Porphyrins 34. Mass spectrometric study of ethane- and ethylene-bis-porphyrins

The mass spectral behavior of 1, 2-di (mesoetioporphyr inyl-1)- and 1, 2-di (mesooctaethylporphyrlnyl) ethanes and ethylenes, their Cu and Ni complexes, as well as Ni Schiff bases of 1, 2-di (mesooctaethylporphyrinyl)ethane complexes, under ionization by electron impact and bombardment by accelerated atoms, was studied. Peaks of molecular ions, for which the basic decomposition pathways were established on the basis of an analysis of the parent and daughter ions, were observed in the electron impact mass spectra of all these compounds.For Communication 29, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 24–29, January, 1994.     

Synthesis,structure, and chemical properties of some N-(3-chloro-2-quinoxalyl)arylsulfonamides

We have developed a method for synthesis of N-(3-clzloro-2-quinoxalyl)sulfonamides by reaction of 2,3-dichloroquinoxaline with substituted arylsufonamides. Based on the IR spectra, we have established that in the solid state, the synthesized compounds exist in the form of amide tautomers. Alkylation of these compounds leads to N-metliyl-N-(3-chloro-2-quinoxalyl)arylsulfonamides. We demonstrate the possibility of nucleophilic substitution of the halogen upon treatment with O- and N-nucleophiles. The use of bifunctional nucleophiles leads to condensed quinoxalines.Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 30, No. 3, pp. 387–392, March, 1994.     

Influence of the chemical composition of plant oils on cytochrome P-450

The influence of sunflowerseed and cottonseed oils and also of fractions of normal and oxidized triacylglycerols isolated from them on cytochrome P-450 from rat liver microsomes has been investigated.     

Lipids of cottonseed and palm oils and compositions based on them

The phsicochemical indices and the fatty-acid and triacylglycerol compositions of cottonseed and palm oils, of cottonseed oil hydrogenate, and of compositions based on them have been determined with the aid of IR and UV spectroscopies, GLC analysis, and chemical transformations. The compositions and amounts of the main classes of lipids in the initial oils and the hydrogenate have been studied. It has been found that in the process of hydrogenation the amount of oxygenated components falls. The work was conducted with the financial support of the Uzbek Fund for Fundamental Investigations.     

Integration of the equations of planar and flexural vibrations of anisotropic plates in special functions of generalized complex variables

On the basis of the method of successive approximations in formal series we construct systems of particular solutions of the equations of planar and flexural harmonic vibrations of thin rectilinear anisotropic plates with a plane of symmetry of elastic properties parallel to the faces. The solutions constructed are classified as special sk-functions of generalized complex variables. Translated fromTeoreticheskaya i Prikladnaya Mekhanika No. 24, 1993, pp. 54–61.     

Surface grating formation and erasing on a-Se films

Surface relief formation at holographic recording on amorphous selenium films was demonstrated and investigated. The presence of this optical phase modulation component is essential for ensuring significant, stable and erasable optical recording in a-Se films at 290–320 K temperatures, where conventional photodarkening was known as insignificant and unstable. Photocrystallization can only be observed in super-exposed a-Se films at the given experimental conditions of hologram recording. Erasing behavior of surface relief gratings under heat treatment was also investigated in order to reveal further details of the mechanism. Photoinduced structural transformations within the amorphous phase, connected to local ordering under the condition of light-induced fluidity, are proposed as an explanation for the relief formation and erasing. The observed reversible optical recording process may be useful for the various optoelectronic applications of photoconductive a-Se layers. Received: 12 June 2000 / Accepted: 6 June 2001 / Published online: 30 August 2001     

Some remarks on metaplectic cusp forms and the correspondences of Shimura and Waldspurger

The simple relation between representations of the covering groups of SL₂ and GL₂ makes it possible to fuse and extend the recent metaplectic results of Shimura, Waldspurger, Flicker, and ourselves. By giving a new (purely local andL-function theoretic) treatment of the Waldspurger-Shintani correspondence, we also simplify some of Waldspurger’s original results.