar formulation not only simplifies solving of the problem by reducing the equations of motion to ordinary differential equations but also provides a mean for formulating closure conditions. It is shown that for the class of flows under consideration that depend on three governing parameters the dimensionless mixing length is a function of the normalised distance from the wall and the exponent in the law specifying the free-stream velocity distribution in the outer region and a universal function of local Reynolds number in the wall region, the latter corollary being true even when the skin friction vanishes. In calculations this function is set to be independent of pressure gradient, which gives the results very close to experimental data. There exist four different self-similar flow regimes. Each regime is related to its similarity parameter, one of which is the well-known Clauser equilibrium parameter and the other three are established for the first time. In case of adverse pressure gradient when the exponent lies within certain limits, which depend on Reynolds number, the problem has two solutions with different values of the boundary layer thickness and skin friction, which points out the possibility of hysteresis in near-separating flow. Separation occurs not at the minimum value of the exponent that corresponds to the strongest adverse pressure gradient but at a higher one whose dependence on Reynolds number is calculated in the paper. The results of the theory are in good agreement with experimental data. (© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
1000.
Perepichka IF Roquet S Leriche P Raimundo JM Frère P Roncali J 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(11):2960-2966
The dimer and trimer of 3,4-phenylenedioxythiophene (PheDOT) have been synthesized. Unlike the parent systems based on 3,4-ethylenedioxythiophene (EDOT), these compounds are quite stable under atmospheric conditions. The electronic absorption spectra of di- and tri-PheDOT exhibit a well-resolved vibronic fine structure indicative of self-rigidification of the conjugated structure by noncovalent intramolecular sulfur-oxygen interactions. Comparison of UV-visible data for the PheDOT oligomers with those of the corresponding EDOT oligomers reveals a faster decrease of the HOMO-LUMO gap with chain length for the former. Cyclic voltammetric data show that whereas PheDOT oxidizes at a lower potential than EDOT, the PheDOT dimer and trimer exhibit much higher oxidation potentials than their EDOT-based analogues. A comparative analysis of the electropolymerization of the three PheDOT-based systems shows that although PheDOT is very difficult to polymerize, its dimer and trimer can be readily electropolymerized. This unexpected increase of reactivity with chain extension is discussed with the aid of theoretical calculations. 相似文献