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11.
A New Gamma-Ray Spectrum Catalog for PGAA 总被引:1,自引:0,他引:1
Zs. Révay G. L. Molnár T. Belgya Zs. Kasztovszky R. B. Firestone 《Journal of Radioanalytical and Nuclear Chemistry》2000,244(2):383-389
A major obstacle to the use of the prompt gamma activation analysis (PGAA) method has so far been the lack of a suitable library. Therefore, new measurements have been performed at the PGAA facility at Budapest Research Reactor (BRR) in order to create a prompt -ray catalog for qualitative and quantitative analysis. Prompt -ray energies and associated k
0-factors have been determined by internal standardization. The resulting catalog contains prompt -ray data from neutron capture and other reactions such as (n,), and decay -ray data from short-lived reaction products. Data have been measured for nearly all stable elements, from hydrogen to uranium. Generally, data for several isotopes are given, to enable isotopic analysis as well. 相似文献
12.
13.
Imre T Schlosser G Pocsfalvi G Siciliano R Molnár-Szöllosi E Kremmer T Malorni A Vékey K 《Journal of mass spectrometry : JMS》2005,40(11):1472-1483
A new anionic surfactant (RapiGest SF) was successfully used for site-specific analysis of glycosylation in human alpha-1-acid glycoprotein (AGP). By means of this analytical approach combined with capillary HPLC-mass spectrometry (and tandem mass spectrometry), the N-linked glycosylation pattern of AGP was explored. On the basis of mass matching and MS/MS experiments ca 80 different AGP-derived glycopeptides were identified. Glycosylation shows a markedly different pattern for the various glycosylation sites. At sites I and II, triantennary complex-type oligosaccharides predominate and at sites III, IV and V, tetra-antennary complex-type oligosaccharides predominate. Sites IV and V show the presence of additional N-acetyl lactosamine (Gal-GlcNAc) units (even higher degree of branching and/or longer antennae are also present). 相似文献
14.
K. Gruiz É. Fenyvesi É. Kriston M. Molnár B. Horváth 《Journal of inclusion phenomena and macrocyclic chemistry》1996,25(1-3):233-236
Bioavailability and toxic effect of contaminants are the main limitations during soil bioremediation. Cyclodextrins may influence bioavailability of the contaminants during biodegradation and also toxicity of the pollutant on soil microbes and plants since their ability to form inclusion complei with organic compounds. The effect of cyclodextrins on bioremediation and on toxic effect of hydrocarbons was investigated by testing the activity of hydrocarbon degrading microflora and of plant growth. The effect of cyclodextrins could be demonstrated in both cases: biodegradation of hydrocarbons could be enhanced and toxic effect of hydrocarbons on plants and soil microbes could be decreased by adding cyclodextrins. 相似文献
15.
Bonhommeau S Bréfuel N Pálfi VK Molnár G Zwick A Salmon L Tuchagues JP Sanchez Costa J Létard JF Paulsen H Bousseksou A 《Physical chemistry chemical physics : PCCP》2005,7(15):2909-2914
A quasi-quantitative photo-induced low-spin (LS)-->high-spin (HS) conversion of FeII ions has been observed in the [Fe(TRIM)2]Cl2 complex by irradiating the sample with blue light (488 nm) at 10 K. The time dependence of the HS-->LS relaxation has been studied between 10 K and 44 K by means of magnetic susceptibility measurements. These relaxation curves could be satisfactorily fitted by mono-exponential decays including tunnelling effect except for temperatures below 30 K. The introduction of a distribution of vibrational frequencies into this model improved significantly the fits in the low-temperature range and gave a good agreement with the experimental data in the whole temperature range suggesting a multi-rate relaxation process in this complex. 相似文献
16.
G. L. Molnár Zs. Révay R. L. Paul R. M. Lindstrom 《Journal of Radioanalytical and Nuclear Chemistry》1998,234(1-2):21-26
Applying thek
0 standardization method to prompt-gamma activation analysis (PGAA) offers similar benefits as in instrumental neutron activation
analysis. It has been demonstrated that under constant flux conditionsk
0-factors obtained by normalizing to a titanium comparator, measured separately, yield consistent analytical sensitivity ratios.
The ratio method has been generalized by using stoichiometric compounds for the determination ofk
0-factors. Since chlorine forms compounds with essentially everyelement and it also serves as a detector efficiency standard,k
0 values have been determined relative to chlorine as an internal standard for several analytically important elements in two
reactor facilities: the thermal guided beam at the BRR in Budapest and the cold-neutron beams at the NBSR at NIST. 相似文献
17.
Summary Reinvestigation by HPLC of the petals ofLilium tigrinum and the isolation of some minor compounds is reported. Using HPLC-controlled, preparative-column chromatography, 5,6-diakarpoxanthin
(6), 6-epikarpoxanthin (2), 5,6-diacapsokarpoxanthin (8), and 9Z-antheraxanthin (9Z-13) were isolated and characterized. Based on spectroscopic data the absolute configurations of6 and8 were identical with those originating from paprika, thus the 5,6-diakarpoxanthin (6) and 5,6-diacapsokarpoxanthin (8) have the 3S, 5S, 6S configuration and 6-epikarpoxanthin (2) has the 3S, 5R, 6S configuration.
Presented at: Balaton Symposium on High-Performance Separation Methods, Siófok, Hungary, September 3–5, 1997. 相似文献
18.
M. Liang H. Ohm B. De Sutter K. Sistemich B. Fazekas G. Molnär 《Zeitschrift für Physik A Hadrons and Nuclei》1991,340(2):223-224
The half-lives of low-lying levels of the neutron-rich isotopes102Mo and104Mo have been measured at the fission product separator Josef with the ß-- triple coincidence technique. Values of t1/2= 126(4)ps and 0.72(4)ns have been obtained for the 21
+ levels at 296 keV and 192 keV in102Mo and104Mo, respectively. Deformation parameters of ßq=0.28(1) and 0.31(1), respectively, are deduced, which are smaller than those of the isotones of Sr and Zr. The interacting boson model accounts well for the trend of 2+ energies in the Mo isotopes but slightly overpredicts the B(E2) values at saturation. A smooth dependence of 21
+ vs. E 21
+ is found for the A 100 region in agreement with the hydrodynamical model.Dedicated to Prof. Dr. P. Kienle on the occasion of his 60th birthday 相似文献
19.
In aqueous solutions (with or without salts) containing carboxylic acids, water can be bound with anhydrous sodium sulphate at a molar ratio of [Na2SO4]/[H2O] ? 0.9. This is used prior to gas chromatography of aliphatic and aromatic di- and poly-carboxylic acids (oxalic to mellitic acid) in aqueous matrices (solutions, suspensions). Such acids are extracted quantitatively into diethyl ether within 8–10 min, which is much faster than conventional methods. Esterification is done with diazomethane. 相似文献
20.
Expedient and Diastereodivergent Assembly of Terpenoid Decalin Subunits having Quaternary Stereocenters through Organocatalytic Robinson Annulation of Nazarov Reagent
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Barbara Berkes Kristóf Ozsváth Laura Molnár Tamás Gáti Tamás Holczbauer György Kardos Tibor Soós 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(50):18101-18106
We report an expedient approach to highly functionalized cis‐ and trans‐decalines that could function as key structural subunits toward the synthesis of various classes of terpenoids. Key to the strategy is an organocatalyzed Robinson annulation reaction of the Nazarov reagent that affords chiral enone building blocks with high enantioselectivities. The quaternary carbon stereogenic center can direct the subsequent reactions and allow the rapid and diastereoconvergent assembly of complex decalines with contiguous stereocenters. 相似文献