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181.
Kaji H Maiguma T Inukai Y Ono H Taniguchi R Makino K Tagawa Y Teshima D 《Journal of AOAC International》2005,88(4):1114-1117
A simple liquid chromatography (LC) method was developed for determination of the therapeutic level of mizoribine in human plasma. After precipitation of plasma proteins with 6% perchloric acid, mizoribine was determined by LC with spectophotometric detection. The peak height for mizoribine was linearly related to its concentrations, which ranged from 0.09 to 3.13 microg/mL. Therefore, the limit of quantitation was considered to be 0.09 microg/mL. The accuracy was 104.96-107.37%. The intra- and interday relative standard deviation values were in the range of 1.10-3.25%. The detection limit was 0.025 microg/mL, defined as a signal-to-noise ratio of 3. The plasma concentrations of mizoribine were not related to the dosage. Because mizoribine was mainly excreted in the urine, the plasma concentrations of mizoribine might be affected by a change in renal function. Therefore, the mizoribine concentration in blood should be monitored and the dosage adjusted, depending on the condition of renal function. It was suggested that the present method may be applied well in the therapeutic drug monitoring for mizoribine. 相似文献
182.
The infimal Heegaard gradient of a 3-manifold was defined andstudied by Marc Lackenby in an approach towards proving thewell-known virtually Haken conjecture. As instructive examples,Seifert fibered 3-manifolds are considered in this paper. Theauthor shows that a compact orientable Seifert fibered 3-manifoldhas zero infimal Heegaard gradient if and only if it virtuallyfibers over either the circle or a surface other than the 2-sphereor, equivalently, if it has infinite fundamental group. 2000Mathematics Subject Classification 57M10 (primary), 57N10, 57M50(secondary). 相似文献
183.
Hideaki Haneishi Ritsuko Ohtake Norimichi Tsumura Yoichi Miyake Po-Chie Hung Hans Roehrig William J. Dallas 《Optical Review》1998,5(3):163-173
A method is presented for matching apparent sharpness between digital image display devices with different characteristics. The sharpness is most precisely described by the point spread function (PSF) as opposed to dot density such as DPI (dot per inch). The difference between devices is expressed as difference between transfer functions obtained from the PSFs. In the presented method, spatial frequency filtering for one digital image is carried out where the ratio of the transfer functions or its modified version is used as filter. The modification is introduced as a clipping operation to reduce excessive enhancement when the ratio of the transfer functions has a high pass characteristic with large gain. Through computer simulation including a subjective evaluation experiment and numerical evaluation, the effectiveness of filtering operation for sharpness matching is demonstrated. 相似文献
184.
185.
186.
H. Nagao K. Awazu S. Hayakawa K. Iwamoto M. Toyoda T. Ichihara 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,45(2):279-287
Various dissociation channels of silver bromide cluster ion
Ag2Br+ and silver cluster ion Ag3
+ were observed in
high-energy collisionally-activated dissociation (CAD) using a Cs target.
The fragment patterns of the high-energy CAD were compared with those of the
metastable dissociation and low-energy CAD. The difference in the fragment
patterns between the high-energy CAD and the other dissociation methods was
explained in terms of the internal energy distributions. The dissociation
mechanisms of neutral silver bromide cluster Ag2Br and silver cluster
Ag3 were also investigated by charge inversion mass spectrometry using
the Cs target. While the fragment ions AgBr- and Ag2
- were
dominantly observed in the charge inversion spectrum of Ag2Br+,
the undissociated ion Ag3
- was observed as a predominant peak in
the case of Ag3
+. The dissociation behavior of Ag2Br*
can be explained on the basis of the calculated thermochemical data.
Contrary to this, the predominant existence of the undissociated
Ag3
- cannot be explained by the reported thermochemical data. The
existence of undissociated Ag3
- suggests that the dissociation
barrier is higher than the internal energy of Ag3
*
(theoretical: 1.03 eV, experimental: 2.31 eV) estimated from the ionization
potentials of Ag3 and Cs. 相似文献
187.
Keisuke Ichihara Prof. Hidetoshi Kawai Yuka Togari Emi Kikuta Hitomi Kitagawa Prof. Seiji Tsuzuki Dr. Kenji Yoza Prof. Masamichi Yamanaka Prof. Kenji Kobayashi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(11):3685-3692
Remarkably enhanced stability of the self‐assembled hydrogen‐bonded heterocapsule 1?2 by the encapsulation of 1,4‐bis(1‐propynyl)benzene 3 a was found with Ka=1.14×109 M ?1 in CDCl3 and Ka2=1.59×108 M ?2 in CD3OD/CDCl3 (10 % v/v) at 298 K. The formation of 3 a @( 1?2 ) was enthalpically driven (ΔH°<0 and ΔS°<0) and there was a unique inflection point in the correlation between ΔH° versus ΔS° as a function of polar solvent content. The ab initio calculations revealed that favorable guest–capsule dispersion and electrostatic interactions between the acetylenic parts (triple bonds) of 3 a and the aromatic inner space of 1?2 , as well as less structural deformation of 1?2 upon encapsulation of 3 a , play important roles in the remarkable stability of 3 a @( 1?2 ). 相似文献
188.
Ishida Y Eguchi R Matsunami M Horiba K Taguchi M Chainani A Senba Y Ohashi H Ohta H Shin S 《Physical review letters》2008,100(5):056401
Resonant photoemission at the Ti 2p and O 1s edges on a Nb-doped SrTiO(3) thin film revealed that the coherent state (CS) at the Fermi level (E(F)) had a mainly Ti 3d character whereas the incoherent in-gap state (IGS) positioned approximately 1.5 eV below E(F) had a mixed character of Ti 3d and O 2p states. This indicates that the IGS is formed by a spectral-weight transfer from the CS and subsequent spectral-weight redistribution through d-p hybridization. We discuss the evolution of the excitation spectrum with 3d band filling and rationalize the IGS through a mechanism similar to that proposed by Haldane and Anderson. 相似文献