全文获取类型
收费全文 | 476篇 |
免费 | 25篇 |
国内免费 | 5篇 |
专业分类
化学 | 405篇 |
晶体学 | 9篇 |
力学 | 19篇 |
数学 | 11篇 |
物理学 | 62篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 15篇 |
2021年 | 14篇 |
2020年 | 9篇 |
2019年 | 8篇 |
2018年 | 7篇 |
2017年 | 8篇 |
2016年 | 16篇 |
2015年 | 21篇 |
2014年 | 22篇 |
2013年 | 22篇 |
2012年 | 36篇 |
2011年 | 46篇 |
2010年 | 38篇 |
2009年 | 21篇 |
2008年 | 33篇 |
2007年 | 25篇 |
2006年 | 26篇 |
2005年 | 27篇 |
2004年 | 25篇 |
2003年 | 22篇 |
2002年 | 15篇 |
2001年 | 9篇 |
2000年 | 10篇 |
1999年 | 6篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 6篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 3篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1985年 | 1篇 |
排序方式: 共有506条查询结果,搜索用时 31 毫秒
71.
72.
Jin Jeong Chang Nyung Kim Baek Youn Young Saeng Kim 《International Journal of Heat and Fluid Flow》2004,25(6):1006-1014
The thermal contact resistance is a principal parameter interfering with heat transfer in a fin–tube heat exchanger. However, the thermal contact resistance in the interface between tubes and fins has not been clearly investigated. The objective of the present study is to examine the thermal contact conductance for various fin–tube heat exchangers with tube diameter of 9.52 mm and to find a correlation between the thermal contact conductance and effective factors such as expansion ratio, fin type, fin spacing and hydrophilic coating. In this study, experiments have been conducted only to measure heat transfer rate between hot and cold water. To minimize heat loss to the ambient air by the natural convection fin–tube heat exchangers have been placed in an insulated vacuum chamber. Also, a numerical scheme has been employed to calculate the thermal contact conductance with the experimental data. As a result, a new correlation including the influences of expansion ratio, slit of fin and fin coating has been introduced, and the portion of each thermal resistance has been estimated in the fin–tube heat exchangers with 9.52 mm tube. 相似文献
73.
We synthesized a novel 1,3,5-substituted triethylbenzene derivative with a benzimidazole moiety as a binding and signalling subunit. The triethylbenzene platform was judiciously incorporated into the receptor design such that all the fluorophores are in close proximity to each other in order to facilitate stacking. The advantage of this approach lies in the fact that the receptor will offer a dual channel emission for the multiple ratiometric determination of metal ions. The sensor was tested in a CH3CN/H2O (7:3, v/v, pH 7.1) HEPES buffered solution and successfully developed for the ratiometric and simultaneous estimation of Fe3+ and Cu2+ ions in aqueous samples. 相似文献
74.
We synthesized a novel benzimidazole-based, anthracene-coupled fluorescent receptor capable of recognizing and estimating the concentrations of Fe3+ in semi-aqueous solution by ratiometric estimation. Our sensor can be made highly selective for Fe3+ over other metal ions by changing the solvent composition. 相似文献
75.
Yoo NY Youn YS Oh NM Oh KT Lee DK Cha KH Oh YT Lee ES 《Colloids and surfaces. B, Biointerfaces》2011,88(1):419-424
The purpose of this study was to fabricate porous poly(lactide-co-glycolide) (PLGA) microparticles for efficient pulmonary deposition and increased therapeutic duration of the antioxidant anthocyanin (ATH). These microparticles were prepared by a water-in-oil-in-water (W(1)/O/W(2)) multi-emulsion method with vaporizing ammonium bicarbonate (AB) as a porogen and starch as a viscous additive. High porosity achieved by the decomposition reaction of AB to the base of ammonia, carbon dioxide, and water vapor at 50°C enabled efficient deposition of ATH throughout the entire lung in BALB/c mice. In addition, the porous microparticles incorporating starch showed sustained ATH release characteristics (up to 5 days) and protracted antioxidant activity (up to 5 days) for 2,2-diphenyl-1-pikryl-hydrazyl (DPPH) radicals, which was comparable to that of the porous microparticles without starch which completely released ATH in 2h. Furthermore, these porous microparticles incorporating starch led to longer ATH residence (up to 20 days) in in vivo lung epithelium. We believe that this system has great pharmaceutical potential as a long-acting antioxidant for continuously relieving oxidative stress in pulmonary diseases like chronic obstructive pulmonary disease (COPD). 相似文献
76.
Spintronic devices are very important for futuristic information technology. Suitable materials for such devices should have half-metallic properties so that only one spin passes through the device. In particular, organic half metals have the advantage that they may be used for flexible devices and have a long spin-coherence length. We predict that the one-dimensional infinite chromium porphyrin array, which we call Cr-PA(∞), shows half-metallic behavior when the spins on the chromium atoms are in a parallel alignment. Since the chromium atoms are separated by a large distance (>8 ?), the coupling between spins is small and thus their directions can be readily controlled by an external magnetic field. In the ferromagnetic state, the band gap for major spin electrons is 0.30 eV, while there is no band gap for the minor spin electrons, thus reflecting the half-metallic property. This unique property originates from the high spin state of Cr which results in the spin asymmetry of the conduction band in Cr-PA(∞). Electron transport of Cr-PA(1,2,3) is calculated with the nonequilibrium Green function technique in the presence of Au electrodes. It turned out that the spin-filtering ability appears from the dimeric Cr-PA(2). Thus, a new organometallic framework for designing a spin filter is proposed. Though many others have designed novel spintronic devices, none of them are realized due to the lack of a practical fabrication method at present. However, the porphyrin-based spintronic device provides a synthesizable framework. 相似文献
77.
Determination of hexavalent chromium (Cr(VI)) in plastics using organic-assisted alkaline extraction
An organic-assisted alkaline extraction method was developed for the determination of hexavalent chromium (Cr(VI)) in plastics. The solubilization of polymer as a pre-step of the alkaline extraction provided good extraction efficiency of Cr(VI) from the sample. The optimization of the experimental conditions affecting the extraction and UV–vis spectrophotometric analysis was accomplished by evaluating the recovery rate of Cr(VI) through the analysis of Cr(VI) in in-house polymer reference materials (RMs). With the proposed method, most of the Cr(VI) in polymers was released within a short extraction time of 30 min and the Cr(III)-DPCO complex can be kept stable for 24 h. The heating for the extraction of the Cr(VI) was not necessary. The optimal pH of the final solution was fixed at 2.0. The proposed extraction method was applied successfully for the determination of Cr(III) and Cr(VI) in spiked samples. The practical applicability of this new method was evaluated through the analysis of Cr(VI) in in-house polymer RMs. The good linearity was demonstrated at desired concentrations of the range 0–3.3 mg L−1. The detection limits were quite low, varying from 0.0061 to 0.0285 mg L−1. The recovery of Cr(VI) was between 97 and 106%, and the relative standard deviation (R.S.D.) was below 6%. 相似文献
78.
79.
Lee SY Lee S Kho IH Lee JH Kim JH Chang JH 《Chemical communications (Cambridge, England)》2011,47(36):9989-9991
An enzyme-magnetic nanoparticle conjugate is prepared via conjugation of Ni(2+) ions onto the surface of magnetic nanoparticles to interact with a six histidine-tagged enzyme. The catalytic properties and enzyme rigidification of the conjugates are more stable at high concentrations of aromatic hydrocarbons. 相似文献
80.
Lee BR Oh KT Oh YT Baik HJ Park SY Youn YS Lee ES 《Chemical communications (Cambridge, England)》2011,47(13):3852-3854
We report charge-switching ionic nanocomplexes comprised of glycol chitosan grafted with 2,3-dimethylmaleic acid (DMA) (denoted as 'GCS-g-DMA' hereafter) and a proapoptotic peptide. This system allowed for improved peptide delivery to tumor sites via a mechanism of selective peptide release when the pH was dropped from 7.4 to 6.8. 相似文献