Quantum chemical study of molecular ion complexes with hydrogen bonds (Review)

Institute of Bioorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated from Zhurnal Strukturnoi Khimii, Vol. 33, No. 6, pp. 157–183, November–December, 1992.     

Congruences,equational theories and lattice representations

We survey results concerning the representations of lattices as lattices of congruences and as lattices of equational theories. Recent results and open problems will be mentioned.To László Fuchs on the occasion of his 70th birthday     

Light transmission by polymer-dispersed liquid crystals

Light transmission of nematic liquid crystals dispersed in a polymeric matrix is investigated. The paper gives a theoretical analysis of light transmission by the liquid crystal-polymer and liquid crystaldye-polymer systems based on determination of the total cross section of extinction. The mathematical model is considered in the anomalous diffraction approximation. The theoretical calculations are in good agreement with experimental data obtained for films based on cyanodiphenyl dispersed into a polyvinyl acetate matrix.Institute of Theoretical and Applied Mechanics, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 34, No. 6, pp. 118–122, November–December, 1993.Translated by L. Chernomorskaya     

Rapid multielemental analysis of Chinese reference soils by laser ablation inductively coupled plasma-source mass spectrometry

Summary Laser ablation inductively coupled plasma-source mass spectrometry has been used to determine thirty elements (Na, Mg, Al, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, As, Rb, Sb, Cs, Ba, La, Ce, Nd, Sm, Eu, Dy, Ho, Yb, Hf, Ta, W, Th, U) in seven Chinese reference soils. The Surrey prototype spectrometer was employed with sample ablation by a free-running ruby laser. Concentrations in the soils (GSS-2 to GSS-8) were calculated from elemental responses and sensitivities derived from another soil in the series, namely GSS-1. Comparisons with previous neutron activation analyses are made. Rapid semiquantitative analyses are proved feasible. About eighty percent of the LA-ICP-MS determined concentrations were within a factor of two of the concentrations measured by INAA, and many were considerably closer than this. Precisions were typically in the range 2–10% RSD, but some were considerably poorer for elements present at trace levels.     

Micron-image transfer system with brightness amplifier in gold-vapor laser

A gas-discharge gold-vapor laser on self-terminating transitions with operating wavelength λ=312.2 nm has been used to develop a highly efficient system for image transfer. An optical scheme and all its parameters have been chosen optimal for image quality. It has been found both theoretically and experimentally that the best results on micron-structure image transfer are obtained with 2–5-times image reduction. Various types of masks have been used. A 1-µm structure has been resolved due to the choice of optimal exposure time of 10 ms under a period of pulse repetition (0.6 – 0.8) ms; in this case, the minimal fringe dimension was ≈2 µm with an image dimension of 2 mm for a laser tube 1.8 cm in diameter.     

Temperature dependence of the efficiency at which electrons are captured into axial channeling

A procedure for calculating the efficiency at which electrons are captured into axial channeling with a realistic axis potential is discussed. That region in the space of the electron's total transverse energy E and angular momentum L (integrals of motion) which corresponds to stable bound states of the electron with an atomic row is found. The temperature dependence of the capture coefficient is analyzed. As the crystal temperature is increased, the capture coefficient decreases, to a particularly noticeable extent for beams making a small angle with the crystallographic axis and for crystals having a high atomic number z.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 69–74, May, 1988.     

Infrared reflection spectra in contactless nondestructive measurements of the electron density and mobility in indium phosphide

On the basis of numerical calculations and experimental studies we analyze the possibilities of measuring the electrophysical parameters of indium phosphide by means of infrared reflection spectra at wavelengths ranging from 5 to 200 m. We demonstrate that contactless nondestructive measurements of the electron density in the range 10¹⁶–10²⁰ cm^–3 can be made with a relative error not exceeding 15%, and of mobility with a relative error not exceeding 25%. A nomogram method is presented for rapid conversion of data from infrared reflection spectra into the parameters being measured.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 22–27, January, 1988.