Molecular Complexes of Crown Ethers in Crystals and Solutions

A review of the experimental and theoretical studies of the crown ether complexes with polar molecules in their crystals, solutions, and in a gas phase is given. The type of the molecular bonds in the complexes, their stoichiometry, and the change in the macrocycle conformation during complex formation are considered, as well as the effect of the macrocycle structure and the nature of the medium on the efficiency of the molecular bonding. New data are given on the enthalpies of transfer of the crown ethers from tetrachloromethane into solvents capable of forming hydrogen bonds. The enthalpies of specific interactions of macrocycles with the molecules of the solvents in the medium of the same solvents are characterized. The conformations of the crown ethers in the media under study are discussed.     

Inverse Problem with Free Boundary for Heat Equation

We establish conditions for the existence and uniqueness of a solution of the inverse problem for a one-dimensional heat equation with unknown time-dependent leading coefficient in the case where a part of the boundary of the domain is unknown.     

Growth and study of single crystals of (Na,K)NbO<Subscript>3</Subscript> solid solutions

(Na, K)NbO₃ crystals with a perovskite structure and a KNbO₃ content up to 40 mol % were grown from flux with the use of the solvent NaBO₂. The dielectric measurements of the crystals grown revealed phase transitions that had never been observed before in ceramic samples.     

Phase diagram of multilayer magnetic structures

Multilayer ferromagnet-layered antiferromagnet (Fe/Cr) structures frustrated because of roughness of interlayer boundaries were studied by mathematical modeling methods. The phase diagram of a three-layer system (plotted as film thickness versus the degree of roughness of the interfaces) was obtained, and the order parameter distributions in each phase were determined. The character of phase transitions in this system was studied. The applicability range of the Slonczewski magnetic proximity model was determined.     

Contributions to the synthesis of some ferrocene-containing antibiotics

This Review discusses the synthesis and characterization by our Group of new antibiotics belonging to the class of penicillins, cephalosporins and rifamycins with ferrocenyl and 1, 1′-ferrocenilene residues in the molecule. As reactants for 6-aminopenicillanic acid (6-APA) and 7-aminocephalosporanic acid (7-ACA) the following were used: 1, 1-bis(chlorocarbonyl)ferrocene, ferrocenyl sulfochloride, 1, 1′-ferrocenylenedisulfochloride and thioglycolic acids S-modified with ferrocene. In the synthesis of rifamycins, the hydrazides of the thioglycolic acids, S-modified with ferrocene, were employed as nucleophilic agents. The synthesized intermediates were characterized by elemental analysis, TLC, IR, UV and ¹H NMR spectra. The characterization of new antibiotics was made by TLC, IR and UV spectral analysis. Biological activity was tested on Gram-negative and Gram-positive bacteria. Good activity is reported towards Gram-positive bacteria in the case of derivatives containing residues of thioglycolic acid S-modified with ferrocene, the antibacterial activity being similar to that of amoxicillin, carbenicillin and cephalothin. All compounds are inactive towards Gram-negative bacteria.     

Plant polysaccharides I. Polysaccharides ofLagochilus and their biological activity

Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, fax (3712) 89 14 75. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 313–314, March–April, 1995. Original article submitted November 7, 1994.     

Number of small solutions of a homogeneous linear congruence

Translated from Matematicheskie Zametki, Vol. 50, No. 4, pp. 102–107, October, 1991.     

Optical diagnostics of dispersing He plasma

An experimental study has been made of the characteristics of radiation from a dispersing helium plasma. From measurements of the space-time dependence of the line intensities of the helium 2³P — n³D series we obtained the distribution of the populations of the n³D levels for n=3–10. The study has shown that over a wide range of conditions the high-lying levels (n=5–10) are in equilibrium with electrons while a substantial deviation from equilibrium is observed for levels n=3, 4. From the energy distribution of the populations of the upper levels we determined the space-time dependence of the electron temperature, which reflects the process of effective electron cooling during dispersal of the plasma. The gas temperature was estimated from the populations of helium singlet and triplet levels with n=5. The time distribution of the electron density in the plasma was found from the Stark broadening of the spectral lines.Deceased.V. D. Kuznetsov Siberian Physicotechnical Institute, Tomsk State University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 15–19, November, 1992.     

Simulating the Kinematic Dynamo Forced by Heteroclinic Convective Velocity Fields

We report on the integration of the kinematic dynamo problem in a spherical domain forced by velocity fields that are convective fluid flows resulting from a bifurcation analysis of the spherical Bénard problem. We derive a code based on generalized spherical harmonics that ensures a divergence-free magnetic field. We determine the growth or decay of a magnetic field in the kinematic dynamo equation for various physically relevant velocity fields which are stationary as well as time-periodic and chaotic. Velocity signals that are produced by heteroclinic cycles are used as an input to an energy-saturated kinematic dynamo equation that limits the growth of the linearly unstable modes. Preliminary calculations indicate the possibility of reversals of the magnetic field for this case of forcing. Received 8 October 1996 and accepted 28 April 1997     

Resistance of composite flywheel rim to radial tensile stresses from centrifugal forces based on results of pure bending of a rim segment

A method is proposed for evaluating the resistance of a flywheel rim to radial stresses in free rotation. The method is based on loading a rim segment in pure bending and calculating the limiting moment and the corresponding limiting angular velocity. Applicability of the method is substantiated theoretically by investigating the similarity of the radial stress diagrams in rotation and pure bending. The method is verified experimentally for the strained state of a rim segment in pure bending.Translated from Mekhanika Kompozitnykh Materialov, Vol. 29, No. 4, pp. 521–526, July–August, 1993.