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41.
Ida Cattaneo Gasparini 《Annali di Matematica Pura ed Applicata》1960,50(1):467-473
Sunto Esame delle connessioni infinitesimali nello spazio fibrato dei riferimenti proiettivi di una Vn. Definizione di connessione proiettiva regolare Geodetiche di una Vn secondo una connessione proiettiva con speciale riguardo alle connessioni regolari.
Ad Antonio Signorini nel suo 70mo compleanno. 相似文献
42.
Direct beta-glucosidation between benzyl alcohol and D-glucose (5) using the immobilized beta-glucosidase from almonds with the synthetic prepolymer ENTP-4000 gave a benzyl beta-D-glucoside (1) in 53% yield. The coupling of the benzyl beta-D-glucopyranoside congener (8) derived from 1 with phenyl 2,3,4-tri-O-acetyl-1-thio-beta-D-xylopyranoside (9), ethyl 2,3,4-tri-O-acetyl-1-thio-alpha-L-rhamnopyranoside (13), and 2,3,4-tri-O-acetyl-alpha-L-arabinopyranosyl bromide (15) afforded 10, 14, and 16, respectively, as coupled products. Deprotection of 10, 14, and 16 provided the synthetic benzyl beta-D-xylopyranosyl-(1-->6)-beta-D-glucopyranoside (2), benzyl alpha-L-rhamnopyranosyl-(1-->6)-beta-D-glucopyranoside (3), and benzyl alpha-L-arabinopyranosyl-(1-->6)-beta-D-glucopyranoside (4), respectively. 相似文献
43.
Ida Cattaneo-Gasparini 《Annali di Matematica Pura ed Applicata》1964,65(1):81-96
Sunto Si studia, in ipotesi del tutto generali, la struttura quasi prodotto definita su una varietà differenziabile Vn da due campi di proiettori complessi φ
S
R
φ′
S
R
, legati dalla relazioneφ+φ′=Id, e si caratterizzano le connessioni vincolate alla struttura come quelle rispetto alle quali sono identicamente nulli
i differenziali assoluti dei proiettori. In particolare si definisce, tra tutte le connessioni vincolate, una connessione
canonicamente associata a una connessioni complessa preventivamente assegnata su Vn. Si mostra infine come il tensore caratterestico regolare della struttura H
S
R
≡φ′
S
R
−φ
S
R
individui, nello spazio tangente complessificato, una trasformazione involutoria che ha i caratteri di una simmetria rispetto
a uno dei due sottospazi localmente legati alla struttura.
Lavoro eseguito nell'ambito dell'attività del Gruppo di ricerca matematica No 1 del C. N. R. 相似文献
44.
Ida S Unal U Izawa K Altuntasoglu O Ogata C Inoue T Shimogawa K Matsumoto Y 《The journal of physical chemistry. B》2006,110(47):23881-23887
A number of interesting photoluminescence properties of titanate layered oxide intercalated with hydrated Eu3+ have been demonstrated. Photoluminescence intensity of Eu3+ decreased rapidly with time during irradiation by UV light having energy higher than the band gap energy of the host TiO (Ti(1.81)O4) layer. This is presumably due to the decrease in energy transfer from the host TiO layer to Eu3+ as a result of the change in the hydration state of water molecules surrounding Eu3+, which is caused by the hole produced in the TiO valence band. When irradiation was discontinued, the emission intensity gradually recovered. The recovery time increased when the water in the interlayer is removed by heat treatment. This indicates that the state of interlayer water changes during irradiation and returns to its initial state after discontinuation of irradiation. The excitation spectra changed drastically at any given wavelength upon irradiation with UV light. A comparison of the excitation spectra before and after irradiation reveals that only the excitation peak at around the irradiation wavelength decreased upon irradiation, as in the case of spectral hole burning. The hydration state of water molecules surrounding Eu3+ presumably changes depending on the irradiation wavelength, leading to the above spectral change because the Eu/TiO film has a superlattice structure producing holes with different energies. 相似文献
45.
A well-known theorem of de Bruijn and Erd?s states that any set of $n$ non-collinear points in the plane determines at least $n$ lines. Chen and Chvátal asked whether an analogous statement holds within the framework of finite metric spaces, with lines defined using the notion of betweenness. In this paper, we prove that the answer is affirmative for sets of $n$ points in the plane with the $L_1$ metric, provided that no two points share their $x$ - or $y$ -coordinate. In this case, either there is a line that contains all $n$ points, or $X$ induces at least $n$ distinct lines. If points of $X$ are allowed to share their coordinates, then either there is a line that contains all $n$ points, or $X$ induces at least $n/37$ distinct lines. 相似文献
46.
Ida K Sakamoto Y Takenaga H Oyama N Itoh K Yoshinuma M Inagaki S Kobuchi T Isayama A Suzuki T Fujita T Matsunaga G Koide Y Yoshida M Ide S Kamada Y;JT- team 《Physical review letters》2008,101(5):055003
A spontaneous transition phenomena between two states of a plasma with an internal transport barrier (ITB) is observed in the steady-state phase of the magnetic shear in the negative magnetic shear plasma in the JT-60U tokamak. These two ITB states are characterized by different profiles of the second radial derivative of the ion temperature inside the ITB region (one has a weak concave shape and the other has a strong convex shape) and by different degrees of sharpness of the interfaces between the L mode and the ITB region, which is determined by the turbulence penetration into the ITB region. 相似文献
47.
Solvent‐Dependent Structure of the I3− Ion Derived from Photoelectron Spectroscopy and Ab Initio Molecular Dynamics Simulations 下载免费PDF全文
Dr. Naresh K. Jena Ida Josefsson Dr. Susanna K. Eriksson Prof. Anders Hagfeldt Prof. Hans Siegbahn Prof. Olle Björneholm Prof. Håkan Rensmo Dr. Michael Odelius 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(10):4049-4055
Ab initio molecular dynamics (MD) simulations of the solvation of LiI3 in four different solvents (water, methanol, ethanol, and acetonitrile) are employed to investigate the molecular and electronic structure of the I3? ion in relation to X‐ray photoelectron spectroscopy (XPS). Simulations show that hydrogen‐bond rearrangement in the solvation shell is coupled to intramolecular bond‐length asymmetry in the I3? ion. By a combination of charge analysis and I 4 d core‐level XPS measurements, the mechanism of the solvent‐induced distortions has been studied, and it has been concluded that charge localization mediates intermolecular interactions and intramolecular distortion. The approach involving a synergistic combination of theory and experiment probes the solvent‐dependent structure of the I3? ion, and the geometric structure has been correlated with the electronic structure. 相似文献
48.
49.
Bromine formation in the mixture of solid NaBr and KNO3 was observed and the process was studied in different acidified organic solvent–water mixtures by monitoring the bromination of acetanilide and other compounds, containing activated aromatic substituents. This assay is based on fast bromination reaction of these aromatic compounds, as differently from the assay of Br2, the brominated aromatics can be easily determined by conventional gas chromatography–mass spectrometry (GC–MS) methods. It was found that bromine was generated autocatalytically on the surface of salt crystals and the reaction was characterized by a lag period, the duration of which depended on reaction conditions, and importantly on the type of the organic solvent in the reaction mixture. As the bromine formation could be easily controlled by reaction conditions, it was suggested that the studied reaction might have practical applications as an environmentally friendly and economically feasible bromination method. It was also shown that the bromination of aromatics followed the mechanism of classical electrophilic aromatic substitution reaction. 相似文献
50.
Ida S Shiga D Koinuma M Matsumoto Y 《Journal of the American Chemical Society》2008,130(43):14038-14039
One-nanometer-thick nickel hydroxide nanosheets were prepared by exfoliation of layered nickel hydroxides intercalated with dodecyl sulfate (DS) ions. The shape of the nanosheets was hexagonal, as was that of the layered nickel hydroxides intercalated with DS ions. The nickel hydroxide nanosheets exhibited charge-discharge properties in strong alkaline electrolyte. The morphology of the nanosheet changed during the electrochemical reaction. 相似文献