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61.
Flavonoid glycosides from Persea caerulea. Unraveling their interactions with SDS‐micelles through matrix‐assisted DOSY,PGSE, mass spectrometry,and NOESY 下载免费PDF全文
Juan M. Álvarez Álvaro Raya‐Barón Pedro M. Nieto Luis E. Cuca Alberto Fernández‐Gutiérrez Ignacio Fernández 《Magnetic resonance in chemistry : MRC》2016,54(9):718-728
Two flavonoid glycosides derived from rhamnopyranoside ( 1 ) and arabinofuranoside ( 2 ) have been isolated from leaves of Persea caerulea for the first time. The structures of 1 and 2 have been established by 1H NMR, 13C NMR, and IR spectroscopy, together with LC–ESI–TOF and LC–ESI–IT MS spectrometry. From the MS and MS/MS data, the molecular weights of the intact molecules as well as those of quercetin and kaempferol together with their sugar moieties were deduced. The NMR data provided information on the identity of the compounds, as well as the α and β configurations and the position of the glycosides on quercetin and kaempferol. We have also explored the application of sodium dodecyl sulfate (SDS) normal micelles in binary aqueous solution, at a range of concentrations, to the diffusion resolution of these two glycosides, by the application of matrix‐assisted diffusion ordered spectroscopy (DOSY) and pulse field gradient spin echo (PGSE) methodologies, showing that SDS micelles offer a significant resolution which can, in part, be rationalized in terms of differing degrees of hydrophobicity, amphiphilicity, and steric effects. In addition, intra‐residue and inter‐residue proton–proton distances using nuclear Overhauser effect build‐up curves were used to elucidate the conformational preferences of these two flavonoid glycosides when interacting with the micelles. By the combination of both diffusion and nuclear Overhauser spectroscopy techniques, the average location site of kaempferol and quercetin glycosides has been postulated, with the former exhibiting a clear insertion into the interior of the SDS‐micelle, whereas the latter is placed closer to the surface. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
62.
Barluenga J Aznar F Gutiérrez I García-Granda S Llorca-Baragaño MA 《Organic letters》2002,4(24):4273-4276
[reaction: see text] The first cyclopropanation reaction of olefins with Fischer dialkylaminocarbene complexes is presented. The reaction yields 1-aminocyclopropanecarboxylic acid derivatives in a single step, usually with high diastereoselectivity. An approach to the asymmetric version of this reaction is also presented. The synthetic utility of the procedure is exemplified by the synthesis of both cycles of metanoproline in a single step. In addition, the synthesis of the first Fischer carbene containing a halocarbonyl group is reported. 相似文献
63.
Fundamental Group for Some Cuspidal Curves 总被引:1,自引:0,他引:1
In [1], Hirano gives a method for constructing families of curveswith a large number of singularities. The idea is to consideran abelian covering of P2 ramified along three lines in generalposition, and to take the pull-back of a curve C intersectingthe lines non-generically. Similar constructions are used byShimada in [10] and Oka in [8]. We apply this method for thecase where C is a conic, constructing a family of curves withthe following asymptotic behaviour (see [9]):
The goal of this paper is to calculate the fundamentalgroup for the curves in this family as well as their Alexanderpolynomial. 1991 Mathematics Subject Classification 14H20, 14H30,14E20. 相似文献
64.
Daniel Carando Ignacio Zalduendo 《Proceedings of the American Mathematical Society》1999,127(1):241-250
We study the problem of extendibility of polynomials over Banach spaces: when can a polynomial defined over a Banach space be extended to a polynomial over any larger Banach space? To this end, we identify all spaces of polynomials as the topological duals of a space spanned by evaluations, with Hausdorff locally convex topologies. We prove that all integral polynomials over a Banach space are extendible. Finally, we study the Aron-Berner extension of integral polynomials, and give an equivalence for non-containment of .
65.
We define the concept of fuzzy nilpotent algebra, prove that the homomorphic inverse image of a fuzzy nilpotent algebra is also nilpotent and study the intersection and union of fuzzy nilpotent algebras. 相似文献
66.
An improved, isomer-free synthesis of Tetrahydrometinoxocrinine () is described. 相似文献
67.
B. Melić K. Passek-Kumerički J. Trampetić P. Schupp M. Wohlgenannt 《The European Physical Journal C - Particles and Fields》2005,42(4):499-504
This paper is a direct extension of our earlier work on electroweak currents and the Higgs sector in the standard model on non-commutative space-time, now with strong interactions included. Apart from the non-commutative corrections to standard model strong interactions, several new interactions appear. The most interesting ones are gluonic interactions with the electroweak sector. They are elaborated here in detail and the Feynman rules for interactions up to
are provided.Received: 18 March 2005, Revised: 13 May 2005, Published online: 19 July 2005 相似文献
68.
In this Note we obtain existence and uniqueness results for the Helmholtz equation in the half-space with an impedance or Robin boundary condition. Basically, we follow the procedure we have already used in the bi-dimensional case (the half-plane). Thus, we compute the associated Green's function with the help of a double Fourier transform and we analyze its far field in order to obtain radiation conditions that allow us to prove the uniqueness of an outgoing solution. Again, these radiation conditions are somewhat unusual due to the appearance of a surface wave guided by the boundary. An integral representation of the solution is presented by means of the Green's function and the boundary data. To cite this article: M. Durán et al., C. R. Acad. Sci. Paris, Ser. I 341 (2005). 相似文献
69.
Piotr?BilerEmail author Marco?Cannone Ignacio A.?Guerra Grzegorz?Karch 《Mathematische Annalen》2004,330(4):693-708
The existence of solutions of a nonlinear parabolic equation describing the gravitational interaction of particles is studied for the initial data in spaces of (generalized) pseudomeasures. This approach permits us to relax regularity assumptions on the initial conditions and to prove asymptotic stability results for the above problem.Mathematics Subject Classification (2000):35B40, 35K15, 82C21 相似文献
70.