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61.
I. P. Kuranova K. M. Polyakov E. A. Smirnova W. E. Höhne V. S. Lamzin R. Meijer 《Crystallography Reports》2003,48(6):953-958
Crystals of Saccharomyces cerevisiae inorganic pyrophosphatase suitable for X-ray diffraction study were grown by cocrystallization of the enzyme with cobalt chloride and imidodiphosphate. Saccharomyces cerevisiae is a metal-dependent enzyme which catalyzes hydrolysis of inorganic pyrophosphate to orthophosphate. The three-dimensional structure of this enzyme was solved by the molecular-replacement method and refined at 1.8 Å resolution to an R factor of 19.5%. Cobalt and phosphate ions were revealed in the active centers of both identical subunits (A and B) of the pyrophosphatase molecule. In subunit B, a water molecule was found between two cobalt ions. It is believed that this water molecule acts as an attacking nucleophile in the enzymatic cleavage of the pyrophosphate bond. It was demonstrated that cobalt ions and a phosphate group occupy only part of the potential binding sites (two chemically identical and crystallographically independent subunits have different binding sites). The arrangement of ligands and the structure of the nucleophile-binding site are discussed in relation to the mechanism of action of the enzyme and the nature of the metal activator. 相似文献
62.
C.H. Chen 《Journal of sound and vibration》2003,263(4):797-813
A neural-network-based method is offered to determine the flutter derivatives of section models under smooth and turbulent flows. The approach uses the observed dynamic responses to train an appropriate neural network. Subsequently, the modal parameters of the model for different mean velocities of wind flow are directly estimated using weight matrices in the neural network. The flutter derivatives can then be determined accurately. The validity of the present method is verified through numerical studies. Finally, the procedure is employed to process experimental data from an inverted-U-type section model, obtained from wind tunnel tests. 相似文献
63.
V. L. Gilyarov A. I. Slutsker V. P. Volodin L. A. Laius 《Physics of the Solid State》1997,39(1):132-135
The dependence of the energy characteristics on an adiabatically slowly increasing external force is determined analytically
for an anharmonic oscillator. The analytical results are confirmed by a numerical calculation. The nature of the force dependences
of the energy characteristics are determined and discussed.
Fiz. Tverd. Tela (St. Petersburg) 39, 153–157 (January 1997) 相似文献
64.
Mass distributions of fragments in the low-energy fission of nuclei from 187Ir to 213At have been analysed. This analysis has shown that shell effects in symmetric-mode fragment mass yields from the fission of pre-actinide nuclei could be described if one assumes the existence of two strongly deformed neutron shells in the arising fragments with neutron numbers N1 ≈ 52 and N2 ≈ 68. A new method has been proposed for quantitatively describing the mass distributions of the symmetric fission mode for pre-actinides with A ≈ 180–220. 相似文献
65.
B. I. Sokil 《Ukrainian Mathematical Journal》1997,49(11):1777-1781
On the basis of periodic Ateb functions, in the resonance and nonresonance cases, we construct the asymptotic approximation of one-frequency solutions of a boundary-value problem for a nonlinear nonautonomous equation. 相似文献
66.
Double-diffusive convection due to a cylindrical source submerged in a salt-stratified solution is numerically investigated
in this study. For proper simulation of the vortex generated around the cylinder, a computational domain with irregular shape
is employed. Flow conditions depend strongly on the thermal Rayleigh number, Ra
T
, and the buoyancy ratio, R
ρ. There are two types of onset of instability existing in the flow field. Both types are due to either the interaction of
the upward temperature gradient and downward salinity gradient or the interaction of the lateral temperature gradient and
downward salinity gradient. The onset of layer instability due to plume convection is due to the former, whereas, the onset
of layer instability of layers around the cylinder is due to the latter. Both types can be found in the flow field. The transport
mechanism of layers at the top of the basic plume belongs to former while that due to basic plume and layer around the cylinder
are the latter. The increase in Ra
T
reinforces the plume convection and reduces the layer numbers generated around the cylinder for the same buoyancy ratio.
For the same Ra
T
, the increase of R
ρ suppresses the plume convection but reinforces the layers generated around the cylinder. The profiles of local Nusselt number
reflects the heat transfer characteristics of plume convection and layered structure. The profiles of averaged Nusselt number
are between the pure conduction and natural convection modes and the variation is due to the evolution of layers.
Received on 13 September 1996 相似文献
67.
68.
The microwave subsidiary absorption threshold in tangentially magnetized yttrium-iron-garnet (YIG) films was measured as a function of the static magnetic field, film thickness and decrease in the 0.3–3 μm range is observed. The effect is explained quantitatively by using modified Damon-Eshbach dispersion relations which take into account exchange interactions.
The effect of temperature on hcrit, the smallest threshold field amplitude, in the 250<T< 450 K temperature range can be expressed by an empirical relationship hcrit Ms(T)-1.6 where Ms is the saturation magnetization. This hcrit vs Ms relationship is similar to that obtained for the magnetization dependence of parallel pump thresholds in Li-Ti ferrite compounds. 相似文献
69.
H.-J. Sue E. I. Garcia-Meitin N. A. Orchard 《Journal of Polymer Science.Polymer Physics》1993,31(5):595-608
The fracture behavior of a core-shell rubber (CSR) modified epoxy is investigated using both fracture mechanics and microscopy tools. The CSR-modified epoxy is found to be toughened via numerous line-array cavitations of the CSR particles, followed by plastic flow of the epoxy matrix. The toughening effect via the above craze-like damage process is found to be as effective as that of the well-known widespread rubber cavitation/matrix shear yielding mechanisms. The conditions for triggering the craze-like damage appear to be both stress state and rubber concentration dependent. The type of rubber tougheners utilized also plays a critical role in triggering this rather unusual craze-like damage in epoxy systems. © 1993 John Wiley & Sons, Inc. 相似文献
70.
This research extends previous work with dynamic models to manage groundwater quality by using the consumptive nitrate use rate instead of the nitrate application rate. The analysis indicates that misspecification results in overestimation of economic benefits, and supra-optimum nitrogen fertilizer application rates and groundwater nitrate stocks at a steady state. 相似文献