全文获取类型
收费全文 | 507篇 |
免费 | 16篇 |
国内免费 | 12篇 |
专业分类
化学 | 376篇 |
晶体学 | 5篇 |
力学 | 7篇 |
数学 | 83篇 |
物理学 | 64篇 |
出版年
2023年 | 3篇 |
2022年 | 3篇 |
2021年 | 6篇 |
2019年 | 11篇 |
2018年 | 5篇 |
2017年 | 5篇 |
2016年 | 13篇 |
2015年 | 10篇 |
2014年 | 14篇 |
2013年 | 32篇 |
2012年 | 41篇 |
2011年 | 47篇 |
2010年 | 20篇 |
2009年 | 15篇 |
2008年 | 32篇 |
2007年 | 35篇 |
2006年 | 23篇 |
2005年 | 31篇 |
2004年 | 30篇 |
2003年 | 34篇 |
2002年 | 17篇 |
2001年 | 9篇 |
2000年 | 8篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 10篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 4篇 |
1971年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有535条查询结果,搜索用时 15 毫秒
31.
Andrew S. Rowan Thomas S. Moody Roger M. Howard Toby J. Underwood Iain R. Miskelly Yanan He Bo Wang 《Tetrahedron: Asymmetry》2013,24(21-22):1369-1381
Libraries of highly enantioenriched secondary alcohols in both enantiomeric forms were synthesised by enzymatic reduction of their parent ketones using selectAZyme? carbonyl reductase (CRED) technology. Commercially available CREDs were able to reduce a range of substrate classes efficiently and with very high enantioselectivity. Matching substrate classes to small subsets of CREDs enabled the fast development of preparative bioreductions and the rapid generation of 100–1500 mg samples of chiral alcohols in typically >95% ee and the majority in ?99.0% ee. The conditions for small scale synthesis were then scaled up to 0.5 kg to deliver one of the chiral alcohols, (S)-1-(4-bromophenyl)-2-chloroethanol, in 99.8% ee and 91% isolated yield. 相似文献
32.
33.
Daniel Xu Andreas Tairych Iain A. Anderson 《Journal of Polymer Science.Polymer Physics》2016,54(4):465-472
Practice makes perfect to some extent. Research has shown that musicians who practice the piano for long periods of time can suffer a range of hand problems from loss of control to diminished speed. Now imagine a rubber keyboard that is springy, soft, and elastic. This is the new type of input device that dielectric elastomers (DE) can create. However their usage in large sensing systems is limited by a scalability challenge. Each DE sensor is married to a pair of connection cables and electronics, adding to the complexity of the background overheads. A new efficient multi‐frequency method is presented that is capable of detecting internal pressure changes from a difference in the DE's capacitance without the need for any additional wires or connections. This effectively segments the DE into smaller sections, achieving information from a single sensor equivalent to multiple sensors. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 465–472 相似文献
34.
35.
Danny Mortimer Matthew Whiting Joseph P.A. Harrity Simon Jones Iain Coldham 《Tetrahedron letters》2014
Lewis acid mediated intramolecular Mannich reaction between an azocinone and a 3-formylindole was investigated as part of a study towards the synthesis of actinophyllic acid. The intramolecular Mannich reaction resulted in a single diastereomer of the 1-azabicyclo[4.2.1]nonan-5-one core framework, although single crystal X-ray structure analysis revealed that this had the undesired stereochemistry in comparison with the natural product. 相似文献
36.
37.
Automotive proton-exchange membrane fuel cells (PEMFCs) have finally reached a state of technological readiness where several major automotive companies are commercially leasing and selling fuel cell electric vehicles, including Toyota, Honda, and Hyundai. These now claim vehicle speed and acceleration, refueling time, driving range, and durability that rival conventional internal combustion engines and in most cases outperform battery electric vehicles. The residual challenges and areas of improvement which remain for PEMFCs are performance at high current density, durability, and cost. These are expected to be resolved over the coming decade while hydrogen infrastructure needs to become widely available. Here, we briefly discuss the status of automotive PEMFCs, misconceptions about the barriers that platinum usage creates, and the remaining hurdles for the technology to become broadly accepted and implemented. 相似文献
38.
A family of Hecke C*-algebras can be realised as crossed productsby semigroups of endomorphisms. It is shown by dilating representationsof the semigroup crossed product that the category of representationsof the Hecke algebra is equivalent to the category of continuousunitary representations of a totally disconnected locally compactgroup. 相似文献
39.
This paper continues the study of quantised function algebrasO[G] of a semisimple group G at an lth root of unity . Thesealgebras were introduced by De Concini and Lyubashenko in 1994,and studied further by De Concini and Procesi and by Gordon,amongst others. Our main purpose here is to increase understandingof the finite-dimensional factor algebras O[G](g), for g G.We determine the representation type and block structure ofthese factors, and (for many g) describe them up to isomorphism.A series of parallel results is obtained for the quantised Borelalgebras and . 2000 Mathematical Subject Classification: 16W35,17B37. 相似文献
40.
Ashweek NJ Coldham I Snowden DJ Vennall GP 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(1):195-207
Enantiomerically enriched alpha-amino-organolithium species, in which the lithium atom is attached to a stereogenic carbon centre, have been found to be chemically stable at room temperature in a solvent of very low polarity and undergo intramolecular carbolithiation onto an unactivated alkene. The configurational stability of the chiral organolithium species, bearing a variety of N-alkenyl substituents, was probed by studying the enantiomeric purity of the cyclization products. With N-but-3-enyl-2-lithiopyrrolidine, cyclization to the five-membered ring is more rapid than racemization and a high yield of the pyrrolizidine alkaloid (+)-pseudoheliotridane was obtained with no loss of optical purity. In contrast, with N-pent-4-enyl-2-lithiopyrrolidine, cyclization to the six-membered ring was found to occur with significant loss of optical purity. The cyclization to the six-membered ring was determined to occur with a half-life, t(1/2) approximately 90 min at 23 degrees C. The epimerization of this organolithium species in hexane/Et2O 4:1 was calculated to have a half-life, t(1/2) approximately 30 min at 23 degrees C. Enhanced levels of enantioselectivity for the formation of the indolizidine ring system were obtained using an alkene bearing a terminal phenylthio substituent. With N-[(3-phenylthio)-prop-2-enyl]-2-lithiopyrrolidine, cyclization to the four-membered ring occurs with poor enantioselectivity at low temperature in THF but is highly enantioselective at room temperature in a solvent of very low polarity. 相似文献