New biochemical material laser emission in microdroplets using ribo-flavin and its enhancement by mixing highly scattering intralipid medium

New laser emission from a biochemical material, ribo-flavin (vitamin B₂), at 570 nm was observed for the first time in liquid microdroplets pumped at 475 nm using a pulsed optical parametric oscillator. Laser emission spectra from microdroplets containing ribo-flavin in water and glycerol solution exhibit periodic mode structures depending on the microdroplet diameter demonstrating the morphology-dependent resonances. Magnitude enhancement of lasing emission is confirmed experimentally from liquid microdroplets of ribo-flavin solution with appropriate mixture of the fat emulsion Intralipid-10% suspension as highly scattering medium. We believe that such biochemical-soft multiple light scatterer systems may allow a wide range lasing of other bio-materials and even lead to the discovery of some novel species as well as highly sensitive analysis and diagnosis for future applications.     

Magnetic moments and GT-type β-decay matrix elements in nuclei with a LS doubly closed shell plus or minus one nucleon

The magnetic moments and GT-type β-decay matrix elements of nuclei with an ¹⁶O core plus (minus) one nucleon and with a ⁴⁰Ca core plus(minus) one nucleon are studied from the point of view of configuration mixing in terms of second order perturbation theory. It is found that the effect of the mixing of highly excited configurations through a tensor force is essential to explain the large reduction of the GT-type β-decay matrix elements. It is also found that modulus of the isovector parts of the gyromagnetic ratio, g_τS and g_τl, are appreciably reduced by the configuration mixing.     

High-Resolution Reflectometry by Optical Multidigitized Coherence

We propose and confirm a novel technique of optical frequency domain reflectometry based on multidigitized coherence using a multimode laser. The proposed system can easily provide the potential for high resolution on the order of 10 μm without scanning frequencies as in frequency domain reflectometers of either continuous or stepwise sweep. The theoretical approach agrees well with the experimental results demonstrated using a commercially available multimode laser diode.     

Laser operation with output feedback pumping and first-order phase transition analogy

It is shown that by means of the newly proposed regime of output feedback pumping, a conventional laser exhibiting only second-order phase transition behavior generally displays the nonequilibrium analogue of a first-order phase transition. Optical bistability should also be achieved in the laser system under feedback pumping incorporated with an externally injected optical signal.     

A comparison of two single-pulse shock-tube techniques: The thermal decomposition of ethyl chloride and n-propyl chloride

This investigation presents a detailed examination of the relative reliability of the comparative and absolute rate methods as they are applied to kinetic studies in the single-pulse shock tube. For this purpose two previously studied reactions, the thermal elimination of HCl from ethyl chloride and n-propyl chloride, were selected and mixtures of these compounds were shock heated to temperatures in the range of 960°-1100°K. The experimental results were analyzed by both methods and the rate constants obtained from these analyses are compared with those of previous studies. The advantages and shortcomings of both methods are noted and it is concluded that reliable kinetic data can be obtained by the absolute rate (isolation technique) method with careful examination of the gas-dynamic flow conditions and taking cognizance of the incident shock deceleration. The limitations of the comparative rate technique encountered in the present study were similar to those detailed in previous investigations.     

Direct Monte Carlo simulation of scattering processes of kV electrons in aluminum; comparison of theoretical N(E) spectra with experiment

A Monte Carlo simulation of the scattering processes of kV electrons penetrating into aluminum was performed. The simulation is based on the use of different types of differential cross-sections for individual elastic and inelastic scattering: (i) Elastic scattering; the differential cross-sections derived by partial wave expansion method. (ii) Inelastic scattering; Gryzinski's excitation function for inner-shell electron excitation, Streitwolfs excitation function for conduction electron excitation, and Quinn's mean free path for plasmon excitation. For verification the energy loss spectra obtained from the Monte Carlo calculations were then compared with experiment done with commercial type Auger microprobes, JAMP-3, for angle of incidence 45° and JAMP-10 for normal incidence at primary electron energies of 1.5 and 3.0 keV, respectively. The results show satisfactory agreement between theory and experiment.     

Backscattering correction for quantitative Auger analysis: I. Monte Carlo calculations of backscattering factors for standard materials

The electron backscattering effect which is important for the quantitative interpretation of “matrix effects” in AES is investigated by applying the Monte Carlo calculation technique. The present calculation model is based on the use of a precise elastic scattering cross-section obtained by the partial wave expansion method, as well as on the combined use of Gryzinski's excitation function and Bethe's stopping power for inelastic scattering. Systematic calculations of the backscattering factors were performed for over 25 materials including pure elements, compounds, and alloys, which have been widely used as standard materials for practical Auger analysis. The results should enable the accuracy of quantitative analysis by AES to be improved.     

Photocrosslinkable polymers having p-phenylenediacrylate group in the side chain: Argon laser photoresist

Preparative methods and photosensitivity characteristics of polymers bearing the p-phenylene-diacrylate (PDA) group are described. Condensation of a copolymer of methyl methacrylate and glycidyl methacrylate with p-phenylenediacrylic acid monoester gave highly photosensitive polymers. An alternative method to introduce PDA group is the substitution of chloromethyl-styrene polymer with p-phenylenediacrylic acid monoester monoalkali salt. The latter method was found to be more favorable for preparing soluble photosensitive polymers. The polymers thus prepared showed high sensitivity to light of 488 nm from an Argon laser when sensitizers are used, and the photocrosslinking quantum efficiency was 0.44. Preliminary results on holographic recording with this polymer is also mentioned.