CIDEP spin probing of the nanopores in cotton

Time-resolved electron paramagnetic resonance (TREPR) experiments are reported on an α-hydroxy acetophenone in waterg-glycerol and ethanol-ethanediol mixtures over a viscosity range of 1–32 cP. The magnitude and viscosity dependence of the radical pair mechanism polarization is in good agreement with theory. The triplet mechanism polarization is found to increase with decreasing solvent polarity and this is ascribed to an increase in the α-cleavage rate constant. The liquid spectra are used to interpret TREPR spectra of the acetophenone in dry and wet cotton. In dry cotton anti-phase structure is seen and is due to some of the radical pairs being trapped in cages. The triplet and radical pair mechanism polarization shows that the acetophenone adsorbs to the apolar crystallite surface and releases radicals into the polar amorphous regions where they experience a microviscosity of approximately 30 cP. In wet cotton there are no cages and the viscosity is greater than in ethanol alone.     

Monte Carlo方法研究低能电子束曝光沉积能分布规律

建立一个描述低能电子在多元多层介质中散射的物理模型,运用MonteCarlo方法模拟低能电子在靶体胶衬底中的复杂散射过程,在此基础上通过大量计算研究入射束能、胶层厚度、衬底材料等不同曝光条件对抗蚀剂沉积能密度分布的影响,获得沉积能分布规律:适量的低束能、薄胶层、低原子序数衬底可以使前散射电子对胶中沉积能密度分布的贡献增大、背散射电子的贡献减小,从而提高曝光分辨率. 关键词： 电子束曝光 MonteCarlo方法 低能电子散射 能量沉积     

Excitation and ionization of sodium clusters by a strong electromagnetic field

This paper reports on a study of the excitation and ionization of small sodium clusters by femtosecond light pulses with a maximum intensity of 5×10¹²–1×10¹⁴ W/cm² and photon energy from 1 to 3 eV made in terms of the density functional theory and jellium model through direct numerical solution of the Kohn-Sham time-dependent equation. The dependence of the degree of ionization on the intensity, duration, and frequency of the light pulses, as well as on the cluster size, is studied. The efficiency of the processes is shown to be determined primarily by the field intensity rather than by the total pulse energy.     

Barrier-free intermolecular proton transfer in the uracil-glycine complex induced by excess electron attachment

The photoelectron spectra (PES) of anions of uracil-glycine and uracil-phenylalanine complexes reveal broad features with maxima at 1.8 and 2.0 eV. The results of ab initio density functional B3LYP and second order M?ller-Plesset theory calculations indicate that the excess electron occupies a π^* orbital localized on uracil. The excess electron attachment to the complex can induce a barrier-free proton transfer (BFPT) from the carboxylic group of glycine to the O8 atom of uracil. As a result, the four most stable structures of the anion of uracil-glycine complex can be characterized as the neutral radical of hydrogenated uracil solvated by the anion of deprotonated glycine. The similarity between the PES spectra for the uracil complexes with glycine and phenylalanine suggests that the BFPT is also operative in the case of the latter anionic species. The BFPT to the O8 atom of uracil may be related to the damage of nucleic acid bases by low energy electrons because the O8 atom is involved in a hydrogen bond with adenine in the standard Watson-Crick pairing scheme. Received 6 April 2002 Published online 13 September 2002     

On the polarization interaction between two closely spaced conducting spheres in a uniform electrostatic field

An electrostatic interaction between two separate, grounded, uncharged, perfectly conducting spheres of different radii in a uniform electrostatic field is investigated. It is shown that at a small center-to-center distance of the spheres, the force of the polarization interaction between the spheres depends appreciably more weakly on that distance in comparison to the force of the electrostatic interaction of two elementary dipoles as it should be in view of the interaction between two like polarization charges.     

遥感傅里叶变换红外光谱的大气层析技术

遥感傅里叶变换红外光谱层析技术是一项新的气体分析技术，它可用于构造气体浓度峰图形，定量分析工业污染气体总释放量等方面，随着算法的不断优化，在重构气体在空间的分布方面，遥感傅里叶变换红外光谱层析技术正在不断成长。     

Controlling global stochasticity of Hamiltonian systems by nonlinear perturbation

A method of controlling global stochasticity in Hamiltonian systems by applying nonlinear perturbation is proposed. With the well-known standard map we demonstrate that this control method can convert global stochasticity into regular motion in a wide chaotic region for arbitrary initial condition, in which the control signal remains very weak after a few kicks. The system in which chaos has been controlled approximates to the original Hamiltonian system, and this approach appears robust against small external noise. The mechanism underlying this high control efficiency is intuitively explained. Received 15 January 2002 Published online 6 June 2002     

Spontaneous formation of a system of highly ordered germanium nanoislands upon epitaxial deposition on profiled (111) silicon substrates under electromigration conditions

Atomic-force microscopy was used to study the surface topography of SiGe structures grown by epitaxial deposition of Ge on profiled Si(111) substrates under electromigration conditions. Systems of highly ordered germanium nanosized islands with dimensions of 10–20 nm and a density of 6×10¹⁰ cm^?2 were obtained. It is shown that the geometrical parameters of self-organizing nanoislands can be controlled by a proper choice of the growth and postgrowth annealing conditions for these structures.     

Synthesis and structures of nitroxyalkyl methylphosphonates

The reactions of ethylene glycol mononitrate and glycerol 1,3-dinitrate with methylphosphonic dichloride afforded new nitroxyalkyl methylphosphonates.     

To the description of hadron mass spectrum in the nonrelativistic quark potential model

The comparison of different confinement models of hadrons in non-relativistic quark potential model with the use of hyperspherical functions is carried out in the present work. Numerical values of the masses of non-strange (the lightest) hadrons belonging to the meson octet and baryon decuplet are obtained in this model. The best values of masses are obtained with the potential which incorporates the quasi-relativistic one-gluon exchange and the confinement termAr ⁿ withn=2/3. The natural appearance of the Yukawa-type potential in this model is also discussed.