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排序方式: 共有127条查询结果,搜索用时 15 毫秒
111.
A. M. Yusof N. H. Idris N. A. N. N. Malek A. K. H. Wood 《Journal of Radioanalytical and Nuclear Chemistry》2009,281(2):269-272
Column studies were performed to evaluate the performance of modified zeolite-Y with ion Fe (zeolite-FeY) in removing As(III),
As(V), Se(IV) and Se(VI) from groundwater. The removal capacities for zeolite-FeY was carried out on arsenic and selenium
species in aqueous solution by co-precipitation technique with DBDTC-Pp complex in the pH range of 1.5–2.5 followed by the
neutron activation analysis (NAA) using a TRIGA-MkII reactor with an average flux of 2.1 × 1012 neutrons cm−2 s−1 and inductively coupled plasma-mass spectrometry (ICP-MS) technique as comparison. The accuracy between the results obtained
from both techniques were compared and evaluated. 相似文献
112.
Azeez O. Idris Duduzile Nkosi Nobanathi Maxakato Omotayo A. Arotiba 《International journal of environmental analytical chemistry》2017,97(6):534-547
In this work, a simple experimental procedure was reported for the electroanalytical determination of selenium (IV) using reduced graphene oxide (rGO) to modify glassy carbon electrode (GCE). The rGO was obtained by reduction of graphene oxide obtained via Hummer’s method. The synthesised rGO was characterised using X-ray diffraction, Raman spectroscopy, scanning electron microscope (SEM), energy-dispersive spectroscopy and transmission Electron microscopy (TEM). GCE was modified with rGO and the electrochemical properties of the bare and modified electrode were investigated using cyclic voltammetry and electrochemical impedance spectroscopy. The results obtained showed that the modified electrode exhibited more excellent electrochemical properties than the bare GCE. The optimum conditions for detection of selenium in water using square wave anodic stripping voltammetry were as follows: deposition potential ?500 mV, pH 1, pre-concentration time of 240 s and 0.1 M nitric acid was used as supporting electrolyte. The linear regression equation obtained was I (µA) = 0.8432C + 9.2359 and the detection limit was calculated to be 0.85 μg L?1. However, Cu(II) and Cd(II) are the two cations that interfered in the analysis of selenium in water.The sensor was also applied for real sample water analysis and the result obtained was affirmed with inductively coupled plasma optical emission spectroscopic method. It is believed that our proposed sensor hold promise for practical application. 相似文献
113.
Aziman Eli Syafiqah Ismail Aznan Fazli Jubri Siti Fatimah Rahmat Muhammad Abdullah Idris Wan Mohd Razi 《Journal of Radioanalytical and Nuclear Chemistry》2021,330(3):667-683
Journal of Radioanalytical and Nuclear Chemistry - Comprehensive radiological survey and evaluation of heavy metal contamination were conducted in Chini Lake, which has been awarded a pristine... 相似文献
114.
Reactions of [Fe2(CO)6(μ-pdt)] (1) (pdt = SCH2CH2CH2S) and small bite-angle diphosphines have been studied. A range of products can be formed being dependent upon the nature of the diphosphine and reaction conditions. With bis(diphenylphosphino)methane (dppm), thermolysis in toluene leads to the formation of a mixture of bridge and chelate isomers [Fe2(CO)4(μ-dppm)(μ-pdt)] (2) and [Fe2(CO)4(κ2-dppm)(μ-pdt)] (3), respectively. Both have been crystallographically characterised, 3 being a rare example of a chelating dppm ligand in a first row binuclear system. At room temperature in MeCN with added Me3NO · 2H2O, the monodentate complex [Fe2(CO)5(κ1-dppm)(μ-pdt)] (4) is initially formed. Warming 4 to 100 °C leads the slow conversion to 2, while oxidation (on alumina) gives [Fe2(CO)5(κ1-dppmO)(μ-pdt)] (5). With bis(dicyclohexylphosphino)methane (dcpm), heating in toluene cleanly affords [Fe2(CO)4(μ-dcpm)(μ-pdt)] (6). With Me3NO · 2H2O in MeCN the reaction is not clean as the phosphine is oxidised but monodentate [Fe2(CO)5(κ1-dcpm)(μ-pdt)] (7) can be seen spectroscopically. With 1,2-bis(diphenylphosphino)benzene (dppb) and cis-1,2-bis(diphenylphosphino)ethene (dppv) the chelate complexes [Fe2(CO)4(κ2-dppb)(μ-pdt)] (8) and [Fe2(CO)4(κ2-dppv)(μ-pdt)] (9), respectively are the final products under all conditions, although a small amount of [Fe2(CO)5(κ2-dppvO)(μ-pdt)] (10) was also isolated. Protonation of 2 with HBF4 affords a cation with poor stability while with the more basic diiron centre in 6 readily forms the stable bridging-hydride complex [(μ-H)Fe2(CO)4(μ-dcpm)(μ-pdt)][BF4] (11) which has been crystallographically characterised. 相似文献
115.
Zebrafish (Danio rerio) is the widely used vertebrate model animal for understanding the complexity of development and disease process. Zebrafish has been also extensively used in understanding the mechanism of regeneration for its extensive capability of regenerating fins and other tissues. We have analyzed the proteome profile of zebrafish caudal fin in its native state based on one-dimensional gel electrophoresis LCMS/MS and two-dimensional gel electrophoresis MS/MS analyses. A total of 417 proteins were identified as zebrafish fin tissue specific, which includes 397 proteins identified based on one-dimensional gel electrophoresis LCMS/MS analysis and 101 proteins identified based on two-dimensional gel electrophoresis MALDI MS/MS. The proteins mapped to the zebrafish fin tissue were shown to be involved in various biological activities related to development, apoptosis, signaling and metabolic process. Focal adhesion, regulation of actin cytoskeleton, cancer-related pathways, mitogen-activated protein kinase signaling, antigen processing and presentation, and proteasome are some of the important pathways associated with the identified proteome data set of the zebrafish fin. 相似文献
116.
Cerkez I Kocer HB Worley SD Broughton RM Huang TS 《Langmuir : the ACS journal of surfaces and colloids》2011,27(7):4091-4097
Two N-halamine copolymer precursors, poly(2,2,6,6-tetramethyl-4-piperidyl methacrylate-co-acrylic acid potassium salt) and poly(2,2,6,6-tetramethyl-4-piperidyl methacrylate-co-trimethyl-2-methacryloxyethylammonium chloride) have been synthesized and successfully coated onto cotton fabric via a layer-by-layer (LbL) assembly technique. A multilayer thin film was deposited onto the fiber surfaces by alternative exposure to polyelectrolyte solutions. The coating was rendered biocidal by a dilute household bleach treatment. The biocidal efficacies of tested swatches composed of treated fibers were evaluated against Staphylococcus aureus and Escherichia coli. It was determined that chlorinated samples inactivated both S. aureus and E. coli O157:H7 within 15 min of contact time, whereas the unchlorinated control samples did not exhibit significant biocidal activities. Stabilities of the coatings toward washing and ultraviolet light exposure have also been studied. It was found that the stability toward washing was superior, whereas the UVA light stability was moderate compared to previously studied N-halamine moieties. The layer-by-layer assembly technique can be used to attach N-halamine precursor polymers onto cellulose surfaces without using covalently bonding tethering groups which limit the structure designs. In addition, ionic precursors are very soluble in water, thus promising for biocidal coatings without the use of organic solvents. 相似文献
117.
SA Idris K Alotaibi TA Peshkur P Anderson LT Gibson 《Journal of colloid and interface science》2012,386(1):344-349
Speciation and separation of chromium (VI) and chromium (III) from aqueous solutions were investigated using amino-propyl functionalised mesoporous silica (AP-MCM-41) as an adsorbent. The as-synthesised adsorbent was produced following a simple synthesis method at room temperature prior to template removal using microwave digestion. The maximum adsorption capacity at 111.1mg/g was calculated according to the Langmuir isotherm model, suggesting a 1:1 monolayer adsorption mechanism. Moreover, AP is a simple chelate, yet it can extract Cr (VI) exclusively from solutions containing other mixed metal ions simply by tuning the solution pH. Recovery of Cr (VI) from loaded sorbents is equally easy to perform with 100% extraction efficiencies allowing reuse of the sorbent and recovery of Cr (VI) from aqueous solutions containing a complex mixture of ions. The material would find use in environmental remediation applications, as a selective adsorbent of Cr (VI) or even as a solid-phase extraction stationary phase to remove and pre-concentrate Cr (VI) from aqueous solutions; this study demonstrates enrichment factors of 100 although higher levels are also possible. 相似文献
118.
This study is carried out to investigate the numerical solutions of the Kawahara, KdV‐Kawahara, and the modified Kawahara equations by using the meshless method based on collocation with radial basis functions. Results of the meshless method with different radial basis functions are presented for the travelling wave solution of the Kawahara type equations. © 2010 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 28: 542–553, 2012 相似文献
119.
The rate of dye adsorption from aqueous effluents onto palm kernel shell (PKS) activated carbon has been studied experimentally using the batch adsorption method. The adsorption rates of methylene blue on PKS for systems of different initial dye concentrations are modeled using a film-pore-concentration dependent surface diffusion (FPCDSD) model. The FPCDSD model is sufficiently general and can be reduced easily to describe other simplified models. Using the FPCDSD model, only a single set of mass transfer parameters is required to describe the methylene blue/PKS system for different initial concentrations. A different set of mass transfer parameters are needed to obtain the best fitting if the pore diffusion is not included in the model. 相似文献
120.
Mudasir A. Tantry Gulzar A. Bhat Ahmed Idris Javid A. Dar Suliman Yousef Al Omar Khalid Z. Masoodi Bashir A. Ganai Azra N. Kamili Abdul S. Shawl 《Helvetica chimica acta》2014,97(11):1497-1506
The hydroalcoholic (EtOH/H2O) extract of matured leaf margins of lemon balm (Melissa officinalis L.) afforded a new 3,23‐disulfate of 2α,3β‐23,29‐tetrahydroxyolean‐12‐en‐28‐oic acid 28‐O‐β‐D ‐glucopyranoside ( 1 ) and a new 23‐monosulfate of 2α,23‐dihydroxyurs‐12‐en‐28‐oic acid 3‐O‐β‐D ‐glucopyranoside ( 2 ), along with six known compounds, i.e., 23‐monosulfate of 2α,3β,19α,23‐tetrahydroxyurs‐12‐ene‐28‐oic acid 28‐O‐β‐D ‐glucopyranoside ( 3 ), 3,5,6‐trihydroxydehydro‐α‐ionol 9‐O‐β‐D ‐glucopyranoside ( 4 ), quadranoside III ( 5 ), rosmarinic acid ( 6 ), caffeic acid ( 7 ), and luteolin ( 8 ). All the isolated compounds were evaluated for their antioxidant, antimicrobial, antimalarial, and cytotoxic activities. Only rosmarinic acid exhibited substantial antioxidant and antimicrobial activities, whereas sulfated terpenes showed considerably lower or no antimicrobial activity. 相似文献