全文获取类型
收费全文 | 632篇 |
免费 | 16篇 |
国内免费 | 12篇 |
专业分类
化学 | 424篇 |
晶体学 | 6篇 |
力学 | 34篇 |
数学 | 108篇 |
物理学 | 88篇 |
出版年
2023年 | 5篇 |
2021年 | 6篇 |
2020年 | 5篇 |
2019年 | 15篇 |
2018年 | 7篇 |
2017年 | 8篇 |
2016年 | 13篇 |
2015年 | 11篇 |
2014年 | 14篇 |
2013年 | 38篇 |
2012年 | 46篇 |
2011年 | 54篇 |
2010年 | 22篇 |
2009年 | 16篇 |
2008年 | 35篇 |
2007年 | 43篇 |
2006年 | 27篇 |
2005年 | 38篇 |
2004年 | 33篇 |
2003年 | 41篇 |
2002年 | 18篇 |
2001年 | 9篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1998年 | 4篇 |
1997年 | 11篇 |
1996年 | 5篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1988年 | 4篇 |
1986年 | 11篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 5篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 7篇 |
1977年 | 9篇 |
1976年 | 2篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1972年 | 2篇 |
1971年 | 3篇 |
1967年 | 2篇 |
排序方式: 共有660条查询结果,搜索用时 15 毫秒
61.
Joseph W. Rumer Sheng‐Yao Dai Matthew Levick Laure Biniek David J. Procter Iain McCulloch 《Journal of polymer science. Part A, Polymer chemistry》2013,51(6):1285-1291
Two novel dihydropyrroloindoledione (DPID)‐based copolymers have been synthesized in a two directional approach and characterized (gel permeation chromatography (GPC), ultraviolet‐visible (UV–vis), cyclic voltammetry, and computational models). These planar, broad absorption copolymers show promise for use in organic electronics, with deep energy levels and low bandgaps. The two‐directional Knoevenagel condensation used demonstrates the versatility of DPID as a useful yet underexploited conjugated unit. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
62.
Nichole Cates Miller Roman Gysel Chad E. Miller Eric Verploegen Zach Beiley Martin Heeney Iain McCulloch Zhenan Bao Michael F. Toney Michael D. McGehee 《Journal of Polymer Science.Polymer Physics》2011,49(7):499-503
Polymer:fullerene blends have been widely studied as an inexpensive alternative to traditional silicon solar cells. Some polymer:fullerene blends, such as blends of poly(2,5‐bis(3‐tetradecylthiophen‐2‐yl)thieno[3,2‐b]thiophene (pBTTT) with phenyl‐c71‐butyric acid methyl ester (PC71BM), form bimolecular crystals due to fullerene intercalation between the polymer side chains. Here we present the determination of the eutectic pBTTT:PC71BM phase diagram using differential scanning calorimetry (DSC) and two‐dimensional grazing incidence X‐ray scattering (2D GIXS) with in‐situ thermal annealing. The phase diagram explains why the most efficient pBTTT:PC71BM solar cells have 75–80 wt % PC71BM since these blends lie in the center of the only room‐temperature phase region containing both electron‐conducting (PC71BM) and hole‐conducting (bimolecular crystal) phases. We show that intercalation can be suppressed in 50:50 pBTTT:PC71BM blends by using rapid thermal annealing to heat the blends above the eutectic temperature, which forces PC71BM out of the bimolecular crystal, followed by quick cooling to kinetically trap the pure PC71BM phase. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
63.
Motivated by Khovanov homology and relations between the Jones polynomial and graph polynomials, we construct a homology theory for embedded graphs from which the chromatic polynomial can be recovered as the Euler characteristic. For plane graphs, we show that our chromatic homology can be recovered from the Khovanov homology of an associated link. We apply this connection with Khovanov homology to show that the torsion-free part of our chromatic homology is independent of the choice of planar embedding of a graph. We extend our construction and categorify the Bollobás-Riordan polynomial (a generalization of the Tutte polynomial to embedded graphs). We prove that both our chromatic homology and the Khovanov homology of an associated link can be recovered from this categorification. 相似文献
64.
The drag and the inertia coefficients of the in-line force were determined experimentally based on the Morison equation. The
interrelationship of the in-line force coefficients with the frequency ratio, the amplitude ratio, and the y-direction response
were carefully examined. The experimental results show that the frequency ratio is more important in determining the drag
coefficient than either the Reynolds number or the reduced velocity, and that the drag coefficient is highly coupled to the
y-direction response.
Paper was presented at 1985 SEM Spring Conference on Experimental Mechanics held in Las Vegas on June 9–14, 1985. 相似文献
65.
Jonathan P. Williams Julie Ann Lough Iain Campuzano Keith Richardson Peter J. Sadler 《Rapid communications in mass spectrometry : RCM》2009,23(22):3563-3569
We report the development of an enhanced algorithm for the calculation of collision cross‐sections in combination with Travelling‐Wave ion mobility mass spectrometry technology and its optimisation and evaluation through the analysis of an organoruthenium anticancer complex [(η6‐biphenyl)RuII(en)Cl]+. Excellent agreement was obtained between the experimentally determined and theoretically determined collision cross‐sections of the complex and its major product ion formed via collision‐induced dissociation. Collision cross‐sections were also experimentally determined for adducts of this ruthenium complex with the single‐stranded oligonucleotide hexamer d(CACGTG). Ion mobility tandem mass spectrometry measurements have allowed the binding sites for ruthenium on the oligonucleotide to be determined. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
66.
67.
Richard Ducray Pascal Boutron Hervé Germain Maryannick Lamorlette Mickael Maudet Georges Pasquet Iain Simpson 《Tetrahedron letters》2010,51(36):4755-4701
A two-step synthesis of 3-(2-chloropyrimidin-4-yl)imidazo[1,2-a]pyridines is presented. The late stage elaboration of the imidazopyridine through a cyclocondensation allows a rapid access to a variety of substitution patterns. The intermediate enol ethers were obtained from inexpensive reagents in a ligand-free Heck coupling. This methodology has been extended to the formation of pyrazolo[1,5-a]pyridines via a formal 1,3-dipolar cycloaddition. 相似文献
68.
Jonathan P. Williams Hazel I. A. Phillips Iain Campuzano Peter J. Sadler 《Journal of the American Society for Mass Spectrometry》2010,21(7):1097-1106
The three-dimensional conformation of a protein is an important property and plays a key role in its biological activity.
We show here that ion mobility-mass spectrometry (IM-MS) can be used to detect conformational changes in the protein ubiquitin
in the gas phase induced by reaction with the anticancer drug cisplatin. The primary adduct was ubiquitin-{Pt(NH3)2} under denaturing conditions. Up to three different conformations appear to be generated upon platination depending on the
charge state. The collision cross-sections (Ω) for each conformation indicate that the conformations of the platinated protein
are contracted in size compared with unmodified ubiquitin with generally smaller Ω values. Ion mobility-tandem MS allowed
determination of the platinum binding site without a requirement for prior Chromatographic separation. A rapid 30-min digestion
of cisplatin-modified ubiquitin with trypsin allowed the platination site to be identified as the N-terminal methionine following
low-energy collision-induced dissociation (CID) studies of the modified peptide. The data were generated using a Traveling-Wave
based ion mobility-MS approach. Such cisplatin-induced shape changes may have a significant effect on its function in vivo.
This work highlights the usefulness of the ion-mobility mass spectrometry technique for shedding new light on such protein
interactions. 相似文献
69.
Gabrielse G Kolthammer WS McConnell R Richerme P Kalra R Novitski E Grzonka D Oelert W Sefzick T Zielinski M Fitzakerley D George MC Hessels EA Storry CH Weel M Müllers A Walz J;ATRAP Collaboration 《Physical review letters》2011,106(7):073002
Adiabatic cooling is shown to be a simple and effective method to cool many charged particles in a trap to very low temperatures. Up to 3×10(6) p are cooled to 3.5 K-10(3) times more cold p and a 3 times lower p temperature than previously reported. A second cooling method cools p plasmas via the synchrotron radiation of embedded e(-) (with many fewer e(-) than p in preparation for adiabatic cooling. No p are lost during either process-a significant advantage for rare particles. 相似文献
70.
On the inversion of diffusion NMR data: Tikhonov regularization and optimal choice of the regularization parameter 总被引:1,自引:0,他引:1
Day IJ 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2011,211(2):178-185
The analysis of diffusion NMR data in terms of distributions of diffusion coefficients is hampered by the ill-posed nature of the required inverse Laplace transformation. Na?ve approaches such as multiexponential fitting or standard least-squares algorithms are numerically unstable and often fail. This paper updates the CONTIN approach of the application of Tikhonov regularization to stabilise this numerical inversion problem and demonstrates two methods for automatically choosing the optimal value of the regularization parameter. These approaches are computationally efficient and easy to implement using standard matrix algebra techniques. Example analyses are presenting using both synthetic data and experimental results of diffusion NMR studies on the azo-dye sunset yellow and some polymer molecular weight reference standards. 相似文献