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91.
In the present paper an attempt has been made to study the intermittent and scaling behaviour of particles produced in the
interactions of 28Si-Em at 14.6A GeV. For this purpose, the method of normalized scaled factorial moments, F
q
, has been utilized. We have also studied some interesting features regarding the occurence of non-thermal phase transition
and scaling nature of F
q
-moments. 相似文献
92.
Zafar A. Siddiqi Sarvendra Kumar Mohd. Khalid M. Shahid 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,72(5):970-974
The bimetallic complexes [M2LCl4] (M = Cr, Co, Ni, Cu) prepared via metal template cyclization reactions were characterized by physico-chemical and spectroscopic methods. L is a 30-membered [N10] macrocycle with tetraamide functions bind metal ions through aza donors forming hexa-coordinate geometry. The perspective view and important structural parameters have been computed from the molecular model (MOPAC) method. The electrochemical studies indicate existence of quasi-reversible redox couples in solution. The metal complexes were screened (in vitro) against a few pathogenic fungi and bacteria to assess their growth inhibiting potential. 相似文献
93.
Structures and phase transitions for the isostructural series of compounds KFeO2, RbFeO2 and CsFeO2 have been systematically studied by synchrotron X-ray high resolution powder diffraction experiments and in case of CsFeO2 also by single crystal diffractometry. At room temperature, all of the three compounds crystallize in the orthorhombic (Pbca) KGaO2 type of structure consisting of a three dimensional network of corner-sharing [FeO4/2]− tetrahedra, which at elevated temperatures shows a reversible phase transformation to a cubic structure (space group ). For KFeO2, RbFeO2 and CsFeO2 this phase transformation takes place at 1003 K, 737 K and 350 K respectively, as confirmed by differential scanning calorimetry and X-ray diffraction. Upon heating through the transitions the major structural changes are driven by the onset or enhancement of librational motion of the FeO4 tetrahedra. Due to this phenomenon the Fe-O-Fe bonds appear to step-wise getting straight, seemingly approaching 180° within the time and space averaged structure. 相似文献
94.
Zafar M. N. Nazar M. F. Raza M. A. Mughal E. U. Dalebrook A. F. Wright L. J. 《Russian Journal of General Chemistry》2017,87(3):554-563
Russian Journal of General Chemistry - Bis(pyridinium)amine 4,4'-[(2-aminophenyl)azanediyl]bis(1-methylpyridin-1-ium)triflate ([H2L][TfO]2) was synthesized and characterized by elemental... 相似文献
95.
Mir Azam Khan Zafar Iqbal Mohammad Rasul Jan Jasmin Shah Waqar Ahmad Zia Ul Haq Obaidullah 《Journal of Analytical Chemistry》2006,61(1):32-36
A simple spectrophotometric assay for the quantification of lactulose in pharmaceutical preparations was developed. The method
is based on hydrolysis of lactulose under acidic conditions. The hydrolyzed product reacts with resorcinol, giving absorption
peaks at 398 and 480 nm. Both absorption wavelengths can be used for the determination of lactulose. The limit of detection
of lactulose at 398 nm and 480 nm was 0.075 μg mL−1 and 0.65 μg mL−1, respectively. The calibration was linear in the range of 5–25 μg mL−1. Analytical conditions were optimized, and the method was validated for analysis of pharmaceutical preparations. The determined
amount of lactulose was found to be in good agreement with labeled claims in commercial products. The proposed method is economical,
convenient, and suitable for the quantification of lactulose in pharmaceutical preparations.
The text was submitted by the authors in English. 相似文献
96.
J. N. Spencer A. Grushow T. F. Ganunis K. N. Allott S. P. Kneizys H. Willis S. Puppala C. M. Salata A. I. Zafar B. J. Stein L. C. Hahn 《Journal of solution chemistry》1989,18(5):471-480
Thermodynamic parameters for the hydrogen bonded complexes of m-cresol with various bases in the solvent benzene have been determined from calorimetric and spectroscopic data. These data were analyzed by linear solvation energy relationships. When combined with data previously determined for the same complexes in CCl4 and cyclohexane solvents, it is shown that solvent effects on the thermodynamics of hydrogen bond formation are due to solvation of the free m-cresol and base through dipolar and perhaps donor-acceptor interactions. 相似文献
97.
Summary Dimethyl telluride, Me2Te, reacts with first row transition metal bis(chlorosulphates), M(SO3Cl)2(M=CrII, MnII, FeII, CoII, NiII, CuII) in MeCN resulting in the formation of compounds of the type [M(SO3Cl)2-(Me2Te)2]. These compounds are stable under N2 but decompose on exposure to moist air. The covalent nature of bonding of the SO3Cl– group has been ascertained on the basis of a positive shift in 1 (A) vibration, splitting of the doubly degenerate (E) modes and low molar conductivity values. The magnetic moments and electronic spectra suggest an octahedral geometry for these compounds (except for the NiII complex where a tetragonal distortion is observed) where each SO3Cl– group is bonded in a bidentate manner. 相似文献
98.
The 16-membered modified [N6] macrocylic ligand (L), a mimic to cyclic, hexapeptide is reacted with MCl2 and MCl3 resulting in complexes with stoichiometrices [MLCl2] (M = Cr, Mn, Co, Ni, Cu), [MLCl3] (M = Pt, Pd) and [MLCl2]Cl (M = Fe, Ru). Its reactions with the precursors [M(Ph3P)2Cl2] (M = Co, Ni, Pt, Pd) follow a ligand displacement path affording the final products which do not contain coordinated Ph3P. Complexes have been characterized from results of elemental analyses, conductometric, magnetic susceptibility, i.r. and
u.v.–vis (ligand field) spectral studies. Magnetic susceptibility and ligand field spectral data are consistent with a hexacoordinate
geometry for Cr2+, Mn2+, Fe3+, Co2+, Ni2+ and Cu2+ and four coordinate square-planar geometry for Pt2+ and Pd2+. Molecular orbital computations using CSChem ultra MOPAC software for an optimized minimum energy plot of the structure shows
that the ligand binds metal ions as a tetradentate (N,N,N,N) chelating agent. Cyclic voltammetric studies indicate formation
of stable reversible or quasi-reversible redox couples in solutions, which corroborates a kinetic stability of these complexes
in their variable oxidation states. 相似文献
99.
In this study, we present linear analysis of electrostatic counter-streaming instability in spin-polarized electron–positron–ion (e-p-i) plasma. With the aid of the separate spin evolution-quantum hydrodynamic (SSE-QHD) model, we derive the dispersion relation of counter-streaming instability. We numerically solve the dispersion and find four wave solutions: Langmuir wave, positron acoustic mode, and two electron and positron spin-dependent waves. It is noted that coupling of streaming and spin effects excites Langmuir instability and positron acoustic mode instability. However, in the absence of spin effect, only Langmuir instability will survive in e-p-i plasma. We have also discussed the effects of positron concentration, streaming speed, and spin polarization on the real frequency of waves and the growth rate. The present study may be helpful for understanding longitudinal wave propagation and instabilities in dense magnetized environments. 相似文献
100.
Some theorems for the null conguences within the framework of general theory of relativity are given. These theorems are important in themselves as they illustrate the geometric meaning of the spin coefficients. The newly developed Geroch-Held-Penrose (GHP) formalism has been used throughout the investigations. The salient features of GHP formalism that are necessary for the present work are given, and these techniques are applied to a pair of null congruences C (l) and C(n). 相似文献