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Molecular dynamics simulation of poly(3‐hexylthiophene) helical structure In Vacuo and in amorphous polymer surrounding 下载免费PDF全文
Natalia I. Borzdun Sergey V. Larin Stanislav G. Falkovich Victor M. Nazarychev Igor V. Volgin Alexander V. Yakimansky Alexey V. Lyulin Vikas Negi Peter A. Bobbert Sergey V. Lyulin 《Journal of Polymer Science.Polymer Physics》2016,54(23):2448-2456
The stability of poly(3‐hexylthiophene) (P3HT) helical structure has been investigated in vacuo and in amorphous polymer surrounding via molecular dynamics‐based simulations at temperatures below and above the P3HT melting point. The results show that the helical chain remains stable at room temperature both in vacuo and in amorphous surrounding, and promptly loses its structure at elevated temperatures. However, the amorphous surrounding inhibits the destruction of the helix at higher temperatures. In addition, it is shown that the electrostatic interactions do not significantly affect the stability of the helical structure. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 2448–2456 相似文献
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Back Cover: Single‐Atom Gold Catalysis in the Context of Developments in Parahydrogen‐Induced Polarization (Chem. Eur. J. 19/2015) 下载免费PDF全文
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The edge‐percolation and vertex‐percolation random graph models start with an arbitrary graph G, and randomly delete edges or vertices of G with some fixed probability. We study the computational complexity of problems whose inputs are obtained by applying percolation to worst‐case instances. Specifically, we show that a number of classical ‐hard problems on graphs remain essentially as hard on percolated instances as they are in the worst‐case (assuming ). We also prove hardness results for other ‐hard problems such as Constraint Satisfaction Problems and Subset‐Sum, with suitable definitions of random deletions. Along the way, we establish that for any given graph G the independence number and the chromatic number are robust to percolation in the following sense. Given a graph G, let be the graph obtained by randomly deleting edges of G with some probability . We show that if is small, then remains small with probability at least 0.99. Similarly, we show that if is large, then remains large with probability at least 0.99. We believe these results are of independent interest. 相似文献
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Intra‐ and inter‐supramolecular complexation of poly(butyl methacrylate)‐co‐2‐(1,2,3‐triazol‐4‐yl)pyridine copolymers induced by CoII,FeII, and EuIII ions monitored by molecular hydrodynamics methods 下载免费PDF全文
Georges M. Pavlov Igor Perevyazko Bobby Happ Ulrich S. Schubert 《Journal of polymer science. Part A, Polymer chemistry》2016,54(16):2632-2639
Poly(butyl methacrylate) copolymers embedding bidentate 2‐(1,2,3‐triazol‐4‐yl)pyridine (trzpy) chelating units as comonomer in the side chains were synthesized by controlled radical addition‐fragmentation transfer (RAFT) polymerization. Intracomplexation and intercomplexation of the macromolecules of the poly(butyl methacrylate) copolymers containing 20 % mol of trzpy units induced by CoII, FeII, and EuIII ions were studied in the solutions by macromolecular hydrodynamics methods. The sedimentation velocity of extremely diluted copolymer solutions and the dynamic viscosity of moderately diluted solutions were studied in a wide range of the salts concentrations. Differences were observed with respect to the copolymer behavior in the presence of the Co2+, Fe2+, Eu3+ ions. These differences are namely due to the differences in the number of coordination bonds required for complex formation and not explicitly to the nature of the corresponding anions. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 2632–2639 相似文献
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Michael I. Mishchenko Li Liu Igor V. Geogdzhayev Jing Li Barbara E. Carlson Andrew A. Lacis Brian Cairns Larry D. Travis 《Journal of Quantitative Spectroscopy & Radiative Transfer》2012,113(15):1974-1980
The nominal Global Aerosol Climatology Project (GACP) record of aerosol optical thickness (AOT) and Ångström exponent (AE) over the oceans is extended by 6 months to cover the period from August 1981 through December 2005. The most recent 4-year segment reveals no significant short-term tendencies in globally and hemispherically averaged AOTs and AEs. This finding is consistent with contemporaneous MODIS and MISR results and the accumulating evidence of a gradual transition from global brightening to global dimming. We also analyze the retrieval implications of allowing the imaginary part of the aerosols refractive index Im(m) to change over the duration of the GACP record. Our sensitivity study shows that increasing Im(m) from 0.003 during the 4-year pre-Pinatubo period up to 0.007 during the most recent 4-year segment of GACP data eliminates the previously identified long-term decreasing AOT trend. Should this long-term trend in Im(m) be real then it would cause the global absorption AOT over the oceans to more than double and the global single-scattering albedo to decrease from ~0.95 to ~0.88. Such changes could make tropospheric aerosols significant contributors to the recent surface temperature increase. 相似文献